The proposal of a GSSP for the Berriasian Stage (Cretaceous System): Part 1.

Here in the first part of this publication we discuss the possibilities for the selection of a GSSP for the Berriasian Stage of the Cretaceous System, based on the established methods for correlation in the Tithonian/Berriasian interval. This will be followed, in the second part, by an account of the stratigraphic evidence that justifies the locality of Tré Maroua (Hautes-Alpes, SE France) as the proposed GSSP. Here we discuss the possibilities for correlation in the historical J/K boundary interval, and the evolution of thinking on the positioning of the boundary over recent generations, and in relation to research in the last ten years. The Tithonian/Berriasian boundary level is accepted as occurring within magnetosubzone M19n.2n. The detailed distribution of calpionellids has been recorded at numerous sites, tied to magnetostratigraphy, and the base of the calpionellid Alpina Zone is taken to define the base of the Berriasian Stage. This is at a level just below the distinctive reversed magnetic subzone M19n.1r (the so-called Brodno reversal). We discuss a wide range of magnetostratigraphic and biostratigraphic data from key localities globally, in the type Berriasian areas of France and wider regions (Le Chouet, Saint Bertrand, Puerto Escaño, Rio Argos, Bosso, Brodno, Kurovice, Theodosia etc.). The characteristic datums that typify the J/K boundary interval in Tethys and its extensions are detailed, and the correlative viability of various fossil groups is discussed. The boundary level is correlated to well-known J/K sections globally, and a series of secondary markers and proxies are indicated which assist wider correlation. Particularly significant are the primary basal Berriasian marker, the base of the Alpina Subzone (marked by dominance of small Calpionella alpina, Crassicollaria parvula and Tintinopsella carpathica) and secondary markers bracketing the base of the Calpionella Zone, notably the FOs of the calcareous nannofossil species Nannoconus wintereri (just below the boundary) and the FO of Nannoconus steinmannii minor (just above). Notable proxies for the boundary are: 1) the base of the Arctoteuthis tehamaensis Zone in boreal and subboreal regions, 2) the dated base of the Alpina Subzone at 140.22 ± 0.14 Ma, which also gives a precise age estimate for the system boundary; and 3) the base of radiolarian “unitary zone” 14, which is situated just above the base of the Alpina Subzone

The proposal of a GSSP for the Berriasian Stage (Cretaceous System): Part 2

In part 1 of this work we discussed the possibilities for the selection of a GSSP for the Berriasian Stage of the Cretaceous System, based on prevailing practical methods for correlation in that J/K interval, traditional usage and the consensus over the best boundary markers that had developed in the last forty years. This consensus has developed further, based on the results of multidisciplinary studies on numerous sites over the last decade. Here in Part 2 we give an account of the application of those results by the Berriasian Working Group (ISCS), and present the stratigraphic evidence that justifies the selection of the locality of Tré Maroua (Hautes-Alpes, SE France) as the proposed GSSP. We describe a 45 m-thick section in the Calcaires Blancs vocontiens – that part of the formation covering the calpionellid Chitinoidella, Remanei. Intermedia, Colomi, Alpina, Ferasini, Elliptica and Simplex biozones. The stratigraphic data collected here has been compiled as part of a wider comparative study of complementary Vocontian Basin sites (with localities at Charens, St Bertrand, Belvedere and Le Chouet). Evidence from Tré Maroua thus sits in this substantial regional biostratigraphic and magnetostratigraphic context. For the purposes of the GSSP definition, here we particularly concentrate on the unbroken sequence and biotic markers in the interval immediately below the boundary, the Colomi Subzone (covering circa 675,000 years), and immediately above, the Alpina Subzone (covering circa 725,000 years). Particularly significant fossil datums identified in the Tré Maroua profile are the primary basal Berriasian marker, the base of the Alpina Subzone (a widespread event marked by dominance of small Calpionella alpina, with rare Crassicollaria parvula and Tintinopsella carpathica): the base of the Berriasian Stage is placed at the base of bed 14, which coincides with the base of the Alpina Subzone. Secondary markers bracketing the base of the Calpionella Zone are the FOs of the calcareous nannofossil species Nannoconus wintereri, close below the boundary, and the FO of Nannoconus steinmannii minor, close above. The Tithonian/Berriasian boundary level occurs within M19n.2n, in common with many documented sites, and is just below the distinctive reversed magnetic subzone M19n.1r (the so-called Brodno reversal). We present data which is congruent with magnetostratigraphic and biostratigraphic data from other key localities in France and in wider regions (Le Chouet, Saint Bertrand, Puerto Escaño, Rio Argos, Bosso, Brodno, Kurovice, Theodosia…), and thus the characteristics and datums identified at Tré Maroua are key for correlation and, in general, they typify the J/K boundary interval in Tethys and connected seas

Stratigraphy and microfacies of the Jurassic and lowermost Cretaceous of the Veliky Kamenets section (Pieniny Klippen Belt, Carpathians, Western Ukraine)

The Veliky Kamenets section in the eastern part of the Pieniny Klippen Belt in the Ukrainian Carpathians shows a well exposed, 83 m thick succession composed of Jurassic and lowermost Cretaceous (Berriasian) deposits. The terrigenous part of the section includes: gravels with a sandy matrix (unit 1A), massive grey-green sandstones (unit 1B) and shales with intercalations of siltstones/sandstones and oyster/gastropod lumachelles (unit 2). Organic-walled dinoflagellates document the Toarcian-Aalenian age of the siliciclastic deposits of unit 2. The carbonate part of the succession embraces: stromatactis mud-mounds interfingering with crinoidal limestones (unit 3A), lower nodular limestones (unit 3B), cherty limestones (unit 3C), upper nodular limestones (unit 3D), pink pelitic limestones (unit 3E), limestones with a volcanogenic bed (unit 5) and limestone breccia limestones (unit 6). This succession has yielded abundant ammonites from the Bathonian, Oxfordian and Kimmeridgian (with a stratigraphical hiatus covering the Callovian and Lower Oxfordian), as well as calcareous dinoflagellates (from the Upper Oxfordian towards the top of the succession), and calpionellids (in the Tithonian and Berriasian). Detailed stratigraphical study of the succession based both on ammonites and microfossils has resulted in the recognition of biostratigraphical units and their correlation with the chronostratigraphical scale.The microfacies recognized in the pelagic part of the succession include: the “filament” (Bositra) microfacies (Bathonian), the planktonic foraminifer microfacies (Oxfordian), the Saccocoma microfacies (Kimmeridgian to Upper Tithonian), and the calpionellid microfacies (Upper Tithonian–Berriasian). The volcanogenic rocks (lava flows and volcanic ash) appear in the topmost part of the succession (units 4 to 6) and this volcanic event is very precisely located in the Elliptica-Simplex chrons of the Middle and Late Berriasian

DPPH radical scavenging activity of several naturally occurring coumarins and their synthesized analogs measured by the SIA method

ABSTRACT Coumarins, naturally occurring compounds derived from benzopyran, have recently been studied extensively for their antioxidant properties. A lot of coumarins have been isolated and identified from natural sources and many others have been synthesized. It is also known that pharmacological and biochemical properties and thus also therapeutic application of simple coumarins depend upon the pattern of their substitution. As a part of studies of biological effects, four naturally occurring coumarins and 18 synthesized analogs of several compounds were assayed for 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) scavenging activity. For this purpose the highly reliable DPPH test modified to be performed by sequential injection analysis (SIA) system was used. This in our laboratory-developed method was originally proposed for antioxidant screening of large series of plant extracts. In this assay, the DPPH test using the SIA method was used for fast and sensitive evaluation of EC(50) of coumarins. The evaluation of EC(50) of a single compound takes only 15 to 30 min. The structure-activity relationships of tested compounds are also established. The results verified 7,8-dihydroxy-4-methylcoumarins as excellent DPPH radical scavengers. Obtained results correspond with those of other studies and suggest the SIA procedure as a suitable method for fast and sensitive antioxidant analysis of various types of compounds

Fixing a basal Berriasian and Jurassic/Cretacoeus (J/K) Boubdary: Is there perhaps some light at the end of the tunn

Our tentative proposal is that several biological markers have potential to help define any putative boundary in the traditional basal Berriasian interval. That is, between the base of the Berriasella jacobi Subzone and the base of the Pseudosubplanites grandis Subzone, and therefore straddling the base of magnetozone M18r. Promising micropalaeontological markers are the FADs of Nannoconus steinmannii minor and Nannoconus kamptneri minor, plus the base of the Calpionella alpina Zone, and the bloom(s) of Calpionella alpina and Crassicollaria parvula. The testing and calibration of this constraining event-matrix in the most complete and fossiliferous sections is our task for the near future