REDOX CHROMOPHORE COMPOUNDS AND ELECTRODES OF METAL CONTAINING SUBSTITUTED BIPYRIDINES

Chromophoric compounds, each having a wide range of distinct color changes in response to changes in the oxidation states thereof, are provided in the form of polymerizable monomers, and polymers thereof, of certain metal containing, and electron group substituted, 2,2\u27-bipyridine compounds. United States Patent Number 4,611,89

POLYMER ON GRAPHENE

A top - gated graphene field effect transistor can be fabricated by forming a layer of graphene on a substrate, and applying an electrochemical deposition process to deposit a layer of dielectric polymer on the graphene layer. An electric potential between the graphene layer and a reference electrode is cycled between a lower potential and a higher potential. A top gate is formed above the polymer

Electrochemical preparation of chitosan/hydroxyapatite composite coatings on titanium substrates

Composite coatings containing brushite (CaHPO4 • 2H2O) and chitosan were prepared by electrochemical deposition. The brushite/chitosan composites were converted to hydroxyapatite/chitosan composites in aqueous solutions of sodium hydroxide. The coatings ranged from 1 to 15% chitosan by weight. Qualitative assessment of the coatings showed adhesion signifi cantly improved over that observed for electrodeposited coatings of pure HA

Quantized magnetoresistance in atomic-size contacts

When the dimensions of a metallic conductor are reduced so that they become comparable to the de Broglie wavelengths of the conduction electrons, the absence of scattering results in ballistic electron transport and the conductance becomes quantized. In ferromagnetic metals, the spin angular momentum of the electrons results in spin-dependent conductance quantization and various unusual magnetoresistive phenomena. Theorists have predicted a related phenomenon known as ballistic anisotropic magnetoresistance (BAMR). Here we report the first experimental evidence for BAMR by observing a stepwise variation in the ballistic conductance of cobalt nanocontacts as the direction of an applied magnetic field is varied. Our results show that BAMR can be positive and negative, and exhibits symmetric and asymmetric angular dependences, consistent with theoretical predictions. Includes supplemental figures 1-4

Substrate Dependent Bonding of Chemisorbed 1,1’-Biphenyl-4,4’-Dimethanethiol

We compare the adsorption of 1,1’-biphenyl-4,4’-dimethanethiol (BPDMT) on gold and cobalt surfaces. The molecular orbitals, identified from combined photoemission and inverse photoemission studies, exhibit shifts in binding energies with different deposition methods and substrates. These shifts indicate that this potential molecular dielectric exhibits stronger bonding to cobalt surfaces than gold surfaces

The electronic structure of metal/alkane thiol self-assembled monolayers/metal junctions for magnetoelectronics applications

Long-chain alkane thiols use in metal to organic self-assembled monolayer to metal junctions may be limited by orientational disorder, and photoemission studies suggest that several molecular layers may be needed for the dielectric layer to be effective. Several alkane thiols were investigated in a range of junctions areas 10–102 μm2. Top layer contact deposition, activated with Pd clusters resulted in a high yield of junctions that were not electrically shorted and are stable over a wide temperature range. Zerobias anomalies, observed at low temperatures, are attributed to a Coulomb blockade associated with the Pd clusters

ELECTROCRYSTALLIZATION OF STRONGLY ADHERENT BRUSHITE COATINGS ON PROSTHETIC ALLOYS (continuation)

An electrolytic method for providing bone-emulating, phosphate coatings on prosthetic appliances. Such coatings serve to enhance bone furation after implantation of the appliances. The method of the invention is an electrolysis process wherein the appliance to be coated is immersed in a phosphate-containing electrolyte to serve as the cathode of the electrolysis process. When current is appIied to the electrolysis cell, the electrolyte solution, which includes calcium ions and dihydrogen phosphate ions, is caused to rapidly increase in (localized) pH proximate the cathode element. The localized pH increase creates a supersaturated local condition causing less soluble calcium phosphate salts to crystallize out of the electrolyte solution and adhere to the cathode, thus effecting thereon a coating of brushite. United States Patent Number 5,413,693 Continuation of Ser. No. 638,104, Jan. 4, 1991, Pat. No. 5,310,464

Electrolytic Deposition of Coatings for Prosthetic Metals and Alloys 2008

An article coated with an electrolytically deposited biocompatible composite layer useful as an internal prosthetic device is disclosed. The bio-compatible composite coating that is electrolytically deposited onto the article comprises hydroxyapatite and chitosan. The introduction of chitosan into the crystal matrix of brushite/hydroxyapatite significantly improves the adhesive and chemical and mechanical stability properties of the coating

ELECTROLYTIC DEPOSITION OF COATINGS FOR PROSTHETIC METALS AND ALLOYS

An article coated with an electrolytically deposited biocompatible composite layer useful as an internal prosthetic device is disclosed. The bio-compatible composite coating that is electrolytically deposited onto the article comprises hydroxyapatite and chitosan. The introduction of chitosan into the crystal matrix of brushite/hydroxyapatite significantly improves the adhesive and chemical and mechanical stability properties of the coating. United States Patent Number 7,014,749 B

\u3ci\u3eIn situ\u3c/i\u3e magnetoresistance of Ni nanocontacts

Magnetoresistance properties of Ni nanocontacts in the ballistic quantum regime are investigated in situ during closure and opening of electrochemically grown planar electrodes. The magnitude of conductance change when sweeping the magnetic field is of the order of the quantum conductance e2/h for conductance values spanning 1–100 quanta. The relative orientation of electric current and applied magnetic field changes the magnetoresistance sign, with symmetry properties reminiscent of bulk anisotropy magnetoresistance. Ex situ investigations of samples of higher conductance values, of the order of 1000 quanta, unambiguously show the analogy with bulk anisotropy magnetoresistance