Visualization of defect-induced excitonic properties of the edges and grain boundaries in synthesized monolayer molybdenum disulfide

Atomically thin two-dimensional (2D) transition metal dichalcogenides (TMDCs) are attractive materials for next generation nanoscale optoelectronic applications. Understanding nanoscale optical behavior of the edges and grain boundaries of synthetically grown TMDCs is vital for optimizing their optoelectronic properties. Elucidating the nanoscale optical properties of 2D materials through far-field optical microscopy requires a diffraction-limited optical beam diameter sub-micron in size. Here we present our experimental work on spatial photoluminescence (PL) scanning of large size ( $\geq 50$ microns) monolayer MoS$_2$ grown by chemical vapor deposition (CVD) using a diffraction limited blue laser beam spot (wavelength 405 nm) with a beam diameter as small as 200 nm allowing us to probe nanoscale excitonic phenomena which was not observed before. We have found several important features: (i) there exists a sub-micron width strip ($\sim 500$ nm) along the edges that fluoresces $\sim 1000 \%$ brighter than the region far inside; (ii) there is another brighter wide region consisting of parallel fluorescing lines ending at the corners of the zig-zag peripheral edges; (iii) there is a giant blue shifted A-excitonic peak, as large as $\sim 120$ meV, in the PL spectra from the edges. Using density functional theory calculations, we attribute this giant blue shift to the adsorption of oxygen dimers at the edges, which reduces the excitonic binding energy. Our results not only shed light on defect-induced excitonic properties, but also offer an attractive route to tailor optical properties at the TMDC edges through defect engineering.Comment: 10 pages, 4 figures in Journal of Physical Chemistry C, 201

Electron Capture at Very Small Scattering Angles from Atomic Hydrogen by 25-125-keV Protons

Differential cross sections for electron capture in collisions between protons and hydrogen atoms have been experimentally determined for incident proton energies of 25, 60, and 125 keV in the center-of-mass scattering-angle range of 0-3 mrad. The experimental results compare more favorably with the results of both a multistate and a two-state calculation than with the results of a continuum distorted-wave-approximation calculation. There is no evidence of a Jackson-Schiff-type minimum

Elastic angular differential cross sections for quasi-oneelectron collision systems at intermediate energies: (Na\u3csup\u3e+\u3c/sup\u3e, Li\u3csup\u3e+\u3c/sup\u3e)+H and (Mg\u3csup\u3e+\u3c/sup\u3e, Be\u3csup\u3e+\u3c/sup\u3e)+He

Measurements of elastic angular differential cross sections have been carried out for four quasi-one-electron collision systems at intermediate energies. Data are presented for Na++H collisions at laboratory energies of 35.94, 51.75, 63.89, and 143.75 keV, for Li++H collisions at energies of 19.44 and 43.75 keV, for Mg++He collisions at energies of 30, 66.7, and 150 keV, and for Be++He collisions at an energy of 56.25 keV. The highest energy in each case corresponds to a projectile velocity of (1/2 a.u. Born and Eikonal calculations, in which we model the projectile ion as a heavy structureless ion of charge +1e, are also presented. Our model calculations are in fair agreement with the experimental data over the range of measured scattering angles

Momentum-Transfer Scaling in Hydrogen-Isotope Collision Systems

The differential cross sections for excitation of atomic hydrogen isotopes to their n=2 states by proton or deutron impact are found to follow a simple scaling relationship. The momentum-transfer-scaled differential excitation cross sections, for a projectile velocity of 1.26 a.u., produce one differential cross-section curve for all four possible hydrogen-isotope collision systems. The experimental results are in excellent agreement with our Glauber-approximation calculations

A Polynesian Motif on the Y Chromosome: Population Structure in Remote Oceania

This is the publisher's version, also available electronically from http://digitalcommons.wayne.edu/humbiol/vol79/iss5/5/.The Polynesian motif, a mitochondrial DNA marker of ancestral Polynesian communities, has filled a critical role in reconstructions of remote Oceanic history. Although the motif provides an effective narrative for Polynesian females, no equivalent male history is available from paternal lineages. Here, we describe a Y-chromosome binary polymorphism with absolute Polynesian affinity. We illustrate its unique spatial and temporal connections to early Polynesian communities, and through an analysis of associated short tandem repeat variation, we describe the first clear genealogic structure within Polynesia. Unlike the eastern and western regions advocated by archeology, we identify a tripartite structure comprising interaction spheres in the west (Tonga and Samoa), center (Tahiti), and east (Rapanui/Easter Island). Such patterning, a product of early regional contact and subsequent isolation, signals the conflicting roles of mobility and seclusion in Polynesian prehistory

Isotope Effect and Momentum-Transfer Scaling in the Elastic-Scattering Differential Cross Sections for Hydrogen-Isotope Collision Systems

A projectile-dependent isotope effect was found for the elastic-scattering differential cross sections in the hydrogen-isotope collision systems. All four differential cross sections lie on a common curve if they are divided by the square of the reduced mass and plotted against momentum transfer. The experimental results are in satisfactory agreement with a simple Glauber-approximation calculation

Hierarchical Patterns of Global Human Y-Chromosome Diversity

We examined 43 biallelic polymorphisms on the nonrecombining portion of the Y chromosome (NRY) in 50 human populations encompassing a total of 2,858 males to study the geographic structure of Y-chromosome variation. Patterns of NRY diversity varied according to geographic region and method/level of comparison. For example, populations from Central Asia had the highest levels of heterozygosity, while African populations exhibited a higher level of mean pairwise differences among haplotypes. At the global level, 36% of the total variance of NRY haplotypes was attributable to differences among populations (i.e., Phi(ST) = 0.36). When a series of AMOVA analyses was performed on different groupings of the 50 populations, high levels of among-groups variance (Phi(CT)) were found between Africans, Native Americans, and a single group containing all 36 remaining populations. The same three population groupings formed distinct clusters in multidimensional scaling plots. A nested cladistic analysis (NCA) demonstrated that both population structure processes (recurrent gene flow restricted by isolation by distance and long-distance dispersals) and population history events (contiguous range expansions and long-distance colonizations) were instrumental in explaining this tripartite division of global NRY diversity. As in our previous analyses of smaller NRY data sets, the NCA detected a global contiguous range expansion out of Africa at the level of the total cladogram. Our new results support a general scenario in which, after an early out-of-Africa range expansion, global-scale patterns of NRY variation were mainly influenced by migrations out of Asia. Two other notable findings of the NCA were (1) Europe as a "receiver" of intercontinental signals primarily from Asia, and (2) the large number of intracontinental signals within Africa. Our AMOVA analyses also supported the hypothesis that patrilocality effects are evident at local and regional scales, rather than at intercontinental and global levels. Finally, our results underscore the importance of subdivision of the human paternal gene pool and imply that caution should be exercised when using models and experimental strategies based on the assumption of panmixia

Isotope Effect in Electron-Capture Differential Cross Sections at Intermediate Energies

The isotope dependence in the angular distribution of electron-capture cross sections for protons and deuterons with equal velocity (E=40 keV/u) colliding with atomic hydrogen or deuterium targets is predicted theoretically and observed experimentally. A projectile-dependent effect is observed at small scattering angles. No target dependence was detected in the differential cross sections. A scaling relationship is determined which permits the prediction of differential cross sections for hydrogen-isotope projectiles

Angular Differential and Total Cross Sections for the Excitation of Atomic Hydrogen to Its n=2 State by Helium Ions

Differential cross sections for 15-100 keV He+ excitation of atomic hydrogen to its n=2 level have been determined for c.m. angles from 0 to 8 mrad. The differential cross sections are obtained from an analysis of the angular distribution of the scattered ions which have lost an energy corresponding to the excitation of the target to its n=2 level. The shape of the differential cross section changes rapidly with increasing incident energy. At 15 keV, the differential cross section falls off by a factor of 5 in 6 mrad. At 100 keV, the differential cross section decreases by nearly six orders of magnitude in the same angular range. The higher-energy results are in fair agreement with a recent symmetrized first-order Glauber approximation calculation of the process. Total cross section results are given for the same process in the 15-200 keV range

Live imaging of wound inflammation in Drosophila embryos reveals key roles for small GTPases during in vivo cell migration

Aa robust inflammatory response to tissue damage and infection is conserved across almost all animal phyla. Neutrophils and macrophages, or their equivalents, are drawn to the wound site where they engulf cell and matrix debris and release signals that direct components of the repair process. This orchestrated cell migration is clinically important, and yet, to date, leukocyte chemotaxis has largely been studied in vitro. Here, we describe a genetically tractable in vivo wound model of inflammation in the Drosophila melanogaster embryo that is amenable to cinemicroscopy. For the first time, we are able to examine the roles of Rho-family small GTPases during inflammation in vivo and show that Rac-mediated lamellae are essential for hemocyte motility and Rho signaling is necessary for cells to retract from sites of matrix– and cell–cell contacts. Cdc42 is necessary for maintaining cellular polarity and yet, despite in vitro evidence, is dispensable for sensing and crawling toward wound cues