1,678 research outputs found
Ground state of Li and Be using explicitly correlated functions
We compare the explicitly correlated Hylleraas and exponential basis sets in
the evaluations of ground state of Li and Be. Calculations with Hylleraas
functions are numerically stable and can be performed with the large number of
basis functions. Our results for ground state energies , of Li and Be correspondingly, are the
most accurate to date. When small basis set is considered, explicitly
correlated exponential functions are much more effective. With only 128
functions we obtained about relative accuracy, but the severe
numerical instabilities make this basis costly in the evaluation.Comment: 15 page
Angular momentum spatial distribution symmetry breaking in Rb by an external magnetic field
Excited state angular momentum alignment -- orientation conversion for atoms
with hyperfine structure in presence of an external magnetic field is
investigated. Transversal orientation in these conditions is reported for the
first time. This phenomenon occurs under Paschen Back conditions at
intermediate magnetic field strength. Weak radiation from a linearly polarized
diode laser is used to excite Rb atoms in a cell. The laser beam is polarized
at an angle of pi/4 with respect to the external magnetic field direction.
Ground state hyperfine levels of the 5S_1/2 state are resolved using
laser-induced fluorescence spectroscopy under conditions for which all excited
5P_3/2 state hyperfine components are excited simultaneously. Circularly
polarized fluorescence is observed to be emitted in the direction perpendicular
to both to the direction of the magnetic field B and direction of the light
polarization E. The obtained circularity is shown to be in quantitative
agreement with theoretical predictions.Comment: Accepted for publication in Phys. Rev.
Liquid–liquid phase separation of the Golgi matrix protein GM130
Golgins are an abundant class of peripheral membrane proteins of the Golgi. These very long (50–400 nm) rod-like proteins initially capture cognate transport vesicles, thus enabling subsequent SNARE-mediated membrane fusion. Here, we explore the hypothesis that in addition to serving as vesicle tethers, Golgins may also possess the capacity to phase separate and, thereby, contribute to the internal organization of the Golgi. GM130 is the most abundant Golgin at the cis Golgi. Remarkably, overexpressed GM130 forms liquid droplets in cells analogous to those described for numerous intrinsically disordered proteins with low complexity sequences, even though GM130 is neither low in complexity nor intrinsically disordered. Virtually pure recombinant GM130 also phase-separates into dynamic, liquid-like droplets in close to physiological buffers and at concentrations similar to its estimated local concentration at the cis Golgi
Interferometric signatures of single molecules
We built an, interferometer where one of the two slits of a classical Young's setup is replaced by a single molecule embedded in a solid matrix. This enabled direct measurement of the first order coherence of the 0-0 single-molecule emission, which at high excitation powers proves to be split in coherent and incoherent parts. We demonstrate an order of magnitude higher precision in axial localization of single molecules in comparison with that of confocal microscopy. These experiments open a possibility for single-molecule holography. Detection of single molecules with low luminescence quantum yields could be another application of this technique
Imprints of management history on hemiboreal forest ecosystems in the Baltic States
In the Baltic States region, anthropogenic disturbances at different temporal and spatial scales mostly determine dynamics and development phases of forest ecosystems. We reviewed the state and condition of hemiboreal forests of the Baltic States region and analyzed species composition of recently established and permanent forest (PF). Agricultural deforestation and spontaneous or artificial conversion back to forest is a scenario leading to ecosystems designated as recent forest (RF, age up to two hundred years). Permanent forest (PF) was defined as areas with no records of agricultural activity during the last 200 yr, including mostly forests managed by traditional even-aged (clear-cut) silviculture and salvage after natural disturbances. We hypothesized that RF would have distinctive composition, with higher dominance by hardwoods (e.g., aspen and birch), compared to PF. Ordination revealed divergence in the RF stands; about half had the hypothesized composition distinct from PF, with a tight cluster of stands in the part of the ordination space with high hardwood dominance, while the remaining RF stands were scattered throughout the ordination space occupied by PF with highly variable species composition. Planting of conifers, variability in site quality, and variability in spatial proximity to PF with relatively natural ecosystem legacies likely explained the variable compositions of this latter group of RF. We positioned the observations of RF in a classic quantification of site type conditions (based on Estonian forest vegetation survey previously carried out by LA mu hmus), which indicated that RF was more likely to occur on areas of higher soil fertility (in ordination space). Climatic and anthropogenic changes to RF create complex dynamic trends that are difficult to project into the future. Further research in tracing land use changes (using pollen analysis and documented evidence) should be utilized to refine the conceptual framework of ecosystem legacy and memory. Occurrence and frequency of deforestation and its characteristics as a novel disturbance regime are of particular interest.Peer reviewe
On the Theory of Vibronic Superradiance
The Dicke superradiance on vibronic transitions of impurity crystals is
considered. It is shown that parameters of the superradiance (duration and
intensity of the superradiance pulse and delay times) on each vibronic
transition depend on the strength of coupling of electronic states with the
intramolecular impurity vibration (responsible for the vibronic structure of
the optical spectrum in the form of vibrational replicas of the pure electronic
line) and on the crystal temperature through the Debye-Waller factor of the
lattice vibrations. Theoretical estimates of the ratios of the time delays, as
well as of the superradiance pulse intensities for different vibronic
transitions well agree with the results of experimental observations of
two-color superradiance in the polar dielectric KCl:O2-. In addition, the
theory describes qualitatively correctly the critical temperature dependence of
the superradiance effect.Comment: 8 pages, 1 figur
The feasibility of existing JADAS10 cut-off values in clinical practice: a study of data from The Finnish Rheumatology Quality Register
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