3,890 research outputs found
Comparative Assessment of the Factors and Conditions of the Formation of the Neoindustrial Social State in Russia and Germany
Russia and Germany are traditionally reputed as countries with socially oriented economies. Namely, these countries are also close by the index of the share of real sector of economy at GDP. And however, Germany is a founder of social market household largely defined its leadership in world economy, in current conditions of crisis of “the state of general welfare” the search of a new model of development for Germany is also important as for Russia stood on the way of modernization and neo-industrialization. In the article, the hypothesis about forming of the new model of development uniting the social orientation of economy, processes of neoindustrialization, and globalization is made. At the same time, the social orientation is the main aim of socio-economic development, neo-industrialization is a way to achieve it, and globalization is a criterion presupposing more effective use of resources. Theoretical backgrounds of development of “social state” are generalized in the works of German and Russian classics put the backgrounds of economic humanism, it has allowed to prove the fatality of modernization process without considering of deep mental backgrounds and civilization codes of the nation development. The methodological approaches to development of a new model of neo-industrial social state with emphasizing different levels: global, national, local, individual are worked out; and the technique for estimation of factors and conditions of its development is proposed. The technique is tested on the example of Russia and Germany. The comparative analysis conducted has allowed to make the conclusion about similarity of target guidelines, initial conditions, problems and ways of their solving in these countries, that is to be considered both in a strategy and a policy of socio-economic development of these countries and by their international partnership
Evolution of vacancy pores in bounded particles
In the present work, the behavior of vacancy pore inside of spherical
particle is investigated. On the assumption of quasistationarity of diffusion
fluxes, the nonlinear equation set was obtained analytically, that describes
completely pore behavior inside of spherical particle. Limiting cases of small
and large pores are considered. The comparison of numerical results with
asymptotic behavior of considered limiting cases of small and large pores is
discussed.Comment: 25 pages, 10 figure
Cation Transport in Polymer Electrolytes: A Microscopic Approach
A microscopic theory for cation diffusion in polymer electrolytes is
presented. Based on a thorough analysis of molecular dynamics simulations on
PEO with LiBF the mechanisms of cation dynamics are characterised. Cation
jumps between polymer chains can be identified as renewal processes. This
allows us to obtain an explicit expression for the lithium ion diffusion
constant D_{Li} by invoking polymer specific properties such as the Rouse
dynamics. This extends previous phenomenological and numerical approaches. In
particular, the chain length dependence of D_{Li} can be predicted and compared
with experimental data. This dependence can be fully understood without
referring to entanglement effects.Comment: 4 pages, 4 figures, Physical Review Letters in pres
Imaging of fuel mixture fraction oscillations in a driven system using acetone PLIF
Measurements of fuel mixture fraction are made for a jet flame in an acoustic chamber. Acoustic forcing creates a
spatially-uniform, temporally-varying pressure field which results in oscillatory behavior in the flame . Forcing is at 22,27, 32, 37, and 55 Hz. To asses the oscillatory behavior, previous work included chemiluminescence, OH PUF, nitric oxide PUF imaging, and fuel mixture fraction measurements by infrared laser absorption. While these results illuminated what was happening to the flame chemistry, they did not provide a complete explanation as to why these things were happening. In this work, the fuel mixture fraction is measured through PUF of acetone, which is introduced into the fuel stream as a marker. This technique enables a high degree of spatial resolution of fuel/air mixture value. Both non-reacting and reacting cases were measured and comparisons are drawn with the results from the previous work. It is found that structure in the mixture fraction oscillations is a major contributor to the magnitude of the flame oscillations
Ion and polymer dynamics in polymer electrolytes PPO-LiClO4: II. 2H and 7Li NMR stimulated-echo experiment
We use 2H NMR stimulated-echo spectroscopy to measure two-time correlation
functions characterizing the polymer segmental motion in polymer electrolytes
PPO-LiClO4 near the glass transition temperature Tg. To investigate effects of
the salt on the polymer dynamics, we compare results for different ether oxygen
to lithium ratios, namely, 6:1, 15:1, 30:1 and infinity. For all compositions,
we find nonexponential correlation functions, which can be described by a
Kohlrausch function. The mean correlation times show quantitatively that an
increase of the salt concentration results in a strong slowing down of the
segmental motion. Consistently, for the high 6:1 salt concentration, a high
apparent activation energy E_a=4.1eV characterizes the temperature dependence
of the mean correlation times at Tg < T< 1.1T_g, while smaller values E_a=2.5eV
are observed for moderate salt contents. The correlation functions are most
nonexponential for 15:1 PPO-LiClO4, whereas the stretching is reduced for
higher and lower salt concentrations. A similar dependence of the correlation
functions on the evolution time in the presence and in the absence of ions
indicates that addition of salt hardly affects the reorientational mechanism.
For all compositions, mean jump angles of about 15 degree characterize the
segmental reorientation. In addition, comparison of results from 2H and 7Li NMR
stimulated-echo experiments suggests a coupling of ion and polymer dynamics in
15:1 PPO-LiClO4.Comment: 14 pages, 12 figure
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