23,449 research outputs found
Influence of temperature and the role of chromium on the kinetics of sulfidation of 310 stainless steel
The sulfidation of 310 stainless steel was studied over the temperature range from 910 K to 1285 K. By adjusting the ratio of hydrogen sulfide, variations in sulfur potential were obtained. The effect of temperature on sulfidation was determined at three different sulfur potentials: 39/sqNm, 0.014/sqNm, and 0.00015/sqNm. All sulfide scales contained one or two surface layers in addition to a subscale. The second outer layer (OL-II), furthest from the alloy, contained primarily Fe-Ni-S. The first outer layer (OL-I), nearest the subscale, contained FE-Cr-S. The subscale consisted of sulfide inclusions in the metal matrix. At a given temperature and sulfur potential, the weight gain data obeyed the parabolic rate law after an initial transient period. The parabolic rate constants obtained at the sulfur potential of 39/sqNm did not show a break when the logarithm of the rate constant was plotted as a function of the inverse of absolute temperature. Sulfidation carried out at sulfur potentials below 0.02/sqNm, however, did show a break at 1145 K, which is termed as the transition temperature. This break was found to be associated with the changes which had occurred in the Fe:Cr ratio of OL-I. Below the transition temperature the activation energy was found to be approximately 125 kj/mole. Above the transition temperature the rate of sulfidation decreased with temperature but dependent on the Fe:Cr ratio in the iron-chromium-sulfide layers of the OL-I. A reaction mechanism consistent with the experimental results has been proposed
Sulfidation of 310 stainless steel at sulfur potentials encountered in coal conversion systems
The sulfidation of SAE 310 stainless steel was carried out in gas mixtures of hydrogen and hydrogen sulfide over a range of sulfur potentials anticipated in advanced coal gasification processes. The kinetics, composition, and morphology of sulfide scale formation were studied at a fixed temperature of 1,065 K over a range of sulfur potentials from .00015 Nm to the -2nd power to 900 Nm to the -2nd power. At all sulfur potentials investigated, the sulfide scales were found to be multilayered. The relative thickness of the individual layers as well as the composition was found to depend on the sulfur potential. The reaction was found to obey the parabolic rate law after an initial transient period. Considerably longer transient periods were found to be due to unsteady state conditions resulting from compositional variations in the spinel layer. The sulfur pressure dependence on the parabolic rate constant was found to best fit the equation K sub p equals const. (P sub S2) to the 1/nth power, where n equals 3.7. The growth of the outer layers was found to be primarily due to the diffusion of metal ions, iron being the predominant species. The inner layer growth was due to the dissociation of the primary product at the alloy scale interface and depended on the activity of chromium
Some studies on a solid state sulfur probe for coal gasification systems
Measurements on the solid electrolyte cell (Ar + H(2) + H(2)S/CaS + CaF(2) + (Pt)//CaF(2)//(Pt) + CaF(2) + CaS/H(2) + H(2)+Ar) show that the emf of the cell is directly related to the difference in sulfur potentials established at the Ar + H(2) + H(2)S/electrode interfaces. The electrodes convert the sulfur potential gradient across the calcium fluoride electrolyte into an equivalent fluorine potential gradient. Response time of the probe varies from approximately 9 hr at 990 K to 2.5 hr at 1225 K. The conversion of calcium sulfide and/or calcium fluoride into calcium oxide is not a problem anticipated in commercial coal gasification systems. Suggestions are presented for improving the cell for such commercial applications
Corrosion of 310 stainless steel in H2-H2O-H2S gas mixtures: Studies at constant temperature and fixed oxygen potential
Corrosion of SAE 310 stainless steel in H2-H2O-H2S gas mixtures was studied at a constant temperature of 1150 K. Reactive gas mixtures were chosen to yield a constant oxygen potential of approximately 6 x 10 to the minus 13th power/cu Nm and sulfur potentials ranging from 0.19 x 10 to the minus 2nd power/cu Nm to 33 x 10 to the minus 2nd power/cu Nm. The kinetics of corrosion were determined using a thermobalance, and the scales were analyzed using metallography, scanning electron microscopy, and energy dispersive X-ray analysis. Two corrosion regimes, which were dependent on sulfur potential, were identified. At high sulfur potentials (p sub S sub 2 less than or equal to 2.7 x 10 to the minus 2nd power/cu Nm) the corrosion rates were high, the kinetics obeyed a linear rate equation, and the scales consisted mainly of sulfide phases similar to those observed from pure sulfication. At low sulfur potentials (P sub S sub 2 less than or equal to 0.19 x 10 to the minus 2nd power/cu Nm) the corrosion rates were low, the kinetics obeyed a parabolic rate equation, and scales consisted mainly of oxide phases
Stability of chromium (III) sulfate in atmospheres containing oxygen and sulfur
The stability of chromium sulfate in the temperature range from 880 K to 1040 K was determined by employing a dynamic gas-solid equilibration technique. The solid chromium sulfate was equilibrated in a gas stream of controlled SO3 potential. Thermogravimetric and differential thermal analyses were used to follow the decomposition of chromium sulfate. X-ray diffraction analysis indicated that the decomposition product was crystalline Cr2O3 and that the mutual solubility between Cr2(SO4)3 and Cr2O3 was negligible. Over the temperature range investigated, the decomposition pressure were significantly high so that chromium sulfate is not expected to form on commercial alloys containing chromium when exposed to gaseous environments containing oxygen and sulfur (such as those encountered in coal gasification)
Phase relations in the Fe-Ni-Cr-S system and the sulfidation of an austenitic stainless steel
The stability fields of various sulfide phases that form on Fe-Cr, Fe-Ni, Ni-Cr and Fe-Cr-Ni alloys were developed as a function of temperature and the partial pressure of sulfur. The calculated stability fields in the ternary system were displayed on plots of log P sub S sub 2 versus the conjugate extensive variable which provides a better framework for following the sulfidation of Fe-Cr-Ni alloys at high temperatures. Experimental and estimated thermodynamic data were used in developing the sulfur potential diagrams. Current models and correlations were employed to estimate the unknown thermodynamic behavior of solid solutions of sulfides and to supplement the incomplete phase diagram data of geophysical literature. These constructed stability field diagrams were in excellent agreement with the sulfide phases and compositions determined during a sulfidation experiment
On the stranding of the common dolphin, Delphinus delphis at Murud Janjira
A dead male dolphin, Delphinus delphis, locally called
'Gadda' measuring 305 cm in total length was
washed ashore in the early hours of 20 - 3 - '97 at the
sea shore of Murud Janjir
On the unusual landings of lobster, Panulirus polyphagus at Borli Mandla, Raigad District, Maharashtra
The fishery for lobsters locally called shevandi confined
to the Borli Mandla centre, 26 km north of Janjiramurud
Is usually caught during August-March
every year. The present report pertains to the unusual
fishery of the lobster, Panulirus polyphagus landed at
this centre during 4th to 13th August, 1997. On
4-8-'97 and 5-8-'97 very high catch of 20-35 kg per
unit could be observed but reduced to 10-15 kg on subsequent
days with increase in the number of unit
operations
Shear flow induced isotropic to nematic transition in a suspension of active filaments
We study the effects of externally applied shear flow on a model of
suspensions of motors and filaments, via the equations of active hydrodynamics
[PRL {\bf 89} (2002) 058101; {\bf 92} (2004) 118101]. In the absence of shear,
the orientationally ordered phase of {\it both} polar and apolar active
particles is always unstable at zero-wavenumber. An imposed steady shear large
enough to overcome the active stresses stabilises both apolar and moving polar
phases. Our work is relevant to {\it in vitro} studies of active filaments, the
reorientation of endothelial cells subject to shear flow and shear-induced
motility of attached cells.Comment: 8 pages, 4 figures submitted to Europhysics Letter
The eigenspectra of Indian musical drums
In a family of drums used in the Indian subcontinent, the circular drum head
is made of material of non-uniform density. Remarkably, and in contrast to a
circular membrane of uniform density, the low eigenmodes of the non-uniform
membrane are harmonic. In this work we model the drum head by a non-uniform
membrane whose density varies smoothly between two prescribed values. Using a
Fourier-Chebyshev spectral collocation method we obtain the eigenmodes and
eigenvalues of the drum head. For a suitable choice of parameters, which we
find by optimising a cost function, the eigenspectra obtained from our model
are in excellent agreement with experimental values. Our model and the
numerical method should find application in numerical sound synthesis
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