Rapid Determination of Copper in Copper Ores

Low grade copper ores and copper ores in association with considerable quantities of other elements such as iron, lead, zinc and vanadium require a separational step wherein copper is generally seperated as sulphide either with sodium thiosulfate or with thiocetamide. In these methods the precipitated copper sulfide is ignited to cupric oxide, dissolved in dilute nitric acid and titrated idometrically. In a recent methorl wet oxidation of precipitated copper sulfide is effected with nitric acid ,and perchloric acid and titrated with disodium ethylene diamine tetraacetate (EDTA). The authors' work on the beneficiation of low grade copper ores. and extraction of copper, from these ores has necessitated developing a rapid and accurate method for the determination of copper. A separational step wherein cupric ion could be preci-pitated as cuprous oxide has been introduced to avoid ignition of copper sulfide to cupric oxide, which is time consuming

The local power of the gradient test

The asymptotic expansion of the distribution of the gradient test statistic is derived for a composite hypothesis under a sequence of Pitman alternative hypotheses converging to the null hypothesis at rate $n^{-1/2}$, $n$ being the sample size. Comparisons of the local powers of the gradient, likelihood ratio, Wald and score tests reveal no uniform superiority property. The power performance of all four criteria in one-parameter exponential family is examined.Comment: To appear in the Annals of the Institute of Statistical Mathematics, this http://www.ism.ac.jp/editsec/aism-e.htm

Diffuse Neutron Scattering Study of Magnetic Correlations in half-doped La0.5Ca0.5-xSrxMnO3 (x = 0.1, 0.3 and 0.4) Manganites

The short range ordered magnetic correlations have been studied in half doped La0.5Ca0.5-xSrxMnO3 (x = 0.1, 0.3 and 0.4) compounds by polarized neutron scattering technique. On doping Sr2+ for Ca2+ ion, these compounds with x = 0.1, 0.3, and 0.4 exhibit CE-type, mixture of CE-type and A-type, and A-type antiferromagnetic ordering, respectively. Magnetic diffuse scattering is observed in all the compounds above and below their respective magnetic ordering temperatures and is attributed to magnetic polarons. The correlations are primarily ferromagnetic in nature above T\_N, although a small antiferromagnetic contribution is also evident. Additionally, in samples x = 0.1 and 0.3 with CE-type antiferromagnetic ordering, superlattice diffuse reflections are observed indicating correlations between magnetic polarons. On lowering temperature below T\_N the diffuse scattering corresponding to ferromagnetic correlations is suppressed and the long range ordered antiferromagnetic state is established. However, the short range ordered correlations indicated by enhanced spin flip scattering at low Q coexist with long range ordered state down to 3K. In x = 0.4 sample with A-type antiferromagnetic ordering, superlattice diffuse reflections are absent. Additionally, in comparison to x = 0.1 and 0.3 sample, the enhanced spin flip scattering at low Q is reduced at 310K, and as temperature is reduced below 200K, it becomes negligibly low. The variation of radial correlation function, g(r) with temperature indicates rapid suppression of ferromagnetic correlations at the first nearest neighbor on approaching TN. Sample x = 0.4 exhibits growth of ferromagnetic phase at intermediate temperatures (~ 200K). This has been further explored using SANS and neutron depolarization techniques.Comment: 13 pages, 12 figures, To appear in Physical Review

Spin Decoherence from Hamiltonian dynamics in Quantum Dots

The dynamics of a spin-1/2 particle coupled to a nuclear spin bath through an isotropic Heisenberg interaction is studied, as a model for the spin decoherence in quantum dots. The time-dependent polarization of the central spin is calculated as a function of the bath-spin distribution and the polarizations of the initial bath state. For short times, the polarization of the central spin shows a gaussian decay, and at later times it revives displaying nonmonotonic time dependence. The decoherence time scale dep ends on moments of the bath-spin distribuition, and also on the polarization strengths in various bath-spin channels. The bath polarizations have a tendency to increase the decoherence time scale. The effective dynamics of the central spin polarization is shown to be describ ed by a master equation with non-markovian features.Comment: 11 pages, 6 figures Accepted for publication in Phys.Rev

Cavitation Effects on the Stability of a Submerged Journal Bearing

A computational procedure for the mechanism of shear between the liquid sublayer and air cavity in the cavitation zone of a submerged journal bearing is presented here. Using the mass conservation principle, Elrod's universal equation is modified to take into consideration the shear of the air cavity in the cavitation region. Results of steady state and transient response for the submerged journal bearing using the present approach are compared with the universal equation based on the striated flow in the cavitation region. At steady state, the angular extent of cavitation region predicted by the present approach is higher than that predicted by Elrod's model and the limit cycle journal transient response using the present approach predicts higher eccentricity ratios

Shear flow induced isotropic to nematic transition in a suspension of active filaments

We study the effects of externally applied shear flow on a model of suspensions of motors and filaments, via the equations of active hydrodynamics [PRL {\bf 89} (2002) 058101; {\bf 92} (2004) 118101]. In the absence of shear, the orientationally ordered phase of {\it both} polar and apolar active particles is always unstable at zero-wavenumber. An imposed steady shear large enough to overcome the active stresses stabilises both apolar and moving polar phases. Our work is relevant to {\it in vitro} studies of active filaments, the reorientation of endothelial cells subject to shear flow and shear-induced motility of attached cells.Comment: 8 pages, 4 figures submitted to Europhysics Letter

Characteristics of light charged particle emission in the ternary fission of 250Cf and 252Cf at different excitation energies

The emission probabilities and the energy distributions of tritons, α and ^6He particles emitted in the spontaneous ternary fission (zero excitation energy) of ^250Cf and ^252Cf and in the cold neutron induced fission (excitation energy ≈ 6.5 MeV) of ^249Cf and 251Cf are determined. The particle identification was done with suited ΔE-E telescope detectors, at the IRMM (Geel, Belgium) for the spontaneous fission and at the ILL (Grenoble, France) for the neutron induced fission measurements. Hence particle emission characteristics of the fissioning systems ^250Cf and ^252Cf are obtained at zero and at about 6.5 MeV excitation energies. While the triton emission probability is hardly influenced by the excitation energy, the ^4He and ^6He emission probability in spontaneous fission is higher than for neutron induced fission. This can be explained by the strong influence of the cluster preformation probability on the ternary particle emission probability

Magnetic and electron transport properties of the rare-earth cobaltates, La0.7-xLnxCa0.3CoO3 (Ln = Pr, Nd, Gd and Dy) : A case of phase separation

Magnetic and electrical properties of four series of rare earth cobaltates of the formula La0.7-xLnxCa0.3CoO3 with Ln = Pr, Nd, Gd and Dy have been investigated. Compositions close to x = 0.0 contain large ferromagnetic clusters or domains, and show Brillouin-like behaviour of the field-cooled DC magnetization data with fairly high ferromagnetic Tc values, besides low electrical resistivities with near-zero temperature coefficients. The zero-field-cooled data generally show a non-monotonic behaviour with a peak at a temperatures slightly lower than Tc. The near x = 0.0 compositions show a prominent peak corresponding to the Tc in the AC-susceptibility data. The ferromagnetic Tc varies linearly with x or the average radius of the A-site cations, (rA). With increase in x or decrease in (rA), the magnetization value at any given temperature decreases markedly and the AC-susceptibility measurements show a prominent transition arising from small magnetic clusters with some characteristics of a spin-glass. Electrical resistivity increases with increase in x, showed a significant increase around a critical value of x or (rA), at which composition the small clusters also begin to dominate. These properties can be understood in terms of a phase separation scenario wherein large magnetic clusters give way to smaller ones with increase in x, with both types of clusters being present in certain compositions. The changes in magnetic and electrical properties occur parallely since the large ferromagnetic clusters are hole-rich and the small clusters are hole-poor. Variable-range hopping seems to occur at low temperatures in these cobaltates.Comment: 23 pages including figure