Maximum Height to Width Ratio of Freestanding Structures Built Using Ultrasonic Consolidation

Ultrasonic consolidation (UC) is a process whereby metal foils can be metallurgically bonded at or near room temperature. The UC process works by inducing high-speed differential motion (~20kHz) between a newly deposited layer and a substrate (which consists of a base plate and any previously deposited layers of material). This differential motion causes plastic deformation at the interface, which breaks up surface oxides and deforms surface asperities, bringing clean metal surfaces into intimate contact, where bonding occurs. If the substrate is not stiff enough to resist deflection during ultrasonic excitation of newly deposited layers, then it deflects along with the newly deposited layer, resulting in no differential motion and lack of bonding. Geometric issues which control substrate stiffness and deflection were investigated at Utah State University by building a number of free-standing rib structures with varying dimensions and orientations. Each structure was built to a height where lack of bonding between the previously deposited layers and the newly deposited layer caused the building process to fail, a height to width ratio (H/W) of approximately 1:1. The parts were then cut, polished, and viewed under a microscope. An ANSYS model was created to investigate analytically the cause of this failure. It appears build failure is due to excessive deflection of the ribs around a 1:1 H/W, resulting in insufficient differential motion and deformation to achieve bonding. Preliminary results show, when the H/W reaches 1:1, the von Mises stress is found to be tensile along portions of the bonding interface, which eliminates the compressive frictional forces necessary for plastic deformation and formation of a metallurgical bond. These tensile stresses are shown to be concentrated at regions near the edges of the newly deposited foil layer.Mechanical Engineerin

Fluids of hard ellipsoids: Phase diagram including a nematic instability from Percus-Yevick theory

An important aspect of molecular fluids is the relation between orientation and translation parts of the two-particle correlations. Especially the detailed knowledge of the influence of orientation correlations is needed to explain and calculate in detail the occurrence of a nematic phase. The simplest model system which shows both orientation and translation correlations is a system of hard ellipsoids. We investigate an isotropic fluid formed of hard ellipsoids with Percus-Yevick theory. Solving the Percus-Yevick equations self-consistently in the high density regime gives a clear criterion for a nematic instability. We calculate in detail the equilibrium phase diagram for a fluid of hard ellipsoids of revolution. Our results compare well with Monte Carlo Simulations and density functional theory.Comment: 7 pages including 4 figure

Influence of protein concentration and coagulation temperature on rennet-induced gelation characteristics and curd microstructure

peer-reviewedThis study characterized the coagulation properties and defined the cutting window (CW; time between storage modulus values of 35 and 70 Pa) using rheometry for milk standardized to 4, 5, or 6% protein and set at 28, 32, or 36°C. Milks were standardized to a protein-to-fat ratio of approximately 1 by blending ultrafiltration retentate, skim milk, and whole milk. The internal curd microstructure for selected curd samples was analyzed with transmission electron microscopy and scanning electron microscopy. Lowering the coagulation temperature caused longer rennet coagulation time and time to reach storage modulus of 35 Pa, translating into a wider CW. It also led to a lower maximum curd-firming rate (MCFR) with lower firmness at 40 min at a given protein level. Increasing protein levels resulted in the opposite effect, although without an effect on rennet coagulation time at a given temperature. On coagulation at 28°C, milk with 5% protein resulted in a similar MCFR (∼4 Pa/min) and CW (∼8.25 min) compared with milk with 4% protein at 32°C, which reflects more standard conditions, whereas increasing milk to 6% protein resulted in more than doubling of the curd-firming rate (MCFR = 9.20 Pa/min) and a shorter CW (4.60 min). Gels set at 28°C had lower levels of rearrangement of protein network after 40 min compared with those set at 36°C. Protein levels, on the other hand, had no influence on the levels of protein network rearrangement, as indicated by loss tangent values. The internal structure of curd particles, as investigated by both scanning electron microscopy and transmission electron microscopy, appeared to have less cross-linking and smaller casein aggregates when coagulated at 28°C compared with 36°C, whereas varying protein levels did not show a marked effect on aggregate formation. Overall, this study showed a marked interactive effect between coagulation temperature and protein standardization of milk on coagulation properties, which subsequently requires adjustment of the CW during cheesemaking. Lowering of the coagulation temperature greatly altered the curd microstructure, with a tendency for less syneresis during cutting. Further research is required to quantify the changes in syneresis and in fat and protein losses to whey due to changes in the microstructure of curd particles arising from the different coagulation conditions applied to the protein-fortified milk

Ion traps fabricated in a CMOS foundry

We demonstrate trapping in a surface-electrode ion trap fabricated in a 90-nm CMOS (complementary metal-oxide-semiconductor) foundry process utilizing the top metal layer of the process for the trap electrodes. The process includes doped active regions and metal interconnect layers, allowing for co-fabrication of standard CMOS circuitry as well as devices for optical control and measurement. With one of the interconnect layers defining a ground plane between the trap electrode layer and the p-type doped silicon substrate, ion loading is robust and trapping is stable. We measure a motional heating rate comparable to those seen in surface-electrode traps of similar size. This is the first demonstration of scalable quantum computing hardware, in any modality, utilizing a commercial CMOS process, and it opens the door to integration and co-fabrication of electronics and photonics for large-scale quantum processing in trapped-ion arrays.Comment: 4 pages, 3 figure

ΔI=4\Delta I=4 and ΔI=8\Delta I=8 bifurcations in rotational bands of diatomic molecules

It is shown that the recently observed $\Delta I=4$ bifurcation seen in superdeformed nuclear bands is also occurring in rotational bands of diatomic molecules. In addition, signs of a $\Delta I=8$ bifurcation, of the same order of magnitude as the $\Delta I=4$ one, are observed both in superdeformed nuclear bands and rotational bands of diatomic molecules.Comment: LaTex twice, 10 pages and 5 PS figures provided upon demand by the Author

Evaluating the response of freshwater organisms to vital staining

The unintentional introduction of nonindigenous species by ballast water discharge is one of the greatest threats to biodiversity in freshwater systems. Proposed international regulations for ballast water management will require enumeration of viable plankton in ballast water. In this study we analyze the efficacy of vital stains in determining viability of freshwater taxa. The efficacy of vital stains fluorescein diacetate (FDA) and FDA+5-chloromethylfluorescein diacetate (CMFDA) was evaluated with freshwater macroinvertebrates, zooplankton, and phytoplankton. Macroinvertebrates were cultured in laboratory, while plankton were collected from Hamilton Harbour and ballast tanks of commercial vessels. Organisms were subjected to various treatments (i.e., heat, NaClO, and NaOH) to establish efficacy of stains for viable and non-viable organisms. No significant difference in accuracy rate was found between stains, regardless of treatment, within groups of organisms, indicating that the addition of CMFDA is superfluous in the sample region studied. False positive errors, in which dead organisms fluoresced similarly to live organisms, occurred in most groups and were significantly different between test groups. False positive error rates were 2.3% for phytoplankton, 20% for ballast water zooplankton, 35% for Hamilton Harbour zooplankton and 47% for macroinvertebrates. Response to stains varied between taxonomic groups. Low (< 10%) false positive error rates were observed with phytoplankton, soft-bodied rotifers, oligochaetes, and Bosmina spp., while rates between 20% and 50% were observed for Daphnia spp., Hexagenia sp., and Chironomus riparius. False positive rates of copepods, Hyalella azteca, and Hemimysis anomala were between 70% and 100%. The FDA/FDA+CMFDA vital staining methods provide useful tools for viability analysis of freshwater phytoplankton, soft-bodied invertebrates and zooplankton, and may be used for viability analysis of the ≥ 10 µm to < 50 µm size fraction in compliance testing of ballast water. However, viability analysis of larger freshwater crustaceans with vital stains should be undertaken with caution

Tuning magnetic frustration on the diamond lattice of the A-site magnetic spinels CoAl2−x_{2-x}Gax_xO4_4: Lattice expansion and site disorder

The spinels CoB$_2$O$_4$ with magnetic Co$^{2+}$ ions on the diamond lattice A site can be frustrated because of competing near-neighbor ($J_1$) and next-near neighbor ($J_2$) interactions. Here we describe attempts to tune the relative strengths of these interactions by substitution on the non-magnetic B-site. The system we employ is CoAl$_{2-x}$Ga$_x$O$_4$, where Al is systematically replaced by the larger Ga, ostensibly on the B site. As expected, Ga substitution expands the lattice, resulting in Co atoms on the A-site being pushed further from one other and thereby weakening magnetic interactions. In addition, Ga distributes between the B and the A site in a concentration dependent manner displacing an increasing amount of Co from the A site with increasing $x$. This increased inversion, which is confirmed by neutron diffraction studies carried out at room temperature, affects magnetic ordering very significantly, and changes the nature of the ground state. Modeling of the magnetic coupling illustrates the complexity that arises from the cation site disorder.Comment: 9 pages, 10 figure

Comment on ``Evidence for Narrow Baryon Resonances in Inelastic pp Scattering''

Compton scattering data are sensitive to the existence of low-mass resonances reported by Tatischeff et al. We show that such states, with their reported properties, are excluded by previous Compton scattering experiments.Comment: One page, submitted to PR

Molecular Docking, Synthesis, Structure Illucidation, Admet Analysis and Biological Activity Evaluation of Some Fluorinated Chromene Derivatives

The paper constitutes the exploration performed to developed new fluorinated chromene derivations by coupling response of separate fluorinated amino composites using suitable coupling reagents. The response is clean which enable too easy workup and good yield. Chromene derivations (3a- h) are synthesized by coupling response between different fluoro aniline derivations and 6-( trifluoromethyl) -3,4-dihydro-2H-chromene-2-carboxylic acid, N, N ’- Dicyclohexylcarbodiimide( DCC) and( 2-( 1H- benzotriazol-1-yl) hexafluorophosphate( HBTU) are used as a coupling reagent. N, N ’- Dicyclohexylcarbodiimide urea is formed as a side product during response which can remove by filtration. The response was rapid-fire and was conducted at room temperature with high- to- excellentyields, chromene derivations were assessed for tyrosinase and α- glucosidase inhibitory conditioning. Depended on IC50 values. All novel chromenes displayed significant α- glucosidase inhibition compared with reference (IC50 = 7.80 mM). Likewise, the capability of the studied composites to inhibit tyrosinase was estimated and set up to be moderate ‘In silico studies were performed to explore the list modes of the chromenes at the list point of α- glucosidase and tyrosinase. Molecular docking results revealed the significance of hydrogen cling, hydrophobic, π- π mounding, πcation, and essence relations between the target enzymes and the synthesized composites. Inclusively, the results attained in the current work indicated that the studied chromenes may be regarded as supereminent composites for designing new chemicals potentially effective in conditions similar as skin diseases and diabetes mellitus