Quantitative spatiotemporal mapping of thermal runaway propagation rates in lithium-ion cells using cross-correlated Gabor filtering

Abuse testing of lithium-ion batteries is widely performed in order to develop new safety standards and strategies. However, testing methodologies are not standardised across the research community, especially with failure mechanisms being inherently difficult to reproduce. High-speed X-ray radiography is proven to be a valuable tool to capture events occurring during cell failure, but the observations made remain largely qualitative. We have therefore developed a robust image processing toolbox that can quantify, for the first time, the rate of propagation of battery failure mechanisms revealed by high-speed X-ray radiography. Using Gabor filter, the toolbox selectively tracks the electrode structure at the onset of failure. This facilitated the estimation of the displacement of electrodes undergoing abuse via nail penetration, and also the tracking of objects, such as the nail, as it propagates through a cell. Further, by cross-correlating the Gabor signals, we have produced practical, illustrative spatiotemporal maps of the failure events. From these, we can quantify the propagation rates of electrode displacement prior to the onset of thermal runaway. The highest recorded acceleration (≈514 mm s−2) was when a nail penetrated a cell radially (perpendicular to the electrodes) as opposed to axially (parallel to the electrodes). The initiation of thermal runaway was also resolved in combination with electrode displacement, which occurred at a lower acceleration (≈108 mm s−2). Our assistive toolbox can also be used to study other types of failure mechanisms, extracting otherwise unattainable kinetic data. Ultimately, this tool can be used to not only validate existing theoretical mechanical models, but also standardise battery failure testing procedures

Scientific Software Engineering: Mining Repositories to gain insights into BACARDI

For Space Situational Awareness, the German Aerospace Center (DLR) develops the software system "Backbone Catalogue of Relational Debris Information" (BACARDI), which allows for keeping track of resident space objects. BACARDI's key features are automated processing services which produce orbit information and products like collision warnings. We present how we applied new methods of software analytics to the BACARDI project. BACARDI is an example of a complex software system with large development effort carried out by a team of various specialists. Our goal is to design and implement an efficient software development process, balancing the explorative character of a research project and operational requirements (i.e. tailored from official standards in the aerospace domain). Therefore, we established a software development process for the project where we focus on software quality. We applied methods to structure, communicate, and utilize the diverse skills, knowledge, and experience in the team concisely and precisely. After one year of practical utilization, we analyzed the process based on the repository data. By analyzing these data, we assess and prove the effects of the introduced process on the development of a software, which is used in the aerospace domain

Climate indices in historical climate reconstructions:a global state of the art

Abstract. Narrative evidence contained within historical documents and inscriptions provides an important record of climate variability for periods prior to the onset of systematic meteorological data collection. A common approach used by historical climatologists to convert such qualitative information into continuous quantitative proxy data is through the generation of ordinal-scale climate indices. There is, however, considerable variability in the types of phenomena reconstructed using an index approach and the practice of index development in different parts of the world. This review, written by members of the PAGES (Past Global Changes) CRIAS working group – a collective of climate historians and historical climatologists researching Climate Reconstructions and Impacts from the Archives of Societies – provides the first global synthesis of the use of the index approach in climate reconstruction. We begin by summarising the range of studies that have used indices for climate reconstruction across six continents (Europe, Asia, Africa, the Americas, and Australia) as well as the world's oceans. We then outline the different methods by which indices are developed in each of these regions, including a discussion of the processes adopted to verify and calibrate index series, and the measures used to express confidence and uncertainty. We conclude with a series of recommendations to guide the development of future index-based climate reconstructions to maximise their effectiveness for use by climate modellers and in multiproxy climate reconstructions

Regional opening strategies with commuter testing and containment of new SARS-CoV-2 variants

Background Despite the accelerating vaccination process, a large majority of the population is still susceptible to SARS-CoV-2. In addition, we face the spread of novel variants. Until we overcome the pandemic, reasonable mitigation and opening strategies are crucial to balance public health and economic interests. Methods We model the spread of SARS-CoV-2 over the German counties by a graph-SIR-type model with particular focus on commuter testing. We account for political interventions by varying contact reduction values in private and public locations such as homes, schools, workplaces, and other. We consider different levels of lockdown strictness, commuter testing strategies, or the delay of intervention implementation. We conduct numerical simulations to assess the effectiveness of the different intervention strategies after one month. The virus dynamics in the counties are initialized randomly with incidences between 75-150 weekly new cases per 100,000 inhabitants (red zones) or below 10 (green zones) and consider 25 different initial scenarios of randomly distributed red zones (between 2 and 20 % of all counties). To account for uncertainty, we consider an ensemble set of 500 Monte Carlo runs for each scenario. Results We find that the strength of the lockdown in regions with out of control virus dynamics is most important to avoid the spread into neighboring regions. With very strict lockdowns in red zones, commuter testing rates of twice a week can substantially contribute to the safety of adjacent regions. In contrast, less strict lockdowns with the same commuter testing rate quickly and substantially lead to overall higher infection dynamics. A further key contributor is the potential delay of the intervention implementation. In order to keep the spread of the virus under control, strict regional lockdowns with minimum delay and commuter testing of at least twice a week are advisable

Regional opening strategies with commuter testing and containment of new SARS-CoV-2 variants in Germany

Background Despite the vaccination process in Germany, a large share of the population is still susceptible to SARS-CoV-2. In addition, we face the spread of novel variants. Until we overcome the pandemic, reasonable mitigation and opening strategies are crucial to balance public health and economic interests. Methods We model the spread of SARS-CoV-2 over the German counties by a graph-SIR-type, metapopulation model with particular focus on commuter testing. We account for political interventions by varying contact reduction values in private and public locations such as homes, schools, workplaces, and other. We consider different levels of lockdown strictness, commuter testing strategies, or the delay of intervention implementation. We conduct numerical simulations to assess the effectiveness of the different intervention strategies after one month. The virus dynamics in the regions (German counties) are initialized randomly with incidences between 75 and 150 weekly new cases per 100,000 inhabitants (red zones) or below (green zones) and consider 25 different initial scenarios of randomly distributed red zones (between 2 and 20% of all counties). To account for uncertainty, we consider an ensemble set of 500 Monte Carlo runs for each scenario. Results We find that the strength of the lockdown in regions with out of control virus dynamics is most important to avoid the spread into neighboring regions. With very strict lockdowns in red zones, commuter testing rates of twice a week can substantially contribute to the safety of adjacent regions. In contrast, the negative effect of less strict interventions can be overcome by high commuter testing rates. A further key contributor is the potential delay of the intervention implementation. In order to keep the spread of the virus under control, strict regional lockdowns with minimum delay and commuter testing of at least twice a week are advisable. If less strict interventions are in favor, substantially increased testing rates are needed to avoid overall higher infection dynamics. Conclusions Our results indicate that local containment of outbreaks and maintenance of low overall incidence is possible even in densely populated and highly connected regions such as Germany or Western Europe. While we demonstrate this on data from Germany, similar patterns of mobility likely exist in many countries and our results are, hence, generalizable to a certain extent

Análise comparativa do desgaste das interfaces titânio/titânio e titânio/zircónia dos conjuntos pilar/implante após envelhecimento

Objectives: Due to its hardness, zirconia abutments may damage the titanium of the implant's connection during its clinical use. This study aimed to assess the wear of the seating platforms of externally hexed titanium implants when connected to zirconia abutments comparing to titanium abutments, after thermocycling and mechanical loading (TCML).Methods: Six BNT (R) S4 external connection implants (Phibo (R) Dental Solutions, Barcelona, Spain) were selected and divided into two groups (n=3): TiCE, screwed to titanium abutments and ZrCE, screwed to zirconia abutments. The samples underwent thermocycling (5000 cycles; 5-55 degrees C) and mechanical loading (1.2 x 106 cycles; 88.8 N; 4 Hz). Before and after TCML, the seating platforms of the implants were analyzed by 3D profilometry in two areas to measure their topography based on the superficial analysis parameters (Sa and Sz) parameters, and were studied by scanning electron microscopy (SEM). Data were statistically analyzed by Mann-Whitney test (p 0.05 and p = 0.059). The abutment's material (titanium/zirconia) did not statistically significantly influence the Sa and Sz values after TCML (p = 0.886> 0.05 and p = 0.200, respectively). However, the SEM analysis reveals a mild wear in some vertices of the hex when connected to zirconia abutments.Conclusions: After simulating five years of clinical use, the externally hexed implants, analyzed by 3D profilometry, showed similar wear patterns in the corresponding seating platforms when connected to zirconia or titanium abutments. The SEM images showed zirconia particles being transferred to the implant, which requires further study. (C) 2016 Sociedade Portuguesa de Estomatologia e Medicina Dentaria.Objetivos Devido á sua dureza, os pilares de zircónia podem provocar danos sobre o titânio da conexão do implante durante a utilização clínica. O presente trabalho pretendeu avaliar o desgaste das plataformas protéticas de implantes de titânio com conexão hexágono externo quando conectados com pilares de zircónia em comparação com pilares de titânio, após carga cíclica e termociclagem (TCML). Métodos Foram selecionados 6 implantes de conexão externa BNT® S4 Phibo® Dental Solutions (Barcelona, Espanha), que foram divididos em 2 grupos (n = 3): TiCe aparafusados a pilares de titânio e ZrCe aparafusados a pilares de zircónio. As amostras foram submetidas a TCML (5.000 ciclos; 5–55 °C) e carga cíclica (1,2 × 106 ciclos; 88,8 N; 4 Hz). Antes e após TCML, as plataformas de assentamento de conexão dos implantes foram sujeitas a análise por perfilometria 3 D em 2 localizações para a medição da sua topografia com utilização dos parâmetros de análise superficial (Sa e Sz) e examinadas por microscopia eletrónica de varrimento(MEV). Análise estatística: Mann-Whitney test (p < 0,05). Resultados Não se observaram diferenças estatisticamente significativas nos valores de Sa e de Sz entre os implantes no estado inicial e após TCML (p = 0,573 > 0,05 e p = 0,059). O material do pilar (titânio/zircónia) não exerceu influência estatisticamente significativa nos valores de Sa e Sz após TCML (teste U p = 0,886 > 0,05 e p = 0,200, respetivamente). No entanto, a análise por MEV revelou ligeiro desgaste em alguns vértices do hexágono quando conectados com pilares de zircónia. Conclusões Após uma simulação de 5 anos de utilização clínica, os implantes com hexágono externo, analisados por perfilometria 3 D, apresentaram padrões de desgaste das plataformas de assentamento equivalentes quando conectados a pilares de zircónia ou de titânio. As imagens de MEV mostram a passagem de partículas de zircónia para o implante, aspeto que merece investigação suplementar.Authors gratefully acknowledge the funding of Project NORTE-01-0145-FEDER-000022 - SciTech - Science and Technology for Competitive and Sustainable Industries, cofinanced by Programa Operacional Regional do Norte (NORTE2020), through Fundo Europeu de Desenvolvimento Regional (FEDER)

Thermal Runaway of Li-Ion Cells: How Internal Dynamics, Mass Ejection, and Heat Vary with Cell Geometry and Abuse Type

Thermal runaway of lithium-ion batteries can involve various types of failure mechanisms each with their own unique characteristics. Using fractional thermal runaway calorimetry and high-speed radiography, the response of three different geometries of cylindrical cell (18650, 21700, and D-cell) to different abuse mechanisms (thermal, internal short circuiting, and nail penetration) are quantified and statistically examined. Correlations between the geometry of cells and their thermal behavior are identified, such as increasing heat output per amp-hour (kJ Ah-1) of cells with increasing cell diameter during nail penetration. High-speed radiography reveals that the rate of thermal runaway propagation within cells is generally highest for nail penetration where there is a relative increase in rate of propagation with increasing diameter, compared to thermal or internal short-circuiting abuse. For a given cell model tested under the same conditions, a distribution of heat output is observed with a trend of increasing heat output with increased mass ejection. Finally, internal temperature measurements using thermocouples embedded in the penetrating nail are shown to be unreliable thus demonstrating the need for care when using thermocouples where the temperature is rapidly changing. All data used in this manuscript are open access through the NREL and NASA Battery Failure Databank

Five Years of SMARTnet: Data, Processing, and Improvements

SMARTnet, operated by the Astronomical Institute of the University of Bern (AIUB) and the German Aerospace Center (DLR), went online and open to the public in 2017 with two telescope stations located in Zimmerwald, Switzerland, and Sutherland, South Africa. Over its five-year operational timespan, new partners have joined while one partner left, leaving telescope stations distributed today in Australia, South Africa, and Europe. All stations combined, 9 telescopes are actively providing data to the network. New contributors are currently in the applicant phase and will, together with further stations planned by DLR, enhance the network’s capabilities. The retrieved data is used for research, collision warnings, catalogue maintenance or for deriving data products, which can be sold to third parties. For the aforementioned points, the Backbone Catalogue of Relational Debris Information (BACARDI) was developed at DLR. BACARDI processes input data received from SMARTnet to data products such as ephemerides and orbit information for telescope observation planning, and attempts to detect new objects where an association of observations to already known objects is unsuccessful. To better operate the telescope stations, a dedicated software, called SMARTies, is under development in a joint project by AIUB and DLR. With this software, the telescope stations operations can be optimized to increase the daily data acquisition. It is planned to release SMARTies as Open Source software. To avoid deteriorating accuracy of the orbital information, ephemerides forecasted by BACARDI are combined with the planning tool “Optimal Catalog Maintenance and Survey Tasking” (OMST), which will help keeping all resident space objects in the data base. Furthermore, OMST will allow to search for new objects in the vicinity of the telescopes’ field of view in so-called “dead-times”. A short introduction to SMARTnet and its requirements is given, followed by some products retrieved from SMARTnet data. Also, the complete end-to-end chain from observations to processing, forecast, and its feed-back loop to observations is presented. Lastly, selected campaigns of some of the telescopes are presented. As part of non-regular observations, supporting observations can be acquired in case of special events (e.g. DART)

Guidance for reporting the interpretation of cytogenomic test results in haematological neoplasms

Deep insight on Guidance for reporting the interpretation of cytogenomic test results in haematological neoplasms