Postsynthetic modification of zirconium metal-organic frameworks

Metal-organic frameworks (MOFs) have been in the spotlight for a number of years due to their chemical and topological versatility. As MOF research has progressed, highly functionalised materials have become desirable for specific applications, and in many cases the limitations of direct synthesis have been realised. This has resulted in the search for alternative synthetic routes, with postsynthetic modification (PSM), a term used to collectively describe the functionalisation of pre-synthesised MOFs whilst maintaining their desired characteristics, becoming a topic of interest. Advances in the scope of reactions performed are reported regularly; however reactions requiring harsh conditions can result in degradation of the framework. Zirconium-based MOFs present high chemical, thermal and mechanical stabilities, offering wider opportunities for the scope of reaction conditions that can be tolerated, which has seen a number of successful examples reported. This microreview discusses pertinent examples of PSM resulting in enhanced properties for specific applications, alongside fundamental transformations, which are categorised broadly into covalent modifications, surface transformations, metalations, linker and metal exchange, and cluster modifications

Shall Businesses Profit If Their Owners Lose Their Souls? Examining Whether Closely Held Corporations May Seek Exemptions from the Contraceptive Mandate

May for–profit, secular corporations claim the protection of the Religious Freedom Restoration Act (RFRA)? This question is central to numerous lawsuits against the federal government in which business owners argue that certain regulations under the Patient Protection & Affordable Care Act substantially burden the exercise of their religion. This Note examines the threshold hurdle that for–profit business owners must clear to successfully state a claim under RFRA: the question of whether the businesses are “persons” the statute protects. This is an issue of first impression for the U.S. Supreme Court, and it has split the circuit courts of appeal. First, this Note provides an overview of free exercise jurisprudence, with a focus on the ebbs and flows of the Supreme Court’s exemption doctrine. This overview includes a discussion of the Religious Freedom Restoration Act and the laws, regulations, and religious objections that form the basis of the current disputes. Second, this Note introduces the conflict among circuit courts and their varying interpretations of whether for–profit corporations are “persons” under RFRA. Third, this Note assesses this conflict by examining RFRA’s text and the context in which Congress enacted the statute. Nothing within this context precludes corporations from stating RFRA claims. In addition, this Note examines legislative history that supports application of the Dictionary Act, which explains that the word “person” in federal statutes includes corporations. This Note ultimately concludes that RFRA does indeed grant corporations the ability to seek exemptions, but that the statute will require courts to undertake the task of ascertaining the proper contours of the law as applied to different corporate forms

Digital forensics formats: seeking a digital preservation storage format for web archiving

In this paper we discuss archival storage formats from the point of view of digital curation and preservation. Considering established approaches to data management as our jumping off point, we selected seven format attributes which are core to the long term accessibility of digital materials. These we have labeled core preservation attributes. These attributes are then used as evaluation criteria to compare file formats belonging to five common categories: formats for archiving selected content (e.g. tar, WARC), disk image formats that capture data for recovery or installation (partimage, dd raw image), these two types combined with a selected compression algorithm (e.g. tar+gzip), formats that combine packing and compression (e.g. 7-zip), and forensic file formats for data analysis in criminal investigations (e.g. aff, Advanced Forensic File format). We present a general discussion of the file format landscape in terms of the attributes we discuss, and make a direct comparison between the three most promising archival formats: tar, WARC, and aff. We conclude by suggesting the next steps to take the research forward and to validate the observations we have made

Closing the loop: assisting archival appraisal and information retrieval in one sweep

In this article, we examine the similarities between the concept of appraisal, a process that takes place within the archives, and the concept of relevance judgement, a process fundamental to the evaluation of information retrieval systems. More specifically, we revisit selection criteria proposed as result of archival research, and work within the digital curation communities, and, compare them to relevance criteria as discussed within information retrieval's literature based discovery. We illustrate how closely these criteria relate to each other and discuss how understanding the relationships between the these disciplines could form a basis for proposing automated selection for archival processes and initiating multi-objective learning with respect to information retrieval

Variation of word frequencies across genre classification tasks

This paper examines automated genre classification of text documents and its role in enabling the effective management of digital documents by digital libraries and other repositories. Genre classification, which narrows down the possible structure of a document, is a valuable step in realising the general automatic extraction of semantic metadata essential to the efficient management and use of digital objects. In the present report, we present an analysis of word frequencies in different genre classes in an effort to understand the distinction between independent classification tasks. In particular, we examine automated experiments on thirty-one genre classes to determine the relationship between the word frequency metrics and the degree of its significance in carrying out classification in varying environments

Revenue volatility faced by Australian wheat farmers

This paper uses variance decomposition modelling to explore how wheat revenue volatility in Australia has changed spatially and temporally. The components of revenue variance are the variances and covariances of wheat prices, the area of wheat harvested and the yield of wheat. The key finding is that the volatility of wheat revenue (detrended) has more than doubled in every main wheat-growing State in Australia over the last 15 years or so Changes in wheat areas are mostly a minor source of revenue variance. The principal cause of volatility is yield changes with price changes increasing slightly in absolute importance when compared to their adjacent previous period. Greater downside yield risk is often the principal cause of the increased yield variance. The implications are that revenue variance, and especially downside revenue risk, has posed major problems for wheat-dominant farm businesses over the last 15 years or so. How Australia’s wheat producers have managed this greater volatility of wheat revenue is likely to have greatly affected the viability of their farm businesses.risk, wheat production, variance decomposition, wheat farming, Agribusiness,

Dynamics of Hippocampal and Cortical Activation during Consolidation of a Nonspatial Memory

Observations of temporally graded retrograde amnesia after hippocampal damage suggest that the hippocampal region plays a critical, time-limited role in memory consolidation. However, these observations do not indicate where permanentmemory is stored, nor do they clarify whether the hippocampus normally remains involved in a nonessential way. Evidence from multiple neural imaging studies indicate the time-limited role of the hippocampus and suggest that the anterior cingulate cortex is a critical storage site of different types of long-term memory. However, each of the previous studies examined spatial memory, leaving open the question of whether different cortical areas support long-term memory for other types ofmaterial. We characterized the course of involvement of cortical and hippocampal areas in animals trained in an explicitlynonspatial task. First, we confirmed previous findings that hippocampal damage produces temporally graded retrogradeamnesia for the social transmission of a food preference (STFP) within our experimental protocol. Damage to thehippocampal region 1 d, but not 21 d, after training impaired subsequent recall of STFP. Then, we characterized theanatomical patterns of activation of the immediate early gene c-fos during retrieval of STFP immediately and 1, 2, and 21 dafter training. The ventral subiculum was activated during retrieval shortly after learning, but the level of activation declined at successive times. In contrast, olfactory recipient regions including piriform, entorhinal, and orbitofrontal cortex showed the opposite pattern, increasingly greater activation in successively later retrieval tests. These findings support the view that different cortical networks support long-term memory for different types of information

The Carbon Challenge for Mixed Enterprise Farms

As part of its climate change policy the Australian government has introduced a Mandatory Renewable Energy Target (MRET) scheme and is also attempting to introduce a Carbon Pollution Reduction Scheme (CPRS). Using as a case study a main agricultural region of Australia, this paper examines how farming systems in this region may be affected by the medium term policy settings of these two schemes. A bio-economic model of the region’s farming systems is developed and used to assess the schemes’ impacts on the nature and profitability of the farming systems. Results show a range of profit and enterprise impacts across the range of farming systems. Farms as providers of biomass for electricity generation and small users of electricity are liable to benefit from the MRET scheme, with the extent of benefit depending on the price offered for biomass. By contrast, the CPRS is liable to more profoundly affect farming systems, especially if agriculture is included in the scheme. The impacts of the CPRS on agriculture are mostly conditional on: the amount of free permits allocated to agriculture, the value of trees as carbon sinks, the extent of pass-through of CPRS-related costs onto agriculture and emission permit prices. Dependent on these factors, farm profits can increase by up to 20 percent or decrease by over 30 percent, relative to the ‘no CPRS’ or ‘business-as-usual’ case. If agriculture is covered by the CPRS, and emission permits and tree growth rates are sufficiently high then optimal farm plans typically involve a combination of reduced livestock numbers, the planting of permanent stands of trees on marginal farmland and other changes to the enterprise mix on farms that reduce emissions.agriculture, greenhouse gases, economic modelling, sequestration, Agricultural and Food Policy, Crop Production/Industries, Environmental Economics and Policy, Institutional and Behavioral Economics, International Relations/Trade, Land Economics/Use,