Model-based prognosis for intergranular corrosion

Among the advantages of Aluminium-based alloys for structural use is their corrosion resistance. However, while Aluminium alloys are highly resistant to uniform (general) corrosion, they are much more susceptible to types of localised corrosion, especially intergranular corrosion, which is a localised attack along the grain boundaries which leaves the grains themselves largely unaffected. In order to estimate the progress of such corrosion in a given sample, it is considered possible to generate a numerical model of some sort. While there has been much effort spent in the development of electrochemistry-based models, the use of grey and black-box models remains largely unexplored. One exception to this is the use of Cellular Automata (CA) models which have recently been exploited to model the progression of uniform corrosion. The object of the current paper is to apply the CA methodology to the case of intergranular corrosion. The first phase of the work has been concerned with generating appropriate CA rules which can qualitatively reproduce observed physics, and this work is reported here. A model is proposed which shows qualitative agreement with experimental data on the advance of the corrosion front

Effects of heat input rates on T-1 and T-1A steel welds

Technology of T-1 and T-1A steels is emphasized in investigation of their weld-fabrication. Welding heat input rate, production weldment circumstances, and standards of welding control are considered

UV chromospheric and circumstellar diagnostic features among F supergiant stars

A survey of F supergiant stars to evaluate the extension of chromospheric and circumstellar characteristics commonly observed in the slightly cooler G, K, and M supergiant is discussed. An ultraviolet survey was elected since UV features of Mg II and Fe II might persist in revealing outer atmosphere phenomena even among F supergiants. The encompassed spectral types F0 to G0, and luminosity classes Ib, Ia, and Ia-0. In addition, the usefulness of the emission line width-to-luminosity correlation for the G-M stars in both the Ca II and Mg II lines is examined

Eagle Syndrome: A Rare Case of Atraumatic, Painful Cervical Neck Swelling

Introduction: Painful neck swelling is a common emergency complaint but can present diagnostic challenges. Eagle syndrome is a rare clinical entity in which a pathologically elongated styloid process or ossified stylohyoid ligament produces a constellation of symptoms in the head and neck region.Case Report: We present the case of a 50-year-old male with a spontaneous, atraumatic fracture of an elongated styloid process associated with hematoma formation and radiological findings of airway impingement.Discussion: The classic triad for Eagle syndrome consists of unilateral cervicofacial pain, globus sensation, and dysphagia. Diagnosis of Eagle syndrome should be made based on a combination of physical examination and radiological findings. Treatment options vary based on severity of symptoms.Conclusion: Although more likely to be an indolent and progressive complaint, providers in the acute care setting should be familiar with Eagle syndrome due to the potential for a spontaneous fracture of an elongated styloid process to cause acute, painful neck swelling and life-threatening airway compromise

Size dependent disruption of tethered lipid bilayers by functionalized polystyrene nanoparticles

AbstractMolecular interactions between engineered nanomaterials (ENM) and biomembranes are not well understood. This study investigated the effects of particle size and surface functional group on polystyrene nanoparticles' (PNPs) potency for biomembrane disruption. Electrochemical impedance spectroscopy was used to measure changes in the electrical resistance (Rm) of a tethered bilayer lipid membrane BLM (tBLM) composed of 1,2-dioleoyl-sn-glycero-phosphocholine (DOPC) following PNP exposure. All PNPs tested triggered a decline in the Rm that could be described using an exponential-decay model. Statistical hierarchical clustering analysis of two model parameters (exponential rate constant and fractional loss of Rm) could distinguish between the PNPs based on both size and surface functional group. For COOH modified nanoparticles, 20nm PNPs were more potent in reducing Rm than 100nm PNP. However, for amidine modified nanoparticles, 120nm PNPs were more potent in reducing Rm than 23nm PNP. The COOH modified PNPs were more potent in reducing Rm than amidine modified PNP, which tended to aggregate following exposure to a tBLM. Ultra performance liquid chromatography–mass spectroscopy analysis suggested that the aggregation may have been triggered by DOPC that was removed from the tBLM by the amidine PNP

High-performance thermionic converter Quarterly progress report, 13 Nov. 1965 - 13 Feb. 1966

Stability and optimization parameters of cesium vapor thermionic converters studied in high performance long life equipment fabrication projec

Groundwater compartmentalisation: a water table height and geochemical analysis of the structural controls on the subdivision of a major aquifer, the Sherwood Sandstone, Merseyside, UK

International audienceCompartmentalisation, the subdivision of an aquifer into discrete and relatively isolated units, may be of critical importance for the protection of groundwater although it has been largely ignored in the groundwater literature. The Lower Triassic Sherwood Sandstone, in north west of England, UK, may be a good example of an aquifer that has been compartmentalised by numerous high angle faults with displacements of up to 300 m. The study was initiated to assess the local groundwater flow, the extent of seawater invasion and the controls on recharge in the aquifer and to try to understand whether the aquifer is broken into discrete compartments. Maps and schematic cross-sections of groundwater heads for the years 1993, and 2002 were prepared to trace any structural controls on the groundwater heads across the area. Studying the contour maps and cross sections revealed that: 1) there are substantial differences in groundwater head across some of the NNW-SSE trending faults implying that groundwater flow is strongly limited by faults, 2) an anticline in the east of the area acts as a groundwater divide and 3) the groundwater head seems to follow the topography in some places, although steep changes in groundwater head occur across faults showing that they locally control the groundwater head. The aquifer was thus provisionally subdivided into several hydrogeological sub-basins based on groundwater head patterns and the occurrence of major structural features (faults and a fold). Using groundwater geochemistry data, contour maps of chloride and sulphate concentration largely support the structural sub-division of the area into hydrogeological sub-basins. Scrutiny of groundwater geochemical data, averaged for each sub-basin, confirmed the degree of compartmentalisation and the occurrence of sealed faults. The variation of the geochemical composition of the groundwater not only relates to the different, localised geochemical processes and seawater intrusion but also relates to compartmentalisation due to faulting. Faults have limited the degree of mixing between the groundwater types thus retaining the specific characteristics of each sub-basin. Highly localised seawater intrusion is mainly controlled by low permeability fault close to the Irish Sea and Mersey estuary. There is effectively no invasion of seawater beyond the faults that lie closest to the coastline. Freshwater recharge to the aquifer seems to be highly localised and mainly occurs by vertical percolation of rain and surface water rather than whole aquifer-scale groundwater flow. This study provides a detailed understanding of the groundwater flow processes in Liverpool as an example of methods can be applied to groundwater management elsewhere