Wirkung des Gemengeanbaus mit Körnerleguminosen sowie der Standraumzuteilung und der Saatstärke auf Kornertrag und Kornproteingehalt von Winterweizen

In stockless organic farms it is difficult to produce winter wheat (Triticum aestivum L.) with high protein content. The objective of this study was to evaluate the effects of intercropping of (i) winter wheat with either winter field bean (Vicia faba L.) or winter pea (Pisum sativum L.), (ii) the spatial arrangement (mixed, row or row-strip intercrop) and (iii) the seeding rate of the wheat (100 or 20 %) on yield formation and grain protein content. Monocropped wheat planted at a seeding rate of 20 % significantly out-yielded monocropped wheat at 100 % seeding rate because of a more efficient use of the mineral nitrogen (N) in soil. A gradient in the spatial and temporal use of mineral soil N by the wheat was found. N was available in particular from deeper soil layers during the grain filling phase in row strip intercrop trials, resulting in a higher grain protein content of the wheat. Monocropped wheat achieved mean protein content levels of 9,9 and 9,4 % at two different sites and protein content increased significantly in mixture (mean: 12,8 and 11,4 %). The highest protein content of 15,4 % was achieved with the row strip intercrop of field bean

An “interaction-mediating” strategy towards enhanced solubility and redox properties of organics for aqueous flow batteries

Aqueous redox flow batteries using electroactive organic materials are currently attracting significant attention. However, the influence of supporting electrolytes on the aqueous solubility, electrochemical reversibility and chemical stability of the organic components has rarely been investigated. Here, a new electrolyte design strategy towards enhanced solubility and chemical stability of active materials is proposed by using interaction-mediating species. 3 molality aqueous imidazolium chlorides, with high ionic conductivity and water-like flowability, enable a record aqueous solubility of 4.3 M for a commercially available nitroxyl radical and reversible 2e^{-} reaction of unmodified methyl viologen at moderate concentrations. With 0.6 M electrolyte, flow cell shows remarkable chemical stability of the nitroxyl radical, excellent cycling stability over 250 cycles at 80 mA cm^{-2}, and a peak power density of 121.6 mW cm^{-2} at 175 mA cm^{-2}. Furthermore, nitroxyl radical catholyte with a concentration of 3 M is tested in a flow cell. It maintains an impressive steady energy efficiency of 65% at 30 mA cm^{-2}. This work paves a new way for the development of high performance aqueous electrolytes based on organic materials

Ultra-processed food consumption and risk of obesity: a prospective cohort study of UK Biobank

Objective: To examine the associations between ultra-processed food consumption and risk of obesity among UK adults. Methods: Participants aged 40-69 years at recruitment in the UK Biobank (2006-2019) with dietary intakes collected using 24-hour recall and repeated measures of adiposity - body mass index (BMI), waist circumference (WC) and percentage of body fat (% BF) - were included (N=22,659; median follow-up: 5 years). Ultra-processed foods were identified using the NOVA classification and their consumption was expressed as a percentage of total energy intake. Multivariable Cox proportional hazards regression models were used to estimate hazard ratios (HR) of several indicators of obesity according to ultra-processed food consumption. Models were adjusted for sociodemographic and lifestyle characteristics. Results: 947 incident cases of overall obesity (BMI≥30 kg/m2) and 1,900 incident cases of abdominal obesity (men: WC≥102cm, women: WC≥88cm) were identified during follow-up. Participants in the highest quartile of ultra-processed food consumption had significantly higher risk of developing overall obesity (HR: 1.79; 95%CI: 1.06─3.03) and abdominal obesity (HR: 1.30; 95%CI: 1.14─1.48). They had higher risk of experiencing a ≥5% increase in BMI (HR: 1.31; 95%CI: 1.20─1.43), WC (HR: 1.35; 95%CI: 1.25─1.45) and %BF (HR: 1.14; 95%CI: 1.03─1.25), than those in the lowest quartile of consumption. Conclusions: Our findings provide evidence that higher consumption of ultra-processed food is strongly associated with a higher risk of multiple indicators of obesity in the UK adult population. Policy makers should consider actions that promote consumption of fresh or minimally processed foods and reduce consumption of ultra-processed foods

The interplay of phonology and orthography in visual cognate word recognition: an ERP study

This study examined the role of phonological and orthographic overlap in the recognition of cognate words by recording electrophysiological and behavioral data. One hundred and ninety-two words were selected: 96 cognate words listed according to their phonological and orthographic overlap vs. 96 noncognate words. Twenty-four proficient European Portuguese-English bilinguals performed a silent reading task with a masked priming paradigm. The results showed that phonology interacts with semantic activation at N400 modulations. Phonological priming effects were dependent on the orthographic overlap of cognate words. Thus, the distinctive processing of cognate words seems to be due to their cross-linguistic similarity, which is consistent with a localist connectionist account on cognate representation and processing.The research reported in this paper wasfunded by FCT (Foundation for Science and Technology), by NSRF (National Strategic Reference Framework), by COMPETE (Operational Agenda for Competitiveness Factors), a program created by the EU as part of the European Regional Development Fund (ERDF), (PTDC/PSI-PCO/104671/2008) and by the Spanish Ministry of Education and Science (PSI2009–12616) and Plan E

Dynamics, cation conformation and rotamers in guanidinium ionic liquids with ether groups

Ionic liquids are modern materials with a broad range of applications, including electrochemical devices, the exploitation of sustainable resources and chemical processing. Expanding the chemical space to include novel ion classes allows for the elucidation of novel structure-property relationships and fine tuning for specific applications. We prepared a set of ionic liquids based on the sparsely investigated pentamethyl guanidinium cation with a 2-ethoxy-ethyl side chain in combination with a series of frequently used anions. The resulting properties are compared to a cation with a pentyl side chain lacking ether functionalization. We measured the thermal transitions and transport properties to estimate the performance and trends of this cation class. The samples with imide-type anions form liquids at ambient temperature, and show good transport properties, comparable to imidazolium or ammonium ionic liquids. Despite the dynamics being significantly accelerated, ether functionalization of the cation favors the formation of crystalline solids. Single crystal structure analysis, ab initio calculations and variable temperature nuclear magnetic resonance measurements (VT-NMR) revealed that cation conformations for the ether- and alkyl-chain-substituted are different in both the solid and liquid states. While ether containing cations adopt compact, curled structures, those with pentyl side chains are linear. The Eyring plot revealed that the curled conformation is accompanied by a higher activation energy for rotation around the carbon-nitrogen bonds, due to the coordination of the ether chain as observed by VT-NMR

Systematic model behavior of adsorption on flat surfaces

A low density film on a flat surface is described by an expansion involving the first four virial coefficients. The first coefficient (alone) yields the Henry's law regime, while the next three correct for the effects of interactions. The results permit exploration of the idea of universal adsorption behavior, which is compared with experimental data for a number of systems