61 research outputs found
Optical properties of NaxV2O5
The optical properties of sodium-deficient NaxV2O5 (0.85 < x <1) single
crystals are analyzed in the wide energy range, from 0.012 to 4.5 eV, using
ellipsometry, infrared reflectivity, and Raman scattering techniques. The
material remains insulating up to the maximal achieved hole concentration of
about 15%. In sodium deficient samples the optical absorption peak associated
to the fundamental electronic gap develops at about 0.44 eV. It corresponds to
the transition between vanadium dxy and the impurity band, which forms in the
middle of the pure NaV2O5 gap. Raman spectra measured with incident photon
energy larger then 2 eV show strong resonant behavior, due to the presence of
the hole-doping activated optical transitions, peaked at 2.8 eV.Comment: 7 pages, 4 fugures, to be published in PR
Optical properties and electronic structure of Ca-doped alpha'-NaV2O5
The dielectric function of alpha'-Na(1-x)Ca(x)V2O5 (0 < x < 20%) was measured
for the a and b axes in the photon energy range 0.8-4.5 eV at room temperature.
By varying the Ca-concentration we control the relative abundancy of V4+ and
V5+. We observe that the intensity of the main optical absorption peak at 1 eV
is proportional to the number of V5+ ions. This rules out the interpretation as
a V4+ d-d excitation, and it establishes that this is the on-rung
bonding-antibonding transition.Comment: 6 pages, ReVTeX, 5 figures in encapsulated postscript forma
Low temperature ellipsometry of NaV2O5
The dielectric function of alpha'NaV2O5 was measured with electric field
along the a and b axes in the photon energy range 0.8-4.5 eV for temperatures
down to 4K. We observe a pronounced decrease of the intensity of the 1 eV peak
upon increasing temperature with an activation energy of about 25meV,
indicating that a finite fraction of the rungs becomes occupied with two
electrons while others are emptied as temperature increases. No appreciable
shifts of peaks were found s in the valence state of individual V atoms at the
phase transition is very small. A remarkable inflection of this temperature
dependence at the phase transition at 34 K indicates that charge ordering is
associated with the low temperature phase.Comment: Revisions in style and order of presentation. One new figure. In
press in Physical Review B. REVTeX, 4 pages with 4 postscript figure
Charge kinks as Raman scatterers in quarter-filled ladders
Charge kinks are considered as fundamental excitations in quarter-filled
charge-ordered ladders. The strength of the coupling of the kinks to the
three-dimensional lattice depends on their energy. The integrated intensity of
Raman scattering by kink-antikink pairs is proportional to or where is the order parameter. The exponent is determined by the
system parameters and by the strength of the electron-phonon coupling.Comment: To be published in Phys. Rev.B (june 2001
Electron Correlation Effects in Resonant Inelastic X-ray Scattering of NaV2O5
Element- and site-specific resonant inelastic x-ray scattering spectroscopy
(RIXS) is employed to investigate electron correlation effects in {}. In contrast to single photon techniques, RIXS at the vanadium
edge is able to probe transitions between V d-bands. A sharp energy
loss feature is observed at -1.56 eV, which is well reproduced by a model
calculation including correlation effects. The calculation identifies the loss
feature as excitation between the lower and upper Hubbard bands and permits an
accurate determination of the Hubbard interaction term eV.Comment: 15 pages, four figures, accepted to Phys. Rev. Let
One-dimensional dynamics of the d-electrons in -NaVO
We have studied the electronic properties of the ladder compound
-NaVO, adopting a joint experimental and theoretical
approach. The momentum-dependent loss function was measured using electron
energy-loss spectroscopy in transmission. The optical conductivity derived from
the loss function by a Kramers-Kronig analysis agrees well with our results
from LSDA+U band-structure calculations upon application of an
antiferromagnetic alignment of the V~3 spins along the legs and an
on-site Coulomb interaction U of between 2 and 3 eV. The decomposition of the
calculated optical conductivity into contributions from transitions between
selected energy regions of the DOS reveals the origin of the observed
anisotropy of the optical conductivity. In addition, we have investigated the
plasmon excitations related to transitions between the vanadium states within
an effective 16 site vanadium cluster model. Good agreement between the
theoretical and experimental loss function was obtained using the hopping
parameters derived from the tight binding fit to the band-structure and
moderate Coulomb interactions between the electrons within the ab plane.Comment: 23 pages, 8 figures; submitted to PR
Proton imaging of an electrostatic field structure formed in laser-produced counter-streaming plasmas
We report the measurements of electrostatic field structures associated with an electrostatic shock formed in laser-produced counter-streaming plasmas with proton imaging. The thickness of the electrostatic structure is estimated from proton images with different proton kinetic energies from 4.7 MeV to 10.7 MeV. The width of the transition region is characterized by electron scale length in the laser-produced plasma, suggesting that the field structure is formed due to a collisionless electrostatic shock
Electronic Properties of \alpha'-NaV_2O_5
We studied electronic excitations in NaV2O5 by Raman. Three main topics are
discussed. The first is related to a broad continuum of excitations found in
the 200-1500 cm-1 range and peaked around 680 cm-1. The resonant Raman profile
of this excitation, the polarization selection rules and the presence of its
overtone in resonance conditions allowed us to conclude that the origin of this
feature is magnetic. We proposed that it arises as a result of light coupling
to multi-spinon Raman excitations. Within this scenario we also argued for a
scenario explaining the puzzling temperature dependence of the magnetic
continuum in terms of an increasing role of next nearest neighbor frustration
and in the context of a strongly fluctuating low temperature phase. The second
topic is related to the observation of a folded S = 1 magnetic mode which
displayed very clear selection rules as a function of the magnetic field
orientation. We proposed that the coupling of the photon field to this
excitation takes place via the antisymmetric, Dzyaloshinskii-Moriya (DM),
interaction which, in a simple dimer model, can also explain the observed
selection rules: no splitting or shifts for magnetic fields parallel to the DM
vector and the observation of two (upward and downward) dispersing branches for
fields perpendicular to the DM vector. Thirdly, we discuss the nature of
several new resonances seen below T_c and focus on the possibilities that they
are either folded phonons or singlet bound states of two triplet excitations.
In particular we emphasized the existence of two modes at 66 and 105 cm-1, the
first one being degenerate with one of the spin gap modes.Comment: 29 pages, 19 figure
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