The avifauna of Bishop and Clerk islets and its relationship to nearby Macquarie Island

A first comprehensive survey of seabirds at Bishop and Clerk islets conducted on 23 December 1993 recorded a total of 12 species. During a three-hour-long visit by helicopter, nine species were found breeding, mostly in nests on the ground, but also in burrows dug in shallow soil. These included the largest known colony of Black-browed Albatross, Thalassarche melanophris, in Australia. Ten bird species are now known to breed at the islets. Specics accounts are given including data on morphometries, abundance, habitats, breeding, threats, interspecific competition for space and unpublished information

Trapping and relocating seals from salmonid fish farms in Tasmania, 1990-2000: was it a success?

In an effort to reduce the impact of seals on fish farms, the trapping and relocation of seals at Tasmanian salmonid farms began in 1990. To the end of May 2000,353 identified individual seals had been trapped in 672 capture events. Most were non-breeding male Australian fur seals (Arctocephalus pusillus doriftrus). The number of seals captured increased (from four in 1990 ro a peak of 164 in 1998) with the size and extent of the farms, and an increase in salmon production from 55 tonnes in 1986/87 to almost 10000 tonnes in 1999/2000. Of 586 capture events 52% were of seals that had been captured more than once. When seals are recaptured following trapping and relocation, this occurs on average 25 days after capture. Capture-mark-recapture calculations show that many seals in the vicinity of fish farms are not 'trappable', suggesting that trapping is only effective for certain individuals. Some individuals are recaptured many times, reflecting the predisposition of some individuals to be captured ('trap-happy'). Interaction is seasonal, with most seals trapped during winter, between May and September. The assessment of trends in capture rates is problematic, due to the lack of capture effort information from the farms. A further confounding factor has been the change in management practice both between farms and over time, as the use of predator nets has become more widespread. Two seals trapped at fish farms and fitted with satellite transmitters before relocation have either not returned to the farm or returned to the vicinity of farms and not interacted with them, although on one occasion the individual was trapped. The effectiveness of the relocation program as a management tool to reduce seal interactions cannot be quantified from the relocation data per se, but relocation does not stop seals interacting with farms

Genetic Variation and Antioxidant Response Gene Expression in the Bronchial Airway Epithelium of Smokers at Risk for Lung Cancer

Prior microarray studies of smokers at high risk for lung cancer have demonstrated that heterogeneity in bronchial airway epithelial cell gene expression response to smoking can serve as an early diagnostic biomarker for lung cancer. As a first step in applying functional genomic analysis to population studies, we have examined the relationship between gene expression variation and genetic variation in a central molecular pathway (NRF2-mediated antioxidant response) associated with smoking exposure and lung cancer. We assessed global gene expression in histologically normal airway epithelial cells obtained at bronchoscopy from smokers who developed lung cancer (SC, n=20), smokers without lung cancer (SNC, n=24), and never smokers (NS, n=8). Functional enrichment analysis showed that the NRF2-mediated, antioxidant response element (ARE)-regulated genes, were significantly lower in SC, when compared with expression levels in SNC. Importantly, we found that the expression of MAFG (a binding partner of NRF2) was correlated with the expression of ARE genes, suggesting MAFG levels may limit target gene induction. Bioinformatically we identified single nucleotide polymorphisms (SNPs) in putative ARE genes and to test the impact of genetic variation, we genotyped these putative regulatory SNPs and other tag SNPs in selected NRF2 pathway genes. Sequencing MAFG locus, we identified 30 novel SNPs and two were associated with either gene expression or lung cancer status among smokers. This work demonstrates an analysis approach that integrates bioinformatics pathway and transcription factor binding site analysis with genotype, gene expression and disease status to identify SNPs that may be associated with individual differences in gene expression and/or cancer status in smokers. These polymorphisms might ultimately contribute to lung cancer risk via their effect on the airway gene expression response to tobacco-smoke exposure.Intramural Research Program of the National Institute of Environmental Health Sciences; National Institutes of Health (Z01 ES100475, U01ES016035, R01CA124640

Seabird Bycatch in Pelagic Longline Fisheries Is Grossly Underestimated when Using Only Haul Data

Hundreds of thousands of seabirds are killed each year as bycatch in longline fisheries. Seabirds are predominantly caught during line setting but bycatch is generally recorded during line hauling, many hours after birds are caught. Bird loss during this interval may lead to inaccurate bycatch information. In this 15 year study, seabird bycatch was recorded during both line setting and line hauling from four fishing regions: Indian Ocean, Southern Ocean, Coral Sea and central Pacific Ocean. Over 43,000 albatrosses, petrels and skuas representing over 25 species were counted during line setting of which almost 6,000 seabirds attempted to take the bait. Bait-taking interactions were placed into one of four categories. (i) The majority (57%) of bait-taking attempts were “unsuccessful” involving seabirds that did not take the bait nor get caught or hooked. (ii) One-third of attempts were “successful” with seabirds removing the bait while not getting caught. (iii) One-hundred and seventy-six seabirds (3% of attempts) were observed being “caught” during line setting, with three albatross species – Laysan (Phoebastria immutabilis), black-footed (P. nigripes) and black-browed (Thalassarche melanophrys)– dominating this category. However, of these, only 85 (48%) seabird carcasses were retrieved during line hauling. Most caught seabirds were hooked through the bill. (iv) The remainder of seabird-bait interactions (7%) was not clearly observed, but likely involved more “caught” seabirds. Bait taking attempts and percentage outcome (e.g. successful, caught) varied between seabird species and was not always related to species abundance around fishing vessels. Using only haul data to calculate seabird bycatch grossly underestimates actual bycatch levels, with the level of seabird bycatch from pelagic longline fishing possibly double what was previously thought

Supplementary data for article: Stanković, I. M.; Božinovski, D. M.; Brothers, E. N.; Belić, M. R.; Hall, M. B.; Zarić, S. D. Interactions of Aromatic Residues in Amyloids: A Survey of Protein Data Bank Crystallographic Data. Crystal Growth and Design 2017, 17 (12), 6353–6362. https://doi.org/10.1021/acs.cgd.7b01035

Supporting information for: [https://doi.org/10.1021/acs.cgd.7b01035]Related to published version: [http://cherry.chem.bg.ac.rs/handle/123456789/2566

Accurate Modeling of the Cubic and Antiferrodistortive Phases of SrTiO3 with Screened Hybrid Density Functional Theory

We have calculated the properties of SrTiO3 (STO) using a wide array of density functionals ranging from standard semi-local functionals to modern range-separated hybrids, combined with several basis sets of varying size/quality. We show how these combination's predictive ability varies significantly, both for STO's cubic and antiferrodistortive (AFD) phases, with the greatest variation in functional/basis set efficacy seen in modeling the AFD phase. The screened hybrid functionals we utilized predict the structural properties of both phases in very good agreement with experiment, especially if used with large (but still computationally tractable) basis sets. The most accurate results presented in this study, namely those from HSE06/modified-def2-TZVP, stand as the most accurate modeling of STO to date when compared to the literature; these results agree well with experimental structural and electronic properties as well as providing insight into the band structure alteration during the phase transition.Comment: 14 pages, 6 figure

Computational investigation of cobalt and copper bis (oxothiolene) complexes as an alternative for olefin purification

Considering that olefins present a large volume feedstock, it is reasonable to expect that their purification is industrially critical. After the discovery of the nickel bis (dithiolene) complex Ni(S2C2(CF3)2)2 that exhibits electro-catalytic activity with olefins but tends to decompose by a competitive reaction route, related complexes have been explored experimentally and theoretically. In this paper, a computational examination is performed on differently charged cobalt and copper bis (oxothiolene) complexes [M (OSC2(CN)2)2] to test their potential applicability as the catalysts for olefin purification, using the simplest olefin, ethylene. Possible reaction pathways for ethylene addition on these complexes were explored, to determine whether some of these candidates can avoid the reaction route that leads to decomposition, which is distinctive from the nickel complex, and to form stable adducts that can subsequently release ethylene by reduction. Our calculations suggest that the neutral cobalt complex might be an alternative catalyst, because all its forms can bind ethylene to produce stable interligand adducts with moderate to low activation barriers, rather than to form intraligand adducts that lead to decomposition. The calculations also predict that these interligand adducts are capable of releasing ethylene upon reduction. In addition, it can produce the desired interligand adducts following two different reaction pathways, assigned as the direct and the indirect, with no need for anion species as co-catalysts, which is crucial for the nickel complex. Thus, the olefin purification process could be much simpler by using this catalyst

Environmental drivers of movement in a threatened seabird: insights from a mechanistic model and implications for conservation

Determining the drivers of movement of different life‐history stages is crucial for understanding age‐related changes in survival rates and, for marine top predators, the link between fisheries overlap and incidental mortality (bycatch), which is driving population declines in many taxa. Here, we combine individual tracking data and a movement model to investigate the environmental drivers and conservation implications of divergent movement patterns in juveniles (fledglings) and adults of a threatened seabird, the white‐chinned petrel (Procellaria aequinoctialis)