Process-dependence of biogenic feedback effects in models of plankton dynamics.

The prospect of human-induced climate change has stimulated research into several biological processes that might affect climate. One such process that has attracted a substantial research effort is the so-called CLAW hypothesis (Charlson et al. 1987). This hypothesis suggests that marine plankton ecosystems may effectively regulate climate by a feedback associated with the production of dimethylsulphide (DMS). Charlson et al. (1987) observed that some of the DMS produced by marine ecosystems is transferred from the ocean to the atmosphere where it is the major source of cloud condensing nuclei (CCN) over the remote oceans. The aerosols resulting from biogenic DMS emissions can have a direct effect on the solar radiative forcing experienced by the Earth through scattering, absorption and reflection and can also lead to increased cloud formation; the CLAW hypothesis proposes that these mechanisms could regulate climate. Charlson et al (1987) argued that an increase in global temperature would lead to increased biogenic DMS emissions from the ocean and result in an increase in scattering, cloud cover and cloud albedo that would increase the proportion of the incoming solar radiation reflected back into space (thus changing the global albedo), and thereby cooling the planet. The objective of this paper is to examine the implications of the climate regulation process proposed by Charlson et al. (1987) for the dynamics of the ecosystems that produce it. Cropp et al. (2007) developed a simple plankton model that incorporated the DMS feedback mechanism and compared its dynamics to the same ecosystem model without the feedback. These simulations revealed that the presence of the feedback generally enhanced the stability of the ecosystem by making it more resilient to perturbation. In this research, we compare the effect of the feedbacks on a similar NPZ ecosystem model that has a greater range of dynamical behaviour than the model used by Cropp et al. (2007). The results of simulations with the new feedback model are compared to the results of Cropp et al. (2007) to elucidate the influence of the model formulation on the effects of the feedback

Modelling dimethylsulphide production at the Bermuda Atlantic time series (BATS)

Dimethylsulphide (DMS) is produced by upper ocean ecosystems and emitted to the atmosphere where it may have an important role in climate regulation. Several attempts to quantify the role of DMS in climate change have been undertaken in modeling studies. We examine a model of biogenic DMS production and describe its endogenous dynamics and sensitivities. We extend the model to develop a one-dimensional version that more accurately resolves the important processes of the mixed layer in determining the ecosystem dynamics. Comparisons of the results of the one-dimensional model with vertical profiles of DMS in the upper ocean measured at the Bermuda Atlantic Time Series suggest that the model represents the interaction between the biological and physical processes well. Our analysis of the model confirms its veracity and provides insights into the important processes determining DMS concentration in the oceans

On the elliptic generating region of a tsunami

The surface elevation is calculated for the three-dimensional motion of waves in a fluid of constant depth subject to a given bottom velocity. An example, modeling tsunami generation, with antisymmetric bottom velocity, is considered in detail. The amplitude of the wave front is found to decay much more rapidly than the main wave. The distribution of amplitude with wave number and with angular position is computed for some cases

Using a finite element grid on corner points in flow models

One of the main functions of a multilayer cover liner is to prevent water from infiltrating into mine or other waste thereby preventing the occurrence of ground water pollution. In the past, numerical models have predominantly dealt with vertical infiltration or infiltration into sloping hillsides of infinite extent. The two layer model investigated in this paper has a more realistic shape which is piece-wise linear with a horizontal top, vertical bottom and a sloping section in-between. At the intersection of these segments are corner points where there are changes from sloping flow dynamics to either vertical or horizontal flow dynamics, depending on the corner point. The abrupt change in dynamics at the corner points can cause numerical problems especially when dealing with the boundary condition at the interface of two soils. This paper will deal with the corner point problem at the soil layer interface and, in particular, investigate the use of a finite element grid around the corner points

Improving procedural fidelity of behavioural interventions for people with intellectual and developmental disabilities: A systematic review

Background: Despite its importance within behavioural intervention, it remains unclear how best to achieve high procedural fidelity. This paper reviewed studies on improving procedural fidelity of behavioural interventions for individuals with intellectual and developmental disabilities (IDD). Method: A systematic literature search was conducted, which identified 20 studies meeting inclusion criteria. Data were extracted on study design, participant characteristics, intervention, target behaviours, effect sizes, maintenance, generalisation, and social validity. A quality rating was also applied. Results: A total of 100 participants took part in the included studies. Most participants were teachers working with children in school settings. There was a significant positive correlation between level of procedural fidelity and client outcomes. Feedback was the most commonly employed intervention to improve procedural fidelity. Conclusions: More research should be conducted in environments with high levels of variability such as community homes to determine how to reach and maintain high levels of procedural fidelity

(±)-Polysiphenol and other Analogues via Symmetrical Intermolecular Dimerizations: a Synthetic, Spectroscopic, Structural and Computational Study

We report an improved total synthesis of 4,5-dibromo-9,10-dihydrophenanthrene-2,3,6,7-tetraol, (±)-polysiphenol, via intermolecular McMurray dimerization of 5-bromovanillin and subsequent intramolecular oxidative coupling as the key steps. The synthetic route is applicable to 4,5-dichloro- and 4,5-difluoro-halologues (as well as a 4,5-dialkyl-analogue). Distinctive AA′BB′ multiplets in their 1H NMR spectra for the dimethylene bridges of the dibromo and dichloro compounds reveal them to be room-temperature stable atropisomers, while for the difluoro compound they present as a singlet. X-ray crystal structure determinations of their tetramethylated synthetic precursors show atropisomeric twist angles of 48°, 46°, and 32°, respectively, with the former representing the largest yet observed in any 4,5-disubstituted-9,10-dihydrophenanthrene. DFT computational studies reveal an unprecedented two-stage atropisomeric interconversion process involving time-independent asynchronous rotations of the dimethylene bridge and the biaryl axis for halologues containing chlorine or bromine, but a more synchronous rotation for the difluoro analogue

The realities of being young, unemployed and poor in post-industrial Britain

Poverty is a complex cultural phenomenon that is very much in existence in contemporary post-industrial Britain. A young person’s poverty-striken situation, in addition to their marginalised hierarchal position, shapes their repetitive life cycle comprising different but interrelated forms of marginality. The young people in this ethnographic study were found to experience marginalisation in their education, training and work spheres, as well as in their community, family and home. The purpose of this article is to carefully analyse the link between marginalised young people’s (in)ability to participate in key social systems and their (lack of) access to financial, cultural and social resources