Silica grain catalysis of methanol formation

The specific catalytic effect of a silica grain on the formation of methanol via the sequential addition of H atoms to CO adsorbed on the surface is investigated. A negatively charged defect on a siliceous edingtonite surface is found to reduce the gas phase barriers for the H + COads and H + H2C=O-ads reactions by 770 and 399 K, respectively, when compared to the same reactions in the gas phase. The catalytic effect of negatively charged surface sites could also be applicable to the hydrogenation of other adsorbed unsaturated species. However, the activation energies on the surface defect are still too large (1150 and 2230 K) for CH3OH to form efficiently at 10-20 K in the interstellar medium via a classical mechanism. It is therefore suggested that quantum mechanical tunnelling through the activation barrier is required for these hydrogen addition reactions to proceed at such temperatures. The calculations show that because the adsorption energies of CO and H2C=O on the negatively charged defect are substantial, CH3OH may form efficiently during the warm-up period in star-forming regions

The diagnostic accuracy and cost-effectiveness of magnetic resonance spectroscopy and enhanced magnetic resonance imaging techniques in aiding the localisation of prostate abnormalities for biopsy : a systematic review and economic evaluation

Peer reviewedPublisher PD

Status of the HIE-ISOLDE project at CERN

The HIE-ISOLDE project represents a major upgrade of the ISOLDE nuclear facility with a mandate to significantly improve the quality and increase the intensity and energy of radioactive nuclear beams produced at CERN. The project will expand the experimental nuclear physics programme at ISOLDE by focusing on an upgrade of the existing Radioactive ion beam EXperiment (REX) linac with a 40 MV superconducting linac comprising thirty-two niobium-on-copper sputter-coated quarter-wave resonators housed in six cryomodules. The new linac will raise the energy of post-accelerated beams from 3 MeV/u to over 10 MeV/u. The upgrade will be staged to first deliver beam energies of 5.5 MeV/u using two high-$\beta$ cryomodules placed downstream of REX, before the energy variable section of the existing linac is replaced with two low-$\beta$ cryomodules and two additional high-$\beta$ cryomodules are installed to attain over 10 MeV/u with full energy variability above 0.45 MeV/u. An overview of the project including a status summary of the different R&D activities and the schedule will outlined.Comment: 7 pages, 12 figures, submitted to the Heavy Ion Accelerator Technology conference (HIAT) 2012, in Chicag

Atomic and Molecular Opacities for Brown Dwarf and Giant Planet Atmospheres

We present a comprehensive description of the theory and practice of opacity calculations from the infrared to the ultraviolet needed to generate models of the atmospheres of brown dwarfs and extrasolar giant planets. Methods for using existing line lists and spectroscopic databases in disparate formats are presented and plots of the resulting absorptive opacities versus wavelength for the most important molecules and atoms at representative temperature/pressure points are provided. Electronic, ro-vibrational, bound-free, bound-bound, free-free, and collision-induced transitions and monochromatic opacities are derived, discussed, and analyzed. The species addressed include the alkali metals, iron, heavy metal oxides, metal hydrides, $H_2$, $H_2O$, $CH_4$, $CO$, $NH_3$, $H_2S$, $PH_3$, and representative grains. [Abridged]Comment: 28 pages of text, plus 22 figures, accepted to the Astrophysical Journal Supplement Series, replaced with more compact emulateapj versio

Adiabatic orientation of rotating dipole molecules in an external field

The induced polarization of a beam of polar clusters or molecules passing through an electric or magnetic field region differs from the textbook Langevin-Debye susceptibility. This distinction, which is important for the interpretation of deflection and focusing experiments, arises because instead of acquiring thermal equilibrium in the field region, the beam ensemble typically enters the field adiabatically, i.e., with a previously fixed distribution of rotational states. We discuss the orientation of rigid symmetric-top systems with a body-fixed electric or magnetic dipole moment. The analytical expression for their "adiabatic-entry" orientation is elucidated and compared with exact numerical results for a range of parameters. The differences between the polarization of thermodynamic and "adiabatic-entry" ensembles, of prolate and oblate tops, and of symmetric-top and linear rotators are illustrated and identified.Comment: 18 pages, 4 figure

The VLT-FLAMES Tarantula Survey V. The peculiar B[e]-like supergiant, VFTS698, in 30 Doradus

We present an analysis of a peculiar supergiant B-type star (VFTS698/Melnick 2/Parker 1797) in the 30 Doradus region of the Large Magellanic Cloud which exhibits characteristics similar to the broad class of B[e] stars. We analyse optical spectra from the VLT-FLAMES survey, together with archival optical and infrared photometry and X-ray imaging to characterise the system. We find radial velocity variations of around 400 km/s in the high excitation Si IV, N III and He II spectra, and photometric variability of ~0.6 mag with a period of 12.7 days. In addition, we detect long-term photometric variations of ~0.25 mag, which may be due to a longer-term variability with a period of ~400 days. We conclude that VFTS698 is likely an interacting binary comprising an early B-type star secondary orbiting a veiled, more massive companion. Spectral evidence suggests a mid-to-late B-type primary, but this may originate from an optically-thick accretion disc directly surrounding the primary.Comment: 18 pages, 14 figures and 8 tables. Table 8 to be published onlin

The host galaxy and late-time evolution of the Super-Luminous Supernova PTF12dam

Super-luminous supernovae of type Ic have a tendency to occur in faint host galaxies which are likely to have low mass and low metallicity. PTF12dam is one of the closest and best studied super-luminous explosions that has a broad and slowly fading lightcurve similar to SN 2007bi. Here we present new photometry and spectroscopy for PTF12dam from 200-500 days (rest-frame) after peak and a detailed analysis of the host galaxy (SDSS J142446.21+461348.6 at z = 0.107). Using deep templates and image subtraction we show that the full lightcurve can be fit with a magnetar model if escape of high-energy gamma rays is taken into account. The full bolometric lightcurve from -53 to +399 days (with respect to peak) cannot be fit satisfactorily with the pair-instability models. An alternative model of interaction with a dense CSM produces a good fit to the data although this requires a very large mass (~ 13 M_sun) of hydrogen free CSM. The host galaxy is a compact dwarf (physical size ~ 1.9 kpc) and with M_g = -19.33 +/- 0.10, it is the brightest nearby SLSN Ic host discovered so far. The host is a low mass system (2.8 x 10^8 M_sun) with a star-formation rate (5.0 M_sun/year), which implies a very high specific star-formation rate (17.9 Gyr^-1). The remarkably strong nebular lines provide detections of the [O III] \lambda 4363 and [O II] \lambda\lambda 7320,7330 auroral lines and an accurate oxygen abundance of 12 + log(O/H) = 8.05 +/- 0.09. We show here that they are at the extreme end of the metallicity distribution of dwarf galaxies and propose that low metallicity is a requirement to produce these rare and peculiar supernovae.Comment: 20 pages, 12 figures, 8 tables, accepted for publication to MNRA