46 research outputs found

    The effect of Smog-Ozone warnings and a vanpool program on traffic volume in york county of south carolina

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    Ground-level ozone is a critical criteria pollutant that is significantly generated by transportation patterns. We study the effect of smog–ozone warnings, triggered by the Environmental Protection Agency, on traffic volume in York County, South Carolina during the period 2006–10. In addition, the subperiods 2006–07 and 2008–10, where the ozone smog-alert thresholds 0.080 parts per million (ppm) and 0.075 ppm, respectively, are examined. The approach followed in this paper is a differences-in-differences (DID) regression. Additionally, a regression discontinuity design in the DID framework is applied. We find a negative and significant decrease in weekday peak-hour traffic volume in the treatment group during 2008–10

    Japan's motor industry Reshaping for the future

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    SIGLEAvailable from British Library Document Supply Centre-DSC:3668.239(EIU-SR--330) / BLDSC - British Library Document Supply CentreGBUnited Kingdo

    Detection of interstellar H 2 CCCHC 3 N: A possible link between chains and rings in cold cores

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    Context. The chemical pathways linking the small organic molecules commonly observed in molecular clouds to the large, complex, polycyclic species long suspected of being carriers of the ubiquitous unidentified infrared emission bands remain unclear. Aims. To investigate whether the formation of mono- and polycyclic molecules observed in cold cores could form via the bottom-up reaction of ubiquitous carbon-chain species with, for example, atomic hydrogen, a search is made for possible intermediates in data taken as part of the GOTHAM (GBT Observations of TMC-1: Hunting for Aromatic Molecules) project. Methods. Markov chain Monte Carlo (MCMC) source models were run to obtain column densities and excitation temperatures. Astrochemical models were run to examine possible formation routes, including (a) a novel grain-surface pathway involving the hydrogenation of C6N and HC6N, (b) purely gas-phase reactions between C3N and both propyne (CH3CCH) and allene (CH2CCH2), and (c) via the reaction CN + H2CCCHCCH. Results. We report the first detection of cyanoacetyleneallene (H2CCCHC3N) in space toward the TMC-1 cold cloud using the Robert C. Byrd 100 m Green Bank Telescope. Cyanoacetyleneallene may represent an intermediate between less-saturated carbon chains, such as the cyanopolyynes, that are characteristic of cold cores and the more recently discovered cyclic species, such as cyanocyclopentadiene. Results from our models show that the gas-phase allene-based formation route in particular produces abundances of H2CCCHC3N that match the column density of 2 × 1011 cm−2 obtained from the MCMC source model, and that the grain-surface route yields large abundances on ices that could potentially be important as precursors for cyclic molecules.</jats:p

    Detection of interstellar H

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    Context. The chemical pathways linking the small organic molecules commonly observed in molecular clouds to the large, complex, polycyclic species long suspected of being carriers of the ubiquitous unidentified infrared emission bands remain unclear. Aims. To investigate whether the formation of mono- and polycyclic molecules observed in cold cores could form via the bottom-up reaction of ubiquitous carbon-chain species with, for example, atomic hydrogen, a search is made for possible intermediates in data taken as part of the GOTHAM (GBT Observations of TMC-1: Hunting for Aromatic Molecules) project. Methods. Markov chain Monte Carlo (MCMC) source models were run to obtain column densities and excitation temperatures. Astrochemical models were run to examine possible formation routes, including (a) a novel grain-surface pathway involving the hydrogenation of C6N and HC6N, (b) purely gas-phase reactions between C3N and both propyne (CH3CCH) and allene (CH2CCH2), and (c) via the reaction CN + H2CCCHCCH. Results. We report the first detection of cyanoacetyleneallene (H2CCCHC3N) in space toward the TMC-1 cold cloud using the Robert C. Byrd 100 m Green Bank Telescope. Cyanoacetyleneallene may represent an intermediate between less-saturated carbon chains, such as the cyanopolyynes, that are characteristic of cold cores and the more recently discovered cyclic species, such as cyanocyclopentadiene. Results from our models show that the gas-phase allene-based formation route in particular produces abundances of H2CCCHC3N that match the column density of 2 × 1011 cm−2 obtained from the MCMC source model, and that the grain-surface route yields large abundances on ices that could potentially be important as precursors for cyclic molecules
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