CO Abundance Variations in the Orion Molecular Cloud

Infrared stellar photometry from 2MASS and spectral line imaging observations of 12CO and 13CO J = 1-0 line emission from the FCRAO 14m telescope are analysed to assess the variation of the CO abundance with physical conditions throughout the Orion A and Orion B molecular clouds. Three distinct Av regimes are identified in which the ratio between the 13CO column density and visual extinction changes corresponding to the photon dominated envelope, the strongly self-shielded interior, and the cold, dense volumes of the clouds. Within the strongly self-shielded interior of the Orion A cloud, the 13CO abundance varies by 100% with a peak value located near regions of enhanced star formation activity. The effect of CO depletion onto the ice mantles of dust grains is limited to regions with AV > 10 mag and gas temperatures less than 20 K as predicted by chemical models that consider thermal-evaporation to desorb molecules from grain surfaces. Values of the molecular mass of each cloud are independently derived from the distributions of Av and 13CO column densities with a constant 13CO-to-H2 abundance over various extinction ranges. Within the strongly self-shielded interior of the cloud (Av > 3 mag), 13CO provides a reliable tracer of H2 mass with the exception of the cold, dense volumes where depletion is important. However, owing to its reduced abundance, 13CO does not trace the H2 mass that resides in the extended cloud envelope, which comprises 40-50% of the molecular mass of each cloud. The implied CO luminosity to mass ratios, M/L_{CO}, are 3.2 and 2.9 for Orion A and Orion B respectively, which are comparable to the value (2.9), derived from gamma-ray observations of the Orion region. Our results emphasize the need to consider local conditions when applying CO observations to derive H2 column densities.Comment: Accepted for publication in MNRAS. 21 pages, 14 figure

Link Between Endowments, Economics and Environment in Conventinal and unconventional Gas Reservoirs

This paper presents a methodology for connecting endowments, economics and the environment in conventional, tight, shale and Coalbed Methane (CBM) reservoirs. The volumetric estimates are generated by a Variable Shape Distribution model (VSD). The VSD has been shown in the past to be useful for the evaluation of conventional and tight gas reservoirs. However, this is the first paper in which the method is used to also include shale gas and CBM formations. Results indicate a total gas endowment of 70,000 tcf, split between 15,000 tcf in conventional reservoirs, 15,000 tcf in tight gas, 30,000 tcf in shale gas and 10,000 tcf in CBM reservoirs. Thus, natural gas formations have potential to provide a significant contribution to global energy demand estimated at approximately 790 quads by 2035. A common thread between unconventional formations is that nearly all of them must be hydraulically fractured to attain commercial production. A significant volume of data indicates that the probabilities of hydraulic fracturing (fracking) fluids and/or methane contaminating ground water through the hydraulically-created fractures are very low. Since fracking has also raised questions about the economic viability of producing unconventional gas in some parts of the world, supply curves are estimated in this paper for the global gas portfolio. The curves show that, in some cases, the costs of producing gas from unconventional reservoirs are comparable to those of conventional gas. The conclusion is that there is enough natural gas to supply the energy market for nearly 400 years at current rates of consumption and 110 years with a growth rate in production of 2% per year. With appropriate regulation, this may be done safely, commercially, and in a manner that is more benign to the environment as compared with other fossil fuels

Measurement of the Mitochondrial Membrane Potential and pH Gradient from the Redox Poise of the Hemes of the bc1 Complex

AbstractThe redox potentials of the hemes of the mitochondrial bc1 complex are dependent on the proton-motive force due to the energy transduction. This allows the membrane potential and pH gradient components to be calculated from the oxidation state of the hemes measured with multi-wavelength cell spectroscopy. Oxidation states were measured in living RAW 264.7 cells under varying electron flux and membrane potential obtained by a combination of oligomycin and titration with a proton ionophore. A stochastic model of bc1 turnover was used to confirm that the membrane potential and redox potential of the ubiquinone pool could be measured from the redox poise of the b-hemes under physiological conditions assuming the redox couples are in equilibrium. The pH gradient was then calculated from the difference in redox potentials of cytochrome c and ubiquinone pool using the stochastic model to evaluate the ΔG of the bc1 complex. The technique allows absolute quantification of the membrane potential, pH gradient, and proton-motive force without the need for genetic manipulation or exogenous compounds

The Asia Pacific natural gas market: Large enough for all?

Among natural gas producing nations, there has been some concern about how the Asia Pacific will meet future demand for energy. We argue that natural gas, both regional and global, will play a vital role. Estimates of potential gas consumption in the region are analyzed and used to develop consensus projections to 2030. These consumption profiles are compared with gas supply estimates including indigenous, pipeline and LNG for the Asia Pacific market. From this analytical framework, we find that demand will be sufficiently large to accommodate supplies from diverse sources including North America, the Middle East, Central Asia, Russia, and the Asia Pacific itself. An important policy implication is that gas producing and consuming nations should benefit from promoting gas trade and not be concerned about a situation of potential lack of demand coupled with oversupply

Educational Contracting and the Translation of Research into Practice: The Case of Data Coach Vendors in Delaware

Accountability puts demands on educational agencies that often exceed their capacity. As a result, a variety of educational organizations are contracted to design and implement policy. Programs and services offered by these contractors are not only instrumental in the process of mediating and implementing policy, but may also be instrumental in translating research into practice. To explore this issue, a case study is conducted using vendor proposals for Delaware’s Data Coach initiative. Data are analyzed through content and citation analyses to examine the degree and nature of research use by educational contractors. This research offers new directions for studies of research use in policy but also lessons for policymakers and practitioners that seek the services of educational contractors

Measurement of the Oxidation State of Mitochondrial Cytochrome c from the Neocortex of the Mammalian Brain

Diffuse optical remission spectra from the mammalian neocortex at visible wavelengths contain spectral features originating from the mitochondria. A new algorithm is presented, based on analytically relating the first differential of the attenuation spectrum to the first differential of the chromophore spectra, that can separate and calculate the oxidation state of cytochrome c as well as the absolute concentration and saturation of hemoglobin. The algorithm is validated in phantoms and then tested on the neocortex of the rat during an anoxic challenge. Implementation of the algorithm will provide detailed information of mitochondrial oxygenation and mitochondrial function in physiological studies of the mammalian brain

CO abundance variations in the Orion molecular cloud

Infrared stellar photometry from the Two Micron All-Sky Survey (2MASS) and spectral line imaging observations of 12CO and 13CO J = 1-0 line emission from the Five College Radio Astronomy Observatory (FCRAO) 14-m telescope are analysed to assess the variation of the CO abundance with physical conditions throughout the Orion A and Orion B molecular clouds. Three distinct Av regimes are identified in which the ratio between the 13CO column density and visual extinction changes corresponding to the photon-dominated envelope, the strongly self-shielded interior, and the cold, dense volumes of the clouds. Within the strongly self-shielded interior of the Orion A cloud, the 13CO abundance varies by 100 per cent with a peak value located near regions of enhanced star formation activity. The effect of CO depletion on to the ice mantles of dust grains is limited to regions with Av > 10 mag and gas temperatures less than ∼20 K as predicted by chemical models that consider thermal evaporation to desorb molecules from grain surfaces.Values of the molecular mass of each cloud are independently derived from the distributions of Av and 13CO column densities with a constant 13CO-to-H2 abundance over various extinction ranges. Within the strongly self-shielded interior of the cloud (Av> 3 mag), 13CO provides a reliable tracer of H2 mass with the exception of the cold, dense volumes where depletion is important. However, owing to its reduced abundance, 13CO does not trace the H2 mass that resides in the extended cloud envelope, which comprises 40-50 per cent of the molecular mass of each cloud. The implied CO luminosity to mass ratios, M/LCO, are 3.2 and 2.9 for Orion A and Orion B, respectively, which are comparable to the value (2.9), derived from γ-ray observations of the Orion region. Our results emphasize the need to consider local conditions when applying CO observations to derive H2 column densities. © 2013 The Authors. Published by Oxford University Press on behalf of the Royal Astronomical Society.This work is supported by grants AST-0838222 and AST-1009049 from the National Science Foundation and a stipend from the Massachusetts Space Grant Consortium. CB is funded in part by the UK Science and Technology Facilities Council grant ST/J001627/1 (From Molecular Clouds to Exoplanets and the ERC grant ERC- 2011-StG 20101014 (LOCALSTAR, both held at the University of Exeter. This publication makes use of data products from the 2MASS, which is a joint project of the University of Massachusetts and the Infrared Processing and Analysis Center/California Institute of Technology, funded by the National Aeronautics and Space Administration and the National Science Foundation. This research has made use of the VizieR catalogue access tool, CDS, Strasbourg, France

World Scientists’ Warning of a Climate Emergency

Scientists have a moral obligation to clearly warn humanity of any catastrophic threat and to “tell it like it is.” On the basis of this obligation and the graphical indicators presented below, we declare, with more than 11,000 scientist signatories from around the world, clearly and unequivocally that planet Earth is facing a climate emergency

Quantification of habitat fragmentation reveals extinction risk in terrestrial mammals

Although habitat fragmentation is often assumed to be a primary driver of extinction, global patterns of fragmentation and its relationship to extinction risk have not been consistently quantified for any major animal taxon. We developed high-resolution habitat fragmentation models and used phylogenetic comparative methods to quantify the effects of habitat fragmentation on the world's terrestrial mammals, including 4,018 species across 26 taxonomic Orders. Results demonstrate that species with more fragmentation are at greater risk of extinction, even after accounting for the effects of key macroecological predictors, such as body size and geographic range size. Species with higher fragmentation had smaller ranges and a lower proportion of high-suitability habitat within their range, andmost high-suitability habitat occurred outside of protected areas, further elevating extinction risk. Our models provide a quantitative evaluation of extinction risk assessments for species, allow for identification of emerging threats in species not classified as threatened, and provide maps of global hotspots of fragmentation for the world's terrestrial mammals. Quantification of habitat fragmentation will help guide threat assessment and strategic priorities for global mammal conservation