1,416 research outputs found

    Mechanisms for current-induced conductivity changes in a conducting polymer

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    A layer of polyethylene dioxythiophene:polystyrene sulfonic acid (PEDT:PSS) spun onto the surface of an inorganic semiconductor forms a highly asymmetric rectifying junction when a small current is applied and can be permanently open circuited with application of a high current density. This allows the polymer/semiconductor junction to function as a write-once-read-many-times memory element. We use x-ray photoelectron spectroscopy and temperature induced conductivity measurements to study the morphological and chemical changes responsible for the large current-induced conductivity changes. It is found that by applying a large current to the organic-inorganic semiconductor rectifying heterojunction structure Au/PEDT:PSS/SiAu∕PEDT:PSS∕Si, the ratio of PEDT+PEDT+ to PSS−PSS− near the interface changes due to phase segregation in the presence of both high electric field (>105 V/cm)(>105V∕cm) and temperature. This leads to a decrease in film conductivity by up to six orders of magnitude from its value in the conductive state.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/87796/2/142109_1.pd

    Geographical Analysis of US Green Sector Industry Concentration

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    This paper analyzes the geographic distribution of “green energy” sector clustering in the lower 48 United States using recent developments in industry concentration analysis. Evidence suggests that the ten green energy subsectors and the aggregate of the firms comprising the green energy sector are regionally concentrated. Positive changes in industry concentration from 2002 to 2006 tended to be greatest in non-metropolitan counties, suggesting comparative advantage with respect to site location for the composite of firms making up these sectors.Agglomeration, Location Quotient, Renewable Energy, Community/Rural/Urban Development, Industrial Organization, Research and Development/Tech Change/Emerging Technologies,

    A Laterally Modulated 2D Electron System in the Extreme Quantum Limit

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    We report on magnetotransport of a two-dimensional electron system (2DES), located 32 nm below the surface, with a surface superlattice gate structure of periodicity 39 nm imposing a periodic modulation of its potential. For low Landau level fillings Μ\nu, the diagonal resistivity displays a rich pattern of fluctuations, even though the disorder dominates over the periodic modulation. Theoretical arguments based on the combined effects of the long-wavelength, strong disorder and the short-wavelength, weak periodic modulation present in the 2DES qualitatively explain the data.Comment: 4 pages, 5 figures. to appear in Phys. Rev. Let

    Fluency Assistance Device

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    Currently about 1% of the world population (~70 million people) have a stutter considered a fluency disorder. Some fluency assistance devices are available for this population, but most are highly expensive or unreliable. Fluency Assistance Device (FAD) seeks to assist a niche community of these individuals for whom therapy has been unsuccessful but are currently depending on a device originally known as the Edinburgh Masker. FAD aims to redesign the masker to be more comfortable for the end user. FAD is developing versions 1.1 and 2.0 of the improved masker. Version 1.1 will update the original masker circuitry with surface mount devices. This will allow a slimmer circuitry enclosure, and enable upgrades of the original as requested. Version 2.0 will use Bluetooth technology and a microcontroller to achieve masker functionality with software code. FAD is now finalizing Version 1.1 and beginning Version 2.0.https://mosaic.messiah.edu/engr2020/1008/thumbnail.jp

    Density functional theory based study of graphene and dielectric oxide interfaces

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    We study the effects of insulating oxides in their crystalline forms on the energy band structure of monolayer and bilayer graphene using a \textit{first principles} density functional theory based electronic structure method and a local density approximation. We consider the dielectric oxides, SiO2_{2} (α\alpha-quartz) and Al2_{2}O3_{3} (alumina or α\alpha-sapphire) each with two surface terminations. Our study suggests that atomic relaxations and resulting equilibrium separations play a critical role in perturbing the linear band structure of graphene in contrast to the less critical role played by dangling bonds that result from cleaving the crystal in a particular direction. We also see that with the addition of a second graphene layer, the Dirac cone is restored for the quartz surface terminations. Alumina needs more than two graphene layers to preserve the Dirac cone. Our results are at best semi-quantitative for the common amorphous forms of the oxides considered. However, crystalline oxides for which our results are quantitative provide an interesting option for graphene based electronics, particularly in light of recent experiments on graphene with crystalline dielectrics (hexagonal BN) that find considerable improvements in transport properties as compared to the those with amorphous dielectrics

    Does browning-induced light limitation reduce fish body growth through shifts in prey composition or reduced foraging rates?

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    Browning of waters, coupled to climate change and land use changes, can strongly affect aquatic ecosystems. Browning-induced light limitation may have negative effects on aquatic consumers via shifts in resource composition and availability and by negatively affecting foraging of consumers relying on vision. However, the extent to which light limitation caused by browning affects fish via either of these two pathways is largely unknown. Here we specifically test if fish growth responses to browning in a pelagic food web are best explained by changes in resource availability and composition due to light limitation, or by reduced foraging rates due to decreased visual conditions. To address this question, we set up a mesocosm experiment to study growth responses of two different fish species to browning and conducted an aquaria experiment to study species-specific fish foraging responses to browning. Furthermore, we used a space-for-time approach to analyse fish body length-at-age across >40 lakes with a large gradient in lake water colour to validate experimental findings on species-specific fish growth responses. With browning, we found an increase in chlorophyll a concentrations, shifts in zooplankton community composition, and a decrease in perch (Perca fluviatilis) but not roach (Rutilus rutilus) body growth. We conclude that fish growth responses are most likely to be linked to the observed shift in prey (zooplankton) composition. In contrast, we found limited evidence for reduced perch, but not roach, foraging rates in response to browning. This suggests that light limitation led to lower body growth of perch in brown waters mainly through shifts in resource composition and availability, perhaps in combination with decreased visibility. Finally, with the lake study we confirmed that perch but not roach body growth and length-at-age are negatively affected by brown waters in the wild. In conclusion, using a combination of experimental and observational data, we show that browning of lakes is likely to (continue to) result in reductions in fish body growth of perch, but not roach, as a consequence of shifts in prey availability and composition, and perhaps reduced foraging
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