498 research outputs found
Two-orbital Hubbard model vs spin Heisenberg model: studies on clusters
We perform exact numeric calculations for the two-orbital Hubbard model on
the four-site cluster. In the limit of large on-site coupling the model becomes
equivalent to the spin Heisenberg model. By comparing energy spectra of
these two models, we quantified the range of interaction parameters for which
the Heisenberg model satisfactorily reproduces the two-orbital Hubbard model.
Then we examined how the spectrum evolves when we are outside of this region,
focusing especially on checking of how it is modified when various ways of
interatomic hoppings of electrons between different orbitals are taken into
account. We finally show how these modifications affect the dependence of
specific heat on temperature.Comment: 8 pages, 7 figures, 2 table
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Capturing UK real estate volitility
Volatility, or the variability of the underlying asset, is one of the key fundamental components of property derivative pricing and in the application of real option models in development analysis. There has been relatively little work on volatility in real terms of its application to property derivatives and the real options analysis. Most research on volatility stems from investment performance (Nathakumaran & Newell (1995), Brown & Matysiak 2000, Booth & Matysiak 2001). Historic standard deviation is often used as a proxy for volatility and there has been a reliance on indices, which are subject to valuation smoothing effects. Transaction prices are considered to be more volatile than the traditional standard deviations of appraisal based indices. This could lead, arguably, to inefficiencies and mis-pricing, particularly if it is also accepted that changes evolve randomly over time and where future volatility and not an ex-post measure is the key (Sing 1998). If history does not repeat, or provides an unreliable measure, then estimating model based (implied) volatility is an alternative approach (Patel & Sing 2000).
This paper is the first of two that employ alternative approaches to calculating and capturing volatility in UK real estate for the purposes of applying the measure to derivative pricing and real option models. It draws on a uniquely constructed IPD/Gerald Eve transactions database, containing over 21,000 properties over the period 1983-2005. In this first paper the magnitude of historic amplification associated with asset returns by sector and geographic spread is looked at. In the subsequent paper the focus will be upon model based (implied) volatility
Bose glass behavior in (YbLu)As representing the randomly diluted quantum spin-1/2 chains
The site-diluted compound (YbLu)As is a scarce
realization of the linear Heisenberg antiferromagnet partitioned into
finite-size segments and is an ideal model compound for studying
field-dependent effects of quenched disorder in the one-dimensional
antiferromagnets. It differentiates from the systems studied so far in two
aspects - the type of randomness and the nature of the energy gap in the pure
sample. We have measured the specific heat of single-crystal
(YbLu)As in magnetic fields up to 19.5 T. The contribution
arising from the magnetic subsystem in an applied magnetic field
perpendicular to the chains is determined. Compared to pure YbAs, for
which indicates a gap opening, for diluted systems a
non-exponential decay is found at low temperatures which is consistent with the
thermodynamic scaling of the specific heat established for a Bose-glass phase.Comment: 8 pages, 17 figures, including supplemental material, accepted for
PRB rapid communicatio
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The favorable kinetics and balance of nebivolol-stimulated nitric oxide and peroxynitrite release in human endothelial cells
Background: Nebivolol is a third-generation beta-blocker used to treat hypertension. The vasodilation properties of nebivolol have been attributed to nitric oxide (NO) release. However, the kinetics and mechanism of nebivolol-stimulated bioavailable NO are not fully understood. Methods: Using amperometric NO and peroxynitrite (ONOO-) nanosensors, β3-receptor (agonist: L-755,507; antagonists: SR59230A and L-748,337), ATP efflux (the mechanosensitive ATP channel blocker, gadolinium) and P2Y-receptor (agonists: ATP and 2-MeSATP; antagonist: suramin) modulators, superoxide dismutase and a NADPH oxidase inhibitor (VAS2870), we evaluated the kinetics and balance of NO and ONOO- stimulated by nebivolol in human umbilical vein endothelial cells (HUVECs). NO and ONOO- were measured with nanosensors (diameter ~ 300 nm) placed 5 ± 2 μm from the cell membrane and ATP levels were determined with a bioluminescent method. The kinetics and balance of nebivolol-stimulated NO and ONOO- were compared with those of ATP, 2-MeSATP, and L-755,507. Results: Nebivolol stimulates endothelial NO release through β3-receptor and ATP-dependent, P2Y-receptor activation with relatively slow kinetics (75 ± 5 nM/s) as compared to the kinetics of ATP (194 ± 10 nM/s), L-755,507 (108 ± 6 nM/s), and 2-MeSATP (105 ± 5 nM/s). The balance between cytoprotective NO and cytotoxic ONOO- was expressed as the ratio of [NO]/[ONOO-] concentrations. This ratio for nebivolol was 1.80 ± 0.10 and significantly higher than that for ATP (0.80 ± 0.08), L-755,507 (1.08 ± 0.08), and 2-MeSATP (1.09 ± 0.09). Nebivolol induced ATP release in a concentration-dependent manner. Conclusion: The two major pathways (ATP efflux/P2Y receptors and β3 receptors) and several steps of nebivolol-induced NO and ONOO- stimulation are mainly responsible for the slow kinetics of NO release and low ONOO-. The net effect of this slow kinetics of NO is reflected by a favorable high ratio of [NO]/[ONOO-] which may explain the beneficial effects of nebivolol in the treatment of endothelial dysfunction, hypertension, heart failure, and angiogenesis
Effect of pressure on synthesis of Pr-doped zirconia powders produced by microwave-driven hydrothermal reaction
A high-pressure microwave reactor was used to study the hydrothermal synthesis of zirconia powders doped with 1 mol % Pr.The synthesis was performed in the pressure range from 2 to 8MPa corresponding to a temperature range from 215◦C to 305◦C.This technology permits a synthesis of nanopowders in short time not limited by thermal inertia of the vessel. Microwave heatingpermits to avoid contact of the reactants with heating elements, and is thus particularly well suited for synthesis of dopednanopowders in high purity conditions. A mixture of ZrO2 particles with tetragonal and monoclinic crystalline phases, about15nm in size, was obtained. The p/T threshold of about 5-6MPa/265–280◦C was necessary to obtain good quality of zirconiapowder. A new method for quantitative description of grain-size distribution was applied, which is based on analysis of the finestructure of the X-ray diffraction line profiles. It permitted to follow separately the effect of synthesis conditions on the grain-size distribution of the monoclinic and tetragonal phases
Effect of Pressure on Synthesis of Pr-Doped Zirconia Powders Produced by Microwave-Driven Hydrothermal Reaction
A high-pressure microwave reactor was used to study the hydrothermal synthesis of
zirconia powders doped with 1 mol % Pr. The synthesis was performed in the pressure range
from 2 to 8 MPa corresponding to a temperature range from 215C∘ to 305C∘. This technology
permits a synthesis of nanopowders in short time not limited by thermal inertia of the vessel.
Microwave heating permits to avoid contact of the reactants with heating elements, and is thus
particularly well suited for synthesis of doped nanopowders in high purity conditions.
A mixture of ZrO2 particles with tetragonal and monoclinic crystalline phases, about 15 nm in size, was obtained.
The p/T threshold of about 5-6 MPa/265–280C∘ was necessary to obtain good quality of
zirconia powder. A new method for quantitative description of grain-size distribution was applied, which is
based on analysis of the fine structure of the X-ray diffraction line profiles. It permitted to
follow separately the effect of synthesis conditions on the grain-size distribution of the
monoclinic and tetragonal phases
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