309 research outputs found
Functional Organic Nanomaterials
π-Conjugated polymers have a wide range of applications such as photovoltaics, light-emitting diodes, and sensors. To gain a better understanding of these systems, monodisperse oligomers can be used as a more simplistic model to generate predictive structural and physical properties of corresponding polymers. A divergent/convergent synthetic approach to synthesis of monodisperse π-conjugated oligomers has been developed. These well-defined, thiophene-containing molecular building blocks have been successfully coupled to a ferrocene hinge, which has been found to be highly efficient in the transport of gold atoms using a gold scanning tunneling microscopy tip.
Carbon nanotubes (CNTs) represent a rare class of materials, which exhibit a number of outstanding properties in a single material system, such as high aspect ratio, small diameter, light weight, high mechanical strength, high electrical and thermal conductivities, and near-IR optical and optoelectronic properties. Aerogels are highly porous, low-density materials comprised of a solid, three-dimensional (3D) nanoscale network fully accessible to ions and molecules. By combining the extraordinary properties of CNTs with those of aerogels, a new class of materials becomes accessible with unique multifunctional material properties. CNT aerogels that are mechanically stable and stiff, highly porous, and exhibit excellent electrical conductivity and large specific surface area have been developed.
CNTs are recognized as the ultimate carbon fibers for high-performance, multifunctional materials, where an addition of only a small amount of CNTs, if engineered appropriately, could lead to simultaneously enhanced mechanical strength and electrical conductivity. For the first time, using core-shell multi-walled CNTs as a filler to increase the dielectric constant and reduce the dielectric loss of nanotube-polymer composites has been demonstrated.
While most efforts in the field of CNT-polymer composites have been focused on passive material properties such as mechanical, electrical, and thermal, there is growing interest in harnessing active material functions such as actuation, sensing, and power generation in designed CNT-polymer materials. The synergy between CNTs and the polymer matrix has been judiciously exploited to create highly desirable active material functions in smart material systems. By incorporating CNTs in a Nafion matrix, multi-shape memory healable composites capable of reversible remote, local, and chemical programming have been developed
Evidence for Different Freeze-Out Radii of High- and Low-Energy Pions Emitted in Au+Au Collisions at 1 GeV/nucleon
Double differential production cross sections of negative and positive pions
and the number of participating protons have been measured in central Au+Au
collisions at 1 GeV per nucleon incident energy. At low pion energies the pi^-
yield is strongly enhanced over the pi^+ yield. The energy dependence of the
pi^-/pi^+ ratio is assigned to the Coulomb interaction of the charged pions
with the protons in the reaction zone. The deduced Coulomb potential increases
with increasing pion c.m. energy. This behavior indicates different freeze-out
radii for different pion energies in the c.m.~frame.Comment: IKDA is the Institute for Nuclear Physics in Darmstadt/German
Enhanced Out-of-plane Emission of K+ Mesons observed in Au+Au Collisions at 1 AGeV
The azimuthal angular distribution of K+ mesons has been measured in Au + Au
collisions at 1 AGeV. In peripheral and semi-central collisions, K+ mesons
preferentially are emitted perpendicular to the reaction plane. The strength of
the azimuthal anisotropy of K+ emission is comparable to the one of pions. No
in-plane flow was found for K+ mesons near projectile and target rapidity.Comment: Accepted for publication in Phys. Rev.Let
Economic space: On the analysis and interpretation of pottery production and distribution
Ceramics are particularly well suited for investigating general patterns of the distribution of premodern products. Archaeometric methods, used to determine raw materials and production techniques, permit the identification of places of production. The work of the research group presented here pursues two objectives: (i) to investigate the usefulness of portable X-ray fluorescence equipment for the analysis of ceramics and (ii) to identify, interpret and study distribution areas of ceramic products in comparative prospective. The paper discusses key economic concepts, sets out the archaeometric methodology and presents initial results in the context of two examples
Pleosporales
One hundred and five generic types of Pleosporales are described and illustrated. A brief introduction and detailed history with short notes on morphology, molecular phylogeny as well as a general conclusion of each genus are provided. For those genera where the type or a representative specimen is unavailable, a brief note is given. Altogether 174 genera of Pleosporales are treated. Phaeotrichaceae as well as Kriegeriella, Zeuctomorpha and Muroia are excluded from Pleosporales. Based on the multigene phylogenetic analysis, the suborder Massarineae is emended to accommodate five families, viz. Lentitheciaceae, Massarinaceae, Montagnulaceae, Morosphaeriaceae and Trematosphaeriaceae
Low-energy cross section of the 7Be(p,g)8B solar fusion reaction from Coulomb dissociation of 8B
Final results from an exclusive measurement of the Coulomb breakup of 8B into
7Be+p at 254 A MeV are reported. Energy-differential Coulomb-breakup cross
sections are analyzed using a potential model of 8B and first-order
perturbation theory. The deduced astrophysical S_17 factors are in good
agreement with the most recent direct 7Be(p,gamma)8B measurements and follow
closely the energy dependence predicted by the cluster-model description of 8B
by Descouvemont. We extract a zero-energy S_17 factor of 20.6 +- 0.8 (stat) +-
1.2 (syst) eV b.Comment: 14 pages including 16 figures, LaTeX, accepted for publication in
Physical Review C. Minor changes in text and layou
Supercooled confined water and the Mode Coupling crossover temperature
We present a Molecular Dynamics study of the single particle dynamics of
supercooled water confined in a silica pore. Two dynamical regimes are found:
close to the hydrophilic substrate molecules are below the Mode Coupling
crossover temperature, , already at ambient temperature. The water closer
to the center of the pore (free water) approaches upon supercooling as
predicted by Mode Coupling Theories. For free water the crossover temperature
and crossover exponent are extracted from power-law fits to both the
diffusion coefficient and the relaxation time of the late region.Comment: To be published, Phys. Rev. Lett., 4 pages, 3 figures, revTeX, minor
changes in the figures, references added, changes in the tex
3DLC: A Comprehensive Model for Personal Health Records Supporting New Types of Medical Applications
A Measurement of the Coulomb Dissociation of 8B at 254 MeV/nucleon and the 8B Solar Neutrino Flux
We have measured the Coulomb dissociation of 8B into 7Be and proton at 254
MeV/nucleon using a large-acceptance focusing spectrometer. The astrophysical
S17 factor for the 7Be(p,gamma)8B reaction at E{c.m.} = 0.25-2.78 MeV is
deduced yielding S17(0)=20.6 \pm 1.2 (exp.) \pm 1.0 (theo.) eV-b.
This result agrees with the presently adopted zero-energy S17 factor obtained
in direct-reaction measurements and with the results of other
Coulomb-dissociation studies performed at 46.5 and 51.2 MeV/nucleon.Comment: paper to be published in Phys. Rev. Lett. 3 figures. New Version
fixes formatting problems with the figures only. There are no other change
Medium Effects in Kaon and Antikaon Production in Nuclear Collisions at Subthreshold Beam Energies
Production cross sections of K and K mesons have been measured in C+C
collisions at beam energies per nucleon below and near the nucleon-nucleon
threshold. At a given beam energy, the spectral slopes of the K mesons are
significantly steeper than the ones of the K mesons. The excitation
functions for K and K mesons nearly coincide when correcting for the
threshold energy. In contrast, the K yield exceeds the K yield by a
factor of about 100 in proton-proton collisions at beam energies near the
respective nucleon-nucleon thresholds.Comment: Accepted for publication in Phys. Rev. Let
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