659 research outputs found
Itinerant and local-moment magnetism in EuCr2As2 single crystals
We report on the crystal structure, physical properties, and electronic
structure calculations for the ternary pnictide compound EuCr2As2. X-ray
diffraction studies confirmed that EuCr2As2 crystalizes in the ThCr2Si2-type
tetragonal structure (space group I4/mmm). The Eu ions are in a stable divalent
state in this compound. Eu moments in EuCr2As2 order magnetically below Tm = 21
K. A sharp increase in the magnetic susceptibility below Tm and the positive
value of the paramagnetic Curie temperature obtained from the Curie-Weiss fit
suggest dominant ferromagnetic interactions. The heat capacity exhibits a sharp
{\lambda}-shape anomaly at Tm, confirming the bulk nature of the magnetic
transition. The extracted magnetic entropy at the magnetic transition
temperature is consistent with the theoretical value Rln(2S+1) for S = 7/2 of
the Eu2+ ion. The temperature dependence of the electrical resistivity
\r{ho}(T) shows metallic behavior along with an anomaly at 21 K. In addition,
we observe a reasonably large negative magneto-resistance (~ -24%) at lower
temperature. Electronic structure calculations for EuCr2As2 reveal a moderately
high density of states of Cr-3d orbitals at the Fermi energy, indicating that
the nonmagnetic state of Cr is unstable against magnetic order. Our density
functional calculations for EuCr2As2 predict a G-type AFM order in the Cr
sublattice. The electronic structure calculations suggest a weak interlayer
coupling of the Eu moments.Comment: 9 pages, 7 figure
Valence Fluctuation in CeMo2Si2C
We report on the valence fluctuation of Ce in CeMoSiC as studied
by means of magnetic susceptibility , specific heat , electrical
resistivity and x-ray absorption spectroscopy. Powder x-ray
diffraction revealed that CeMoSiC crystallizes in
CeCrSiC-type layered tetragonal crystal structure (space group
\textit{P4/mmm}). The unit cell volume of CeMoSiC deviates from the
expected lanthanide contraction, indicating non-trivalent state of Ce ions in
this compound. The observed weak temperature dependence of the magnetic
susceptibility and its low value indicate that Ce ions are in valence
fluctuating state. The formal Ce valence in CeMoSiC
= 3.11 as determined from x-ray absorption spectroscopy
measurement is well bellow the value 3.4 in
tetravalent Ce compound CeO. The temperature dependence of specific heat
does not show any anomaly down to 1.8 K which rules out any magnetic ordering
in the system. The Sommerfeld coefficient obtained from the specific heat data
is = 23.4 mJ/mol\,K. The electrical resistivity follows the
behavior in the low temperature range below 35 K confirming a Fermi
liquid behavior. Accordingly both the Kadowaki Wood ratio and
the Sommerfeld Wilson ratio are in the range expected for
Fermi-liquid systems. In order to get some information on the electronic
states, we calculated the band structure within the density functional theory,
eventhough this approach is not able to treat 4f electrons accurately. The
non- electron states crossing the Fermi level have mostly Mo 4d character.
They provide the states with which the 4f sates are strongly hybridized,
leading to the intermediate valent state.Comment: 18 pages, 10 figures Submitted to Journal of Alloys and Compound
Unconventional magnetism in multivalent charge-ordered YbPtGe probed by Pt- and Yb-NMR
Detailed Pt- and Yb nuclear magnetic resonance (NMR) studies
on the heterogeneous mixed valence system YbPtGe are reported. The
temperature dependence of the Pt-NMR shift indicates the
opening of an unusual magnetic gap below 200\,K. was analyzed by a
thermal activation model which yields an isotropic gap \,K. In contrast, the spin-lattice relaxation rate () does
not provide evidence for the gap. Therefore, an intermediate-valence picture is
proposed while a Kondo-insulator scenario can be excluded. Moreover,
() follows a simple metallic behavior, similar to the reference
compound YPtGe. A well resolved NMR line with small shift is assigned to
divalent Yb. This finding supports the proposed model with two sub-sets
of Yb species (di- and trivalent) located on the Yb2 and Yb1 site of the
YbPtGe lattice.Comment: Submitted in Physical Review B (Rapid Communication
Self-supervised automated wrapper generation for weblog data extraction
Data extraction from the web is notoriously hard. Of the types of resources available on the web, weblogs are becoming increasingly important due to the continued growth of the blogosphere, but remain poorly explored. Past approaches to data extraction from weblogs have often involved manual intervention and suffer from low scalability. This paper proposes a fully automated information extraction methodology based on the use of web feeds and processing of HTML. The approach includes a model for generating a wrapper that exploits web feeds for deriving a set of extraction rules automatically. Instead of performing a pairwise comparison between posts, the model matches the values of the web feeds against their corresponding HTML elements retrieved from multiple weblog posts. It adopts a probabilistic approach for deriving a set of rules and automating the process of wrapper generation. An evaluation of the model is conducted on a dataset of 2,393 posts and the results (92% accuracy) show that the proposed technique enables robust extraction of weblog properties and can be applied across the blogosphere for applications such as improved information retrieval and more robust web preservation initiatives
Lifshitz transitions and quasiparticle de-renormalization in YbRhSi
We study the effect of magnetic fields up to 15 T on the heavy fermion state
of YbRhSi via Hall effect and magnetoresistance measurements down to 50
mK. Our data show anomalies at three different characteristic fields. We
compare our data to renormalized band structure calculations through which we
identify Lifshitz transitions associated with the heavy fermion bands. The Hall
measurements indicate that the de-renormalization of the quasiparticles, {\it
i.e} the destruction of the local Kondo singlets, occurs smoothly while the
Lifshitz transitions occur within rather confined regions of the magnetic
field.Comment: 7 pages, 5 figure
Valence fuctuation and magnetic ordering in EuNi2(P1-xGex)2 single crystals
Unusual phases and phase transitions are seen at the magnetic-nonmagnetic
boundary in Ce, Eu and Yb-based compounds. EuNiP is a very unusual
valence fluctuating Eu system, because at low temperatures the Eu valence stays
close to 2.5 instead of approaching an integer value. Eu valence and thus the
magnetic property in this system can be tuned by Ge substitution in P site as
EuNiGe is known to exhibit antiferromagnetc (AFM) ordering of
divalent Eu moments with = 30 K. We have grown
EuNi(PGe) (0.0 0.5) single crystals and
studied their magnetic, thermodynamic and transport properties. Increasing Ge
doping to 0.4 results in a well-defined AFM ordered state with = 12
K for = 0.5. Moreover, the reduced value of magnetic entropy for = 0.5
at suggests the presence of valance fluctuation/ Kondo effect in this
compound. Interestingly, the specific heat exhibits an enhanced Sommerfeld
coefficient upon Ge doping. Subsequently, electronic structure calculations
lead to a non-integral valence in EuNiP but a stable divalent Eu
state in EuNiGe which is in good agreement with experimental results.Comment: 7 pages, 8 figure
Quasiquartet CEF ground state with possible quadrupolar ordering in the tetragonal compound YbRuGe
e have investigated the magnetic properties of YbRuGe by means of
magnetic susceptibility (T), specific heat C(T) and electrical
resistivity (T) measurements performed on flux grown single crystals. The
Curie-Weiss behavior of (T) along the easy plane, the large magnetic
entropy at low temperatures and the weak Kondo like increase in (T)
proves a stable trivalent Yb state. Anomalies in C(T), (T) and (T)
at T = 10.2 K, T = 6.5 K and T = 5.7 K evidence complex
ordering phenomena, T being larger than the highest Yb magnetic ordering
temperature found up to now. The magnetic entropy just above T amounts to
almost Rln4, indicating that the crystal electric field (CEF) ground state is a
quasiquartet instead of the expected doublet. The behavior at T is rather
unusual and suggest that this transition is related to quadrupolar ordering,
being a consequence of the CEF quasiquartet ground state. The combination of a
quasiquartet CEF ground state, a high ordering temperature, and the relevance
of quadrupolar interactions makes YbRuGe a rather unique system
among Yb based compounds.Comment: 11 pages, 5 figure, submitted to PRB rapi
Quantum criticality in the cubic heavy-fermion system CeIn_{3-x}Sn_x
We report a comprehensive study of CeInSn single crystals close to the antiferromagnetic (AF) quantum critical
point (QCP) at by means of the low-temperature thermal
expansion and Gr\"uneisen parameter. This system represents the first example
for a {\it cubic} heavy fermion (HF) in which can be suppressed
{\it continuously} down to T=0. A characteristic sign change of the Gr\"uneisen
parameter between the AF and paramagnetic state indicates the accumulation of
entropy close to the QCP. The observed quantum critical behavior is compatible
with the predictions of the itinerant theory for three-dimensional critical
spinfluctuations. This has important implications for the role of the
dimensionality in HF QCPs.Comment: Physical Review Letters, to be publishe
Superconductivity in SrFe_(2-x)Co_xAs_2: Internal Doping of the Iron Arsenide Layers
In the electron doped compounds SrFe_(2-x)Co_xAs_2 superconductivity with T_c
up to 20 K is observed for 0.2 < x < 0.4. Results of structure determination,
magnetic susceptibility, electrical resistivity, and specific heat are
reported. The observation of bulk superconductivity in all thermodynamic
properties -- despite strong disorder in the Fe-As layer -- favors an itinerant
picture in contrast to the cuprates and renders a p- or d-wave scenario
unlikely. DFT calculations find that the substitution of Fe by Co (x > 0.3)
leads to the suppression of the magnetic ordering present in SrFe_2As_2 due to
a rigid down-shift of the Fe-3d_(x^2-y^2) related band edge in the density of
states.Comment: 5 pages, 3 figure
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