59 research outputs found
MeSi(CH2SnRO)3 (R = Ph, Me3SiCH2): Building blocks for triangular-shaped diorganotin oxide macrocycles
The syntheses of the novel silicon-bridged tris(tetraorganotin) compounds MeSi(CH2SnPh2R)3 (2, R=Ph; 5, R=Me3SiCH2) and their halogen-substituted derivatives MeSi(CH2SnPh(3ân)In)3 (3, n=1; 4, n=2) and MeSi(CH2SnI2R)3 (6, R=Me3SiCH2) are reported. The reaction of compound 4 with di-t-butyltin oxide (t-Bu2SnO)3 gives the oktokaideka-nuclear (18-nuclear) molecular diorganotin oxide [MeSi(CH2SnPhO)3]6 (7) while the reaction of 6 with sodium hydroxide, NaOH, provides the trikonta-nuclear (30-nuclear) molecular diorganotin oxide [MeSi(CH2SnRO)3]10 (8, R=Me3SiCH2). Both 7 and 8 show belt-like ladder-type macrocyclic structures and are by far the biggest molecular diorganotin oxides reported to date. The compounds have been characterized by elemental analyses, electrospray mass spectrometry (ESI-MS), NMR spectroscopy, 1H DOSY NMR spectroscopy (7), IR spectroscopy (7, 8), and single-crystal X-ray diffraction analysis (2, 7, 8)
Double sign reversal of the vortex Hall effect in YBa2Cu3O7-delta thin films in the strong pinning limit of low magnetic fields
Measurements of the Hall effect and the resistivity in twinned
YBa2Cu3O7-delta thin films in magnetic fields B oriented parallel to the
crystallographic c-axis and to the twin boundaries reveal a double sign
reversal of the Hall coefficient for B below 1 T. In high transport current
densities, or with B tilted off the twin boundaries by 5 degrees, the second
sign reversal vanishes. The power-law scaling of the Hall conductivity to the
longitudinal conductivity in the mixed state is strongly modified in the regime
of the second sign reversal. Our observations are interpreted as strong,
disorder-type dependent vortex pinning and confirm that the Hall conductivity
in high temperature superconductors is not independent of pinning.Comment: 4 pages, 4 figure
Facets of the Fully Mixed Nash Equilibrium Conjecture
In this work, we continue the study of the many facets of the Fully Mixed Nash Equilibrium Conjecture, henceforth abbreviated as the FMNE Conjecture, in selfish routing for the special case of n identical users over two (identical) parallel links. We introduce a new measure of Social Cost, defined to be the expectation of the square of the maximum congestion on a link; we call it Quadratic Maximum Social Cost. A Nash equilibrium is a stable state where no user can improve her (expected) latency by switching her mixed strategy; a worst-case Nash equilibrium is one that maximizes Quadratic Maximum Social Cost. In the fully mixed Nash equilibrium, allmixed strategies achieve full support. Formulated within this framework is yet another facet of the FMNE Conjecture, which states that the fully mixed Nash equilibrium is the worst-case Nash equilibrium. We present an extensive proof of the FMNE Conjecture; the proof employs a mixture of combinatorial arguments and ana-lytical estimations. Some of these analytical estimations are derived through some new bounds on generalized medians of the binomial distribution [22] we obtain, which are of independent interest.
Mammalian Sperm Head Formation Involves Different Polarization of Two Novel LINC Complexes
Background: LINC complexes are nuclear envelope bridging protein structures formed by interaction of SUN and KASH proteins. They physically connect the nucleus with the peripheral cytoskeleton and are critically involved in a variety of dynamic processes, such as nuclear anchorage, movement and positioning and meiotic chromosome dynamics. Moreover, they are shown to be essential for maintaining nuclear shape. Findings: Based on detailed expression analysis and biochemical approaches, we show here that during mouse sperm development, a terminal cell differentiation process characterized by profound morphogenic restructuring, two novel distinctive LINC complexes are established. They consist either of spermiogenesis-specific Sun3 and Nesprin1 or Sun1g, a novel non-nuclear Sun1 isoform, and Nesprin3. We could find that these two LINC complexes specifically polarize to opposite spermatid poles likely linking to sperm-specific cytoskeletal structures. Although, as shown in co-transfection/ immunoprecipitation experiments, SUN proteins appear to arbitrarily interact with various KASH partners, our study demonstrates that they actually are able to confine their binding to form distinct LINC complexes. Conclusions: Formation of the mammalian sperm head involves assembly and different polarization of two novel spermiogenesis-specific LINC complexes. Together, our findings suggest that theses LINC complexes connect the differentiating spermatid nucleus to surrounding cytoskeletal structures to enable its well-directed shaping and elongation
The origin and composition of carbonatite-derived carbonate-bearing fluorapatite deposits
Carbonate-bearing fluorapatite rocks occur at over 30 globally distributed carbonatite complexes and represent a substantial potential supply of phosphorus for the fertiliser industry. However, the process(es) involved in forming carbonate-bearing fluorapatite at some carbonatites remain equivocal, with both hydrothermal and weathering mechanisms inferred. In this contribution, we compare the paragenesis and trace element contents of carbonate-bearing fluorapatite rocks from the Kovdor, Sokli, Bukusu, CatalĂŁo I and Glenover carbonatites in order to further understand their origin, as well as to comment upon the concentration of elements that may be deleterious to fertiliser production. The paragenesis of apatite from each deposit is broadly equivalent, comprising residual magmatic grains overgrown by several different stages of carbonate-bearing fluorapatite. The first forms epitactic overgrowths on residual magmatic grains, followed by the formation of massive apatite which, in turn, is cross-cut by late euhedral and colloform apatite generations. Compositionally, the paragenetic sequence corresponds to a substantial decrease in the concentration of rare earth elements (REE), Sr, Na and Th, with an increase in U and Cd. The carbonate-bearing fluorapatite exhibits a negative Ce anomaly, attributed to oxic conditions in a surficial environment and, in combination with the textural and compositional commonality, supports a weathering origin for these rocks. Carbonate-bearing fluorapatite has Th contents which are several orders of magnitude lower than magmatic apatite grains, potentially making such apatite a more environmentally attractive feedstock for the fertiliser industry. Uranium and cadmium contents are higher in carbonate-bearing fluorapatite than magmatic carbonatite apatite, but are much lower than most marine phosphorites
α-optimal sampling plans for lot-by-lot defects inspection
Defects Inspection, Single Sampling Plan, Lot-by-Lot Inspection, Linear Cost Model, Î-Minimax Principle,
TypeA operating characteristic functions of defects sampling plans
Defects inspection, single sampling plan, TypeA/typeB OC,
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