47 research outputs found
Polarized far-infrared and Raman spectra of SrCuO2 single crystals
We measured polarized far-infrared reflectivity and Raman scattering spectra
of SrCuO single crystals. The frequencies for infrared-active modes were
determined using an oscillator-fitting procedure of reflectivity data. The
Raman spectra were measured at different temperatures using several laser
energies . In addition to eight of twelve Raman active modes,
predicted by factor-group analysis, we observed a complex structure in the
Raman spectra for polarization parallel to the {\bf c}-axis, which consists of
Raman-allowed A symmetry modes, and B LO infrared-active
(Raman-forbidden) modes of the first and higher order as well as their
combinations. The Raman-forbidden modes have a stronger intensity at higher
than the Raman-allowed ones. In order to explain this resonance
effect, we measured the dielectric function and optical reflection spectra of
SrCuO in the visible range. We show that the Raman-allowed A symmetry
modes are resonantly enhanced when a laser energy is close to , while
Raman-forbidden (IR-active) modes resonate strongly for laser line energies
close to the electronic transition of higher energy gaps.Comment: to be published in Physica
Determinative Role of the Jahn-Teller Disorder in the Raman Scattering of Mixed-Valence Manganites
The mixed-valence perovskitelike manganites are characterized by unique
interrelation of Jahn-Teller distortions, electric and magnetic properties. The
Jahn-Teller distortion follows the Mn(3+)->Mn(4+) charge transfer with some
delay. Its development depends on the lifetime of Mn in (3+) state, governed by
the Mn(4+)/Mn(3+) ratio and magnetic correlation. The non-coherence of
Jahn-Teller distortions in orthorhombic mixed-valence manganites and
rhombohedral RMnO3 (R = rare earth) results in oxygen disorder. We demonstrate
that the Raman spectra in this case are dominated by disorder-induced bands
reflecting the oxygen partial phonon density of states (PDOS). The PDOS origin
of the main Raman bands in insulating phases of such compounds is evidenced by
the similar lineshape of experimental spectra and calculated smeared PDOS and
disappearance of the PDOS bands in ordered ferromagnetic metallic phase.Comment: 4 pages, 3 figure
Comparative Raman Studies of Sr2RuO4, Sr3Ru2O7 and Sr4Ru3O10
The polarized Raman spectra of layered ruthenates of the Srn+1RunO3n+1
(n=1,2,3) Ruddlesden-Popper series were measured between 10 and 300 K. The
phonon spectra of Sr3Ru2O7 and Sr4Ru3O10 confirmed earlier reports for
correlated rotations of neighboring RuO6 octahedra within double or triple
perovskite blocks. The observed Raman lines of Ag or B1g symmetry were assigned
to particular atomic vibrations by considering the Raman modes in simplified
structures with only one double or triple RuO6 layer per unit cell and by
comparison to the predictions of lattice dynamical calculations for the real
Pban and Pbam structures. Along with discrete phonon lines, a continuum
scattering, presumably of electronic origin, is present in the zz, xx and xy,
but not in the x'y' and zx spectra. Its interference with phonons results in
Fano shape for some of the lines in the xx and xy spectra. The temperature
dependencies of phonon parameters of Sr3Ru2O7 exhibit no anomaly between 10 and
300 K where no magnetic transition occurs. In contrast, two B1g lines in the
spectra of Sr4Ru3O10, corresponding to oxygen vibrations modulating the Ru-O-Ru
bond angle, show noticeable hardening with ferromagnetic ordering at 105 K,
thus indicating strong spin-phonon interaction.Comment: 9 pages, 12 figure
Gold catalysts supported on ceria doped by rare earth metals for water gas shift reaction: Influence of the preparation method
Cataloged from PDF version of article.Gold catalysts based on ceria, doped by various RE metals (La, Sm, Gd, Yb, Y) were studied. The influence of the preparation methods on structure, properties and catalytic activity in the WGS reaction was investigated. The catalysts' supports were prepared using two different methods: co-precipitation (CP) and mechanochemical activation (MA). The catalysts were tested in a wide temperature interval without and after reactivation. All samples were characterized using a combination of X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), Raman spectroscopy (RS) and X-ray photoelectron spectroscopy (XPS) and TPR. It was found that the catalytic activity of MA catalysts is higher than CP ones. The gold catalysts based on ceria doped by Yb and Sm exhibited the highest activity. After reactivation in air the MA samples almost kept the WGS activity same, while the CP catalysts increased it. The catalysts of a single- and double-phase structure are formed as a result of CP and MA preparation, respectively. There are no big differences in the gold particles size (2-3 nm) depending on dopants and on the preparation techniques. The RS spectra analysis indicates that most probably the oxygen vacancies are adjacent to Me(3+) dopant and the ceria structure seems to be better ordered than in the case of alumina as a dopant. There is no distinct correlation between reducibility and WGS activity. The XPS analysis disclose positively charged gold particles in addition to metallic gold within a surface region of fresh samples and only metallic gold on the samples after catalytic processing. There is no simple correlation between the concentration of Ce(3+) in the samples and their WGS activity. (C) 2009 Elsevier B.V. All rights reserved
Phonons and Magnetic Excitations in Mott-Insulator LaTiO
The polarized Raman spectra of stoichiometric LaTiO (T K) were
measured between 6 and 300 K. In contrast to earlier report on half-metallic
LaTiO, neither strong background scattering, nor Fano shape of the
Raman lines was observed. The high frequency phonon line at 655 cm
exhibits anomalous softening below T: a signature for structural
rearrangement. The assignment of the Raman lines was done by comparison to the
calculations of lattice dynamics and the nature of structural changes upon
magnetic ordering are discussed. The broad Raman band, which appears in the
antiferromagnetic phase, is assigned to two-magnon scattering. The estimated
superexchange constant meV is in excellent agreement with the
result of neutron scattering studies.Comment: 4 pages, 5 figure
Optical studies of gap, hopping energies and the Anderson-Hubbard parameter in the zigzag-chain compound SrCuO2
We have investigated the electronic structure of the zigzag ladder (chain)
compound SrCuO2 combining polarized optical absorption, reflection,
photoreflectance and pseudo-dielectric function measurements with the model
calculations. These measurements yield an energy gap of 1.42 eV (1.77 eV) at
300 K along (perpendicular) to the Cu-O chains. We have found that the lowest
energy gap, the correlation gap, is temperature independent. The electronic
structure of this oxide is calculated using both the
local-spin-density-approximation with gradient correction method, and the
tight-binding theory for the correlated electrons. The calculated density of
electronic states for non-correlated and correlated electrons shows
quasi-one-dimensional character. The correlation gap values of 1.42 eV
(indirect transition) and 1.88 eV (direct transition) have been calculated with
the electron hopping parameters t = 0.30 eV (along a chain), t_yz = 0.12 eV
(between chains) and the Anderson-Hubbard repulsion on copper sites U= 2.0 eV.
We concluded that SrCuO_2 belongs to the correlated-gap insulators.Comment: 24 pages, 8 figures, to be published in Phys.Rev.
Magnetic excitations in SrCu2O3: a Raman scattering study
We investigated temperature dependent Raman spectra of the one-dimensional
spin-ladder compound SrCu2O3. At low temperatures a two-magnon peak is
identified at 3160+/-10 cm^(-1) and its temperature dependence analyzed in
terms of a thermal expansion model. We find that the two-magnon peak position
must include a cyclic ring exchange of J_cycl/J_perp=0.09-0.25 with a coupling
constant along the rungs of J_perp approx. 1215 cm^(-1) (1750 K) in order to be
consistent with other experiments and theoretical results.Comment: 4 pages, 3 figure
Gold catalysts supported on ceria doped by rare earth metals for water gas shift reaction: Influence of the preparation method
Gold catalysts based on ceria, doped by various RE metals (La, Sm, Gd, Yb, Y) were studied. The influence of the preparation methods on structure, properties and catalytic activity in the WGS reaction was investigated. The catalysts' supports were prepared using two different methods: co-precipitation (CP) and mechanochemical activation (MA). The catalysts were tested in a wide temperature interval without and after reactivation. All samples were characterized using a combination of X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), Raman spectroscopy (RS) and X-ray photoelectron spectroscopy (XPS) and TPR. It was found that the catalytic activity of MA catalysts is higher than CP ones. The gold catalysts based on ceria doped by Yb and Sm exhibited the highest activity. After reactivation in air the MA samples almost kept the WGS activity same, while the CP catalysts increased it. The catalysts of a single- and double-phase structure are formed as a result of CP and MA preparation, respectively. There are no big differences in the gold particles size (2-3 nm) depending on dopants and on the preparation techniques. The RS spectra analysis indicates that most probably the oxygen vacancies are adjacent to Me3+ dopant and the ceria structure seems to be better ordered than in the case of alumina as a dopant. There is no distinct correlation between reducibility and WGS activity. The XPS analysis disclose positively charged gold particles in addition to metallic gold within a surface region of fresh samples and only metallic gold on the samples after catalytic processing. There is no simple correlation between the concentration of Ce3+ in the samples and their WGS activity. © 2009 Elsevier B.V. All rights reserved
Magnetic and Charge Correlations in La{2-x-y}Nd_ySr_xCuO_4: Raman Scattering Study
Two aspects in connection with the magnetic properties of
La_{2-x-y}Nd_ySr_xCuO_4 single crystals are discussed. The first is related to
long wavelength magnetic excitations in x = 0, 0.01, and 0.03 La_{2-x}Sr_xCuO_4
detwinned crystals as a function of doping, temperature and magnetic field. Two
magnetic modes were observed within the AF region of the phase diagram. The one
at lower energies was identified with the spin-wave gap induced by the
antisymmetric DM interaction and its anisotropic properties in magnetic field
could be well explained using a canonical form of the spin Hamiltonian. A new
finding was a magnetic field induced mode whose dynamics allowed us to discover
a spin ordered state outside the AF order which was shown to persist in a 9 T
field as high as 100 K above the N\'eel temperature T_N for x = 0.01. For these
single magnon excitations we map out the Raman selection rules in magnetic
fields and demonstrate that their temperature dependent spectral weight is
peaked at the N\'eel temperature. The second aspect is related to phononic and
magnetic Raman scattering in La_{2-x-y}Nd_ySr_xCuO_4 with three doping
concentrations: x = 1/8, y = 0; x = 1/8, y = 0.4; and x = 0.01, y = 0. We
observed that around 1/8 Sr doping and independent of Nd concentration there
exists substantial disorder in the tilt pattern of the CuO_6 octahedra in both
the orthorhombic and tetragonal phases which persist down to 10 K and are
coupled to bond disorder in the cation layers. The weak magnitude of existing
charge/spin modulations in the Nd doped structure did not allow us to detect
specific Raman signatures on lattice dynamics or two-magnon scattering around
2200 cm-1.Comment: 26 pages, 22 figure
Nonlinear phononics: A new ultrafast route to lattice control
To date, two types of coupling between electromagnetic radiation and a
crystal lattice have been identified experimentally. One is direct, for
infrared (IR)-active vibrations that carry an electric dipole. The second is
indirect, it occurs through intermediate excitation of the electronic system
via electron-phonon coupling, as in stimulated Raman scattering. Nearly 40
years ago, proposals were made of a third path, referred to as ionic Raman
scattering (IRS). It was posited that excitation of an IR-active phonon could
serve as the intermediate state for a Raman scattering process relying on
lattice anharmonicity as opposed to electron phonon interaction. In this paper,
we report an experimental demonstration of ionic Raman scattering and show that
this mechanism is relevant to optical control in solids. The key insight is
that a rectified phonon field can exert a directional force onto the crystal,
inducing an abrupt displacement of the atoms from the equilibrium positions
that could not be achieved through excitation of an IR-active vibration alone,
for which the force is oscillatory. IRS opens up a new direction for the
coherent control of solids in their electronic ground state, different from
approaches that rely on electronic excitations.Comment: 10 manuscript pages, 3 figure