BAERLIN2014 - stationary measurements and source apportionment at an urban background station in Berlin, Germany

The Berlin Air quality and Ecosystem Research: Local and long-range Impact of anthropogenic and Natural hydrocarbons (BAERLIN2014) campaign was conducted during the 3 summer months (June–August) of 2014. During this measurement campaign, both stationary and mobile measurements were undertaken to address complementary aims. This paper provides an overview of the stationary measurements and results that were focused on characterization of gaseous and particulate pollution, including source attribution, in the Berlin–Potsdam area, and quantification of the role of natural sources in determining levels of ozone and related gaseous pollutants. Results show that biogenic contributions to ozone and particulate matter are substantial. One indicator for ozone formation, the OH reactivity, showed a 31% (0.82±0.44s−1) and 75% (3.7±0.90s−1) contribution from biogenic non-methane volatile organic compounds (NMVOCs) for urban background (2.6±0.68s−1) and urban park (4.9±1.0s−1) location, respectively, emphasizing the importance of such locations as sources of biogenic NMVOCs in urban areas. A comparison to NMVOC measurements made in Berlin approximately 20 years earlier generally show lower levels today for anthropogenic NMVOCs. A substantial contribution of secondary organic and inorganic aerosol to PM10 concentrations was quantified. In addition to secondary aerosols, source apportionment analysis of the organic carbon fraction identified the contribution of biogenic (plant-based) particulate matter, as well as primary contributions from vehicles, with a larger contribution from diesel compared to gasoline vehicles, as well as a relatively small contribution from wood burning, linked to measured levoglucosan

Black Carbon measurements in Germany between 1994 and 2014, link to netCDF files

Lately, black carbon (BC) has received significant attention due to its climate-warming properties and adverse health effects. Nevertheless, long-term observations in urban areas are scarce, most likely because BC monitoring is not required by environmental legislation. This, however, handicaps the evaluation of air quality models which can be used to assess the effectiveness of policy measures which aim at reducing BC concentrations. Here, we present a new dataset of atmospheric BC measurements from Germany constructed from over six million measurements at over 170 stations. Data covering the period between 1994 and 2014 were collected from twelve German federal states and the federal Environment Agency (UBA), quality checked and harmonized into a database with comprehensive metadata. The final data in original time resolution are available for download (link will follow). Though assembled in a consistent way, the dataset is characterized by differences in (a) measurement methodologies for determining evolved carbon and optical absorption, (b) covered time periods, and (c) temporal resolutions that ranged from half hourly to 6-daily measurements. Usage of this dataset thus requires a careful consideration of these differences. Our analysis focuses on 2009, the year with the largest data coverage obtained with one single methodology, as well as on the relative changes in long-term trends over ten years. Stations are grouped into the following categories: urban background, traffic, industrial, and rural. For 2009, we find that BC concentrations at traffic sites were at least twice as high as at urban background, industrial and rural sites. Weekly cycles are most prominent at traffic stations, however, the presence of differences in concentrations during the week and on weekends at other station types suggests that traffic plays an important role throughout the full network. Generally higher concentrations and weaker weekly cycles during the winter months point towards the influence of other sources such as domestic heating. Regarding the long-term trends, advanced statistical techniques allow us to account for instrumentation changes and to separate seasonal and long-term changes in our dataset. Analysis shows a downward trend in BC at nearly all locations and in all conditions, with a high level of confidence for the period of 2005-2014. In depth analysis indicates that background BC is decreasing slowly, while the occurrences of high concentrations are decreasing more rapidly. In summary, legislation - both in Europe and locally - to reduce particulate emissions and indirectly BC appear to be working, based on this analysis. Human health and climate impacts are likely to be diminished because of the improvements in air quality

Long-term monitoring of black carbon across Germany

Lately, black carbon (BC) has received significant attention due to its climate-warming properties and adverse health effects. Nevertheless, long-term observations in urban areas are scarce, most likely because BC monitoring is not required by environmental legislation. This, however, handicaps the evaluation of air quality models which can be used to assess the effectiveness of policy measures which aim to reduce BC concentrations. Here, we present a new dataset of atmospheric BC measurements from Germany constructed from over six million measurements at over 170 stations. Data covering the period between 1994 and 2014 were collected from twelve German Federal States and the Federal Environment Agency, quality checked and harmonized into a database with comprehensive metadata. The final data in original time resolution are available for download (https://doi.org/10.1594/PANGAEA.881173). Though assembled in a consistent way, the dataset is characterized by differences in (a) measurement methodologies for determining evolved carbon and optical absorption, (b) covered time periods, and (c) temporal resolutions that ranged from half hourly to measurements every 6th day. Usage and interpretation of this dataset thus requires a careful consideration of these differences. Our analysis focuses on 2009, the year with the largest data coverage with one single methodology, as well as on the relative changes in long-term trends over ten years. For 2009, we find that BC concentrations at traffic sites were at least twice as high as at urban background, industrial and rural sites. Weekly cycles are most prominent at traffic stations, however, the presence of differences in concentrations during the week and on weekends at other station types suggests that traffic plays an important role throughout the full network. Generally higher concentrations and weaker weekly cycles during the winter months point towards the influence of other sources such as domestic heating. Regarding the long-term trends, advanced statistical techniques allow us to account for instrumentation changes and to separate seasonal and long-term changes in our dataset. Analysis shows a downward trend in BC at nearly all locations and in all conditions, with a high level of confidence for the period of 2005–2014. In depth analysis indicates that background BC is decreasing slowly, while the occurrences of high concentrations are decreasing more rapidly. In summary, legislation – both in Europe and locally – to reduce particulate emissions and indirectly BC appear to be working, based on this analysis. Adverse human health and climate impacts are likely to be diminished because of the improvements in air quality

BAERLIN2014 - stationary measurements and source apportionment at an urban background station in Berlin, Germany

The Berlin Air quality and Ecosystem Research: Local and long-range Impact of anthropogenic and Natural hydrocarbons (BAERLIN2014) campaign was conducted during the three summer months (June–August) of 2014. During this measurement campaign, both stationary and mobile measurements were undertaken to address complementary aims. This paper provides an overview of the stationary measurements and results that were focused on characterization of gaseous and particulate pollution, including source attribution, in the Berlin-Potsdam area, and quantification of the role of natural sources in determining levels of ozone and related gaseous pollutants. Results show that biogenic contributions to ozone and particulate matter are substantial. One indicator for ozone formation, the OH reactivity, showed a 31 % (0.82 ± 0.44 s−1) and 75 % (3.7 ± 0.90 s−1) contribution from biogenic NMVOCs for urban background (2.6 ± 0.68 s−1) and urban park (4.9 ± 1.0 s−1) location, respectively, emphasizing the importance of such locations as sources of biogenic NMVOCs in urban areas. A comparison to NMVOC measurements made in Berlin ca. 20 years earlier generally show lower levels today for anthropogenic NMVOCs. A substantial contribution of secondary organic and inorganic aerosol to PM10 concentrations was quantified. In addition to secondary aerosols, source apportionment analysis of the organic carbon fraction identified the contribution of biogenic (plant-based) particulate matter, as well as primary contributions from vehicles, with a larger contribution from diesel compared to gasoline vehicles, as well as a relatively small contribution from wood burning, linked to measured levoglucosan