A match coefficient approach for damage imaging in structural components by ultrasonic synthetic aperture focus

Ultrasonic Synthetic Aperture Focus (SAF) techniques are commonly used to image structural defects. In this paper, a variation of SAF based on ideas borrowed from Matched Field Processing (MFP) is evaluated to reduce artifacts and sidelobes of the resulting images. In particular, instead of considering the full RF ultrasonic waveforms for the SAF time backpropagation, only selected features from the waveforms are utilized to form a “data vector” and a “replica” (expected) vector of MFP. These vectors are adaptive for the pair of transmitter-receiver and the focus point. The image is created as a matched filter between these two vectors. Experimental results are shown for an isotropic and homogenous metallic plate with simulated defects, probed by six piezoelectric patches used as receivers or transmitters

A simple and sensitive gas chromatography–electron capture detection method for analyzing perfluorocarbon tracers in soil gas samples for storage of carbon dioxide

Co-injection of a conservative tracer during the geological sequestration of CO2 can imprint a marker to the injected gas that can be easily recognized during soil gas surveys in case of CO2 leakage from the reservoir toward the surface. In this work, an ultra-trace detection method, based on gas chromatography with electron capture detection for analyzing perfluorocarbon tracers (PFTs) in soil gas samples was optimized. Three totally fluorinated cycloalcane compounds consisting of five and six atom carbon rings were selected for this purpose. We evaluated the feasibility of collecting PFTs on adsorbent tube packed with a commercial graphitized carbon black (Carbotrap™ 100) sampling 2 L of soil gas. The sorbent tubes were then analyzed by using a two-stage thermal desorption process. The developed method allows to quickly determine these compounds at very low fL/L level, method identification limits ranged from 1.3 to 5.8 fL/L. Moreover, it shows good precision, evaluated by within-day and between-day studies. A preliminary survey of the PFT soil gas background concentrations, conducted by analyzing some soil gas samples collected in two different areas in Central Italy and in the Po Plain, ascertained the PFT background concentration lower than MIL

Theoretical Estimation of CO2 Compression and Transport Costs for an Hypothetical Carbon and Capture & Storage Requalification of the Saline Joniche Power Plant Project

SEI S.p.a. presented a project to build a 1320 MW coal-fired power plant in Saline Joniche, on the Southern tip of Calabria Region, Italy, in 2008. A gross early evaluation about the possibility to add CCS (CO2 Capture & Storage) was performed too. The project generated widespread opposition among environmental associations, citizens and local institutions in that period, against the coal use to produce energy, as a consequence of its GHG clima-alterating impact. Moreover the CCS (also named Carbon Capture & Storage or more recently CCUS: Carbon Capture-Usage-Storage) technology was at that time still an unknown and “mysterious” solution for the GHG avoiding to the atmosphere.   The present study concerns the sizing of the compression and transportation system of the CCS section, included in the project presented at the time by SEI Spa; the sizing of the compression station and the pipeline connecting the plant to the possible Fosca01 offshore injection site previously studied as a possible storage solution, as part of a coarse screening of CO2 storage sites in the Calabria Region. This study takes into account the costs of construction, operation and maintenance (O&M) of both the compression plant and the sound pipeline, considering the gross static storage capacity of the Fosca01 reservoir as a whole as previously evaluated

The application of soil gas technique to geothermal exploration:

Geochemical studies were conducted throughout soil gas and flux surveying for locating both permeable zones in buried reservoirs and the presence of possible gaseous haloes linked to active geothermal systems. In this work we focused our interest on the distribution of soil gas concentrations (Rn, Th, He, H2, O2, N2, CO2, CH4 and H2S) in the soil air of the Tetitlan area considered a potential thermal field and characterized by scarcity of surface manifestations. Radon is used as a tracer gas to provide a qualitative idea of gas transfer (velocity and flux), carbon dioxide and methane are believed to act as carriers for other gases (i.e., Rn and He), helium and hydrogen are used as shallow signals of crustal leaks along faults (Ciotoli et al., 2005). Methane is also considered both a characteristic biogenic indicator of organic matter deposits and a tracer of major crustal discontinuity. A total of 154 soil gas samples were collected in an area of about 80 square kilometres. The same area was investigated throughout a total of 346 of CO2 and CH4 flux measurements

Development of groundwater radon continuous monitors: Comparison between α scintillation and γ spectrometry systems

Two temporised continuous monitoring systems, designed to measure the radon concentration in natural environments, mainly groundwater, were assembled, tested and cross-check compared, evaluating the background noise, sensitivity, calibration values and soundest application in the Earth Science framework. The two systems have been customised by DINCE Laboratory, based on best-fitting criteria selected according to the ING laboratory, partially in the frame of two EC funded, Geochemical Seismic Zonation (GSZ) and Automatic Geochemical Monitoring of Volcanoes, addressed to earthquake prediction research and prototype developing, aimed to seismic and volcanic risks surveillance. Following best-fitting criteria of the radon monitoring aimed to natural risk research, both systems are operative by discrete temporised sampling of an aliquot of groundwater, with a minimal interval of six hours. During their functioning at the ENEA Centre of Frascati (Rome), the test-site chosen, both systems provided a continuous and reliable response

Development of an Italian catalogue of potential CO2storage sites: an approach from deep wells data

Stabilize and reduce the atmospheric concentration of anthropogenic greenhouse gases is one of the principal goal that have to be accomplished in short time, in order to reduce the climate changes and the global warming, following the World Energy Outlook 2007 program by IEA. The most promising remedy, proposed for large CO2 sources like thermoelectric power plants, refineries and cement industries, is to separate the flue gas capturing the CO2 and to store it into deep sub-surface geological reservoirs, such as deep saline aquifers, depleted oil and gas fields and unminable coal beds. Among these options, deep saline aquifers are considered the reservoirs with the larger storage potentiality, as a consequence of a wide availability with respect to deep coal seems, depleted oil fields and gas reservoirs. The identification of a possible storage site necessarily passes through the demonstration that CO2 can be injected in extremely safe conditions into geological deep formations, with impermeable caprock above the aquifer/s, which physic-chemical-mineralogical conditions are useful to a better mineral and solubility trapping as well as the hydrodynamic or physical/ structural ones. In order to support the identification of potential storage reservoirs in Italy, INGV jointly with CESI RICERCA S.p.A. accomplished a detailed reworking of available geological, geophysical, geochemical and seismological data, in order to support the existing European GESTCO as well as the CO2GeoCapacity projects. Aim of this work is to establish some site selection criteria to demonstrate the possibility of the geological storage of CO2 in Italy, even if it is located in an active geodynamical domain. This research started from the study of 7575 wells drilled on Italian territory during the last 50 years for gas/oil and geothermal exploration. Among this data-set as a whole, only 1700 wells (deeper than 800 m) have been selected. Only 1290 of these wells have a public-available composite log and fit with the basic prerequisites for CO2 storage potential, mostly as deep saline aquifer/s presence. Wells data have been organized into a geodatabase containing information about the nature and the thickness of geological formations, the presence of fresh, saline or brackish water, brine, gas and oil, the underground temperature, the permeability, porosity and geochemical characteristics of the caprock and the reservoirs lithologies. Available maps, seismic and geological profiles containing or closer to the analyzed wells have been catalogued too. In order to constrain the supercritical behaviour of the CO2 and to prevent the escape of gaseous CO2 to the surface, a first evaluation of the caprock presence and quality has been done on these selected wells. Using a numerical parameterization of the caprock lithologies, a “Caprock Quality Factor” (Fbp) has been defined, which clustered the wells into 5 different classes of caprock impermeability (ranging between the lowest 1 to highest 5). The analysis shows that more than 50% of the selected wells have an Fbp Factor between 4 and 5 (good and optimal quality of caprock), and are mostly located in foredeep basins of the Alps-Apenninic Chain. The geodatabase also includes: i) the seismogenetic sources (INGV DISS 3.0.4 Database of Individual Seismogenetic Sources), ii) an elaboration of seismic events catalogues (INGV CFTI, CPTI04, NT4.1), iii) the Diffuse Degassing Structures (DDS), as part of the INGV project V5 diffuse degassing in Italy geodatabase, considered as “CO2 analogue” field-tests, iv) the distribution of the thermal anomalies on the Italian Territory, linked to the presence of volcanic CO2 emissions, in order to consider the CO2 diffuse degassing risk assessment on the Italian territory Successively it has been created a geodatabase on the nature and quality of deep aquifers for the high-ranking wells sub-dataset (where the aquifers data are available), containing the following parameters: i) presence of one or more aquifers deeper than 800 meters; ii) thickness of the aquifer/s; iii) lithology of the reservoir/s; iv) available chemical analysis; v) distance from closer power plants or other anthropogenic CO2 sources.The final aim of these work is to help to find potential areas in Italy where CO2 storage feasibility studies can be done. In these cases it is necessary to implement the knowledge by: i) better evaluation of saline aquifer quality; ii) estimation of CO2 storage capacity by 3D-modeling of deep crustal structures; iii) fluid-dynamic and geochemical modelling of water-rock-CO2 interaction paths

An approach to the geochemical modelling of water-rock interaction in CO2 storage geological reservoirs: the Weyburn Project (Canada) case study

Geological storage is one of the most promising technologies for reducing anthropogenic atmospheric emissions of CO2. Among the several CO2 storage techniques, sequestration in deep-seated saline aquifers implies four processes: a) supercritical fluid into geologic structure (physical trapping), b) dissolved CO2(aq) due to very long flow path (hydrodynamic trapping), c) dissolved CO2(aq) (solubility trapping), and d) secondary carbonates (mineral trapping). The appealing concept that CO2 can permanently be retained underground has prompted several experimental studies in Europe and North America sponsored by IEA GHG R&D, EU and numerous international industrials and governments, the most important project being the International Energy Agency Weyburn CO2 Monitoring & Storage, an EnCana’s CO2 injection EOR project at Weyburn (Saskatchewan, Canada). Owing to the possible risks associated to this technique, numerical modelling procedures of geochemical processes are necessary to investigate the short- to long-term consequences of CO2 storage. Assumptions and gap-acceptance are made to reconstruct the reservoir conditions (pressure, pH, chemistry, and mineral assemblage), although most strategic geochemical parameters of deep fluids are computed by a posteriori procedure due to the sampling collection at the wellhead, i.e. using depressurised aliquots. In this work a new approach to geochemical model capable of to reconstruct the reservoir chemical composition (T, P, boundary conditions and pH) is proposed using surface analytical data to simulate the short-medium term reservoir evolution during and after the CO2 injection. The PRHEEQC (V2.11) Software Package via thermodynamic corrections to the code default database has been used to obtain a more realistic modelling. The main modifications brought about the Software Package are: i) addition of new solid phases, ii) use of P>0.1 Mpa, iii) variation of the CO2 supercritical fugacity and solubility under reservoir conditions, iv) addition of kinetic rate equations of several minerals and v) calculation of reaction surface area. The Weyburn Project was selected as case study to test our model. The Weyburn oil-pull is recovered from the Midale Beds (1300-1500 m deep) that consist of two units of Mississippian shallow marine carbonate-evaporites: i) the dolomitic “Marly” and ii) the underlying calcitic “Vuggy”, sealed by an anhydrite cap-rock. About 3 billions mc of supercritical CO2 have been injected into the “Phase A1” injection area. The INGV and the University of Calgary (Canada), have carried out a geochemical monitoring program (ca. thrice yearly- from pre-injection trip: “Baseline” trip, August 2000, to September 2004). The merged experimental data are the base of the present geochemical modeling. On the basis of the available data, i.e. a) bulk mineralogy of the Marly and Vuggy reservoirs; b) mean gas-cap composition at the wellheads and c) selected pre- and post-CO2 injection water samples, the in-situ (62 °C and 0.1 MPa) reservoir chemical composition (including pH and the boundary conditions as PCO2, PH2S) has been re-built by the chemical equilibrium among the various phases, minimizing the effects of the past 30-years of water flooding in the oil field. The kinetic evolution of the CO2-rich Weyburn brines interacting with the host-rock minerals performed over 100 years after injection have also been computed. The reaction path modeling suggests that CO2 can mainly be neutralized by solubility and mineral trapping via Dawsonite precipitation. To validate our model the geochemical impact of three years of CO2 injection (September 2000-2003) has been simulated by kinetically controlled reactions. The calculated chemical composition after the CO2 injection is consistent with the analytical data of samples collected in 2003 with a <5 % error for most analytical species, with the exception of Ca and Mg (error >90%), likely due to the complexation effect of carboxilic acid

Epidemiological and virological assessment of influenza activity in Apulia, Italy, during the seasons 2004 - 2005 and 2005 - 2006.

This study evaluated the impact of influenza and vaccination coverage in Apulia, Italy, during the 2004–2005 and 2005–2006 seasons, using epidemiological and virological surveillance data collected through the Italian Net of Surveillance of Influenza (InfluNet) organized by the Superior Institute of Health (ISS) and the Inter-University Centre of Research on Influenza (CIRI). Vaccination coverage was calculated from the number of doses administered to individuals aged ≤ 65 years. Sentinel physicians reported weekly influenza-like illness (ILI) and acute respiratory illness (ARI) occurrences among patients. Influenza viruses were isolated and identified by cell culture on Madin-Darby Canine Kidney cells and polymerase chain reaction techniques. Vaccination coverage reached 72.7% and 77.0% during the 2004–2005 and 2005–2006 seasons, respectively. Incidence of ILI was higher during the 2004–2005 season compared with the 2005–2006 season, whereas the incidence ARI appeared to show a more constant trend. Incidence rates for ILI and ARI were higher in the 0 − 14-year age group. The increase in vaccination coverage and implementation of a network of epidemiological and virological surveillance are fundamental for the control and prevention of influenza

Spatial distribution of arsenic, uranium and vanadium in the volcanic-sedimentary aquifers of the Vicano–Cimino Volcanic District (Central Italy)

Arsenic concentrations were analysed for 328 water samples collected in the Vicano–Cimino Volcanic District (VCVD), an areawhere severe contamination of groundwater has become a serious problemfollowing the recent application of the EU Directive on the maximum allowable concentration level for As in drinking waters. In addition, uranium and vanadium concentrations were also analysed in light of the enhanced interest on their environmental toxicity. Waters were collected from springs and wells fed by cold and shallow volcanic–sedimentary aquifers, which locally represent the main drinking water source. Thermal springs (≤63 °C) related to an active hydrothermal reservoir and waters associated with a CO2-rich gas phase of deep provenance were also analysed. The collected data showed that the As concentrations in the shallow aquifers varied in a wide range (0.05–300 μg/L) and were primarily controlled by water–rock interaction processes. High As concentrations (up to 300 μg/L) were measured in springs and wells discharging from the volcanic products, and about 66% exceeded the limit of 10 μg/L for drinkingwaters,whereaswaters circulatingwithin the sedimentary formations displayed much lower values (0.05–13 μg/L; ~4% exceeding the threshold limit). Thermal waters showed the highest As concentrations (up to 610 μg/L) as the result of the enhanced solubility of As-rich volcanic rocks during water–rock interaction processes at high temperatures. Where the local structural setting favoured the rise of fluids from the deep hydrothermal reservoir and their interaction with the shallow volcanic aquifer, relatively higher concentrations were found. Moreover, well overexploitation likely caused the lateral inflow of As-rich waters towards not contaminated areas. Uraniumand vanadiumconcentrations ofwaters circulating in the volcanic rocks ranged from0.01 to 85 μg/L and 0.05 to 62 μg/L, respectively. Less than 2% of analysed samples exceeded theWorld Health Organization's provisional guidelines for U (30 μg/L), while none of them was above the Italian limit value of V in drinking water (120 μg/L). Lower U (0.07–22 μg/L and 0.02–13 μg/L, respectively) and V concentrations (0.05–24 μg/L and 0.18–17 μg/L, respectively) were measured in the water samples from the sedimentary aquifer and thermal waters. Local lithology appeared as the main factor affecting the U and V contents in the shallow aquifers, due to the high concentrations of these two elements in the volcanic formations when compared to the sedimentary units. In addition, high U concentrations were found in correspondence with U mineralization occurring within the VCVD, fromwhich U is released in solution mainly through supergene oxidative alteration. Redox conditions seem to play amajor role in controlling the concentrations of U and V inwaters. Oxidizing conditions characterizing the cold waters favour the formation of soluble U- and V-species, whereas thermal waters under anoxic conditions are dominated by relatively insoluble species. Geostatistical techniques were used to draw contour maps by using variogram models and kriging estimation aimed to define the areas of potential health risk characterized by As, U and V-rich waters, thus providing a useful tool for water management in a naturally contaminated area to local Authorities