Numerical simulation of two-phase cross flow in the gas diffusion layer microstructure of proton exchange membrane fuel cells

The cross flow in the under-land gas diffusion layer (GDL) between 2 adjacent channels plays an important role on water transport in proton exchange membrane fuel cell. A 3-dimensional (3D) two-phase model that is based on volume of fluid is developed to study the liquid water-air cross flow within the GDL between 2 adjacent channels. By considering the detailed GDL microstructures, various types of air-water cross flows are investigated by 3D numerical simulation. Liquid water at 4 locations is studied, including droplets at the GDL surface and liquid at the GDL-catalyst layer interface. It is found that the water droplet at the higher-pressure channel corner is easier to be removed by cross flow compared with droplets at other locations. Large pressure difference Δp facilitates the faster water removal from the higher-pressure channel. The contact angle of the GDL fiber is the key parameter that determines the cross flow of the droplet in the higher-pressure channel. It is observed that the droplet in the higher-pressure channel is difficult to flow through the hydrophobic GDL. Numerical simulations are also performed to investigate the water emerging process from different pores of the GDL bottom. It is found that the amount of liquid water removed by cross flow mainly depends on the pore's location, and the water under the land is removed entirely into the lower-pressure channel by cross flow

Efficient spin-current injection in single-molecule magnet junctions

We study theoretically spin transport through a single-molecule magnet (SMM) in the sequential and cotunneling regimes, where the SMM is weakly coupled to one ferromagnetic and one normalmetallic leads. By a master-equation approach, it is found that the spin polarization injected from the ferromagnetic lead is amplified and highly polarized spin-current can be generated, due to the exchange coupling between the transport electron and the anisotropic spin of the SMM. Moreover, the spin-current polarization can be tuned by the gate or bias voltage, and thus an efficient spin injection device based on the SMM is proposed in molecular spintronics.Comment: 4 figure

The upper critical field and its anisotropy in LiFeAs

The upper critical field $\mu_0H_{c2}(T_c)$ of LiFeAs single crystals has been determined by measuring the electrical resistivity using the facilities of pulsed magnetic field at Los Alamos. We found that $\mu_0H_{c2}(T_c)$ of LiFeAs shows a moderate anisotropy among the layered iron-based superconductors; its anisotropic parameter $\gamma$ monotonically decreases with decreasing temperature and approaches $\gamma\simeq 1.5$ as $T\rightarrow 0$. The upper critical field reaches 15T ($H\parallel c$) and 24.2T ($H\parallel ab$) at $T=$1.4K, which value is much smaller than other iron-based high $T_c$ superconductors. The temperature dependence of $\mu_0H_{c2}(T_c)$ can be described by the Werthamer-Helfand-Hohenberg (WHH) method, showing orbitally and (likely) spin-paramagnetically limited upper critical field for $H\parallel c$ and $H\parallel ab$, respectively.Comment: 5 pages,5 figure

Observation of Landau quantization and standing waves in HfSiS

Recently, HfSiS was found to be a new type of Dirac semimetal with a line of Dirac nodes in the band structure. Meanwhile, Rashba-split surface states are also pronounced in this compound. Here we report a systematic study of HfSiS by scanning tunneling microscopy/spectroscopy at low temperature and high magnetic field. The Rashba-split surface states are characterized by measuring Landau quantization and standing waves, which reveal a quasi-linear dispersive band structure. First-principles calculations based on density-functional theory are conducted and compared with the experimental results. Based on these investigations, the properties of the Rashba-split surface states and their interplay with defects and collective modes are discussed.Comment: 6 pages, 5 figure