Detailed Analysis of Nearby Bulgelike Dwarf Stars II. Lithium Abundances

Li abundances are derived for a sample of bulgelike stars with isochronal ages of 10-11 Gyr. These stars have orbits with pericentric distances, Rp, as small as 2-3 kpc and Zmax < 1 kpc. The sample comprises G and K dwarf stars in the metallicity range -0.80<[Fe/H]< +0.40. Few data of Li abundances in old turn-off stars (> 4.5 Gyr) within the present metallicity range are available. M67 (4.7 Gyr) and NGC 188 (6 Gyr) are the oldest studied metal-rich open clusters with late-type stars. Li abundances have also been studied for few samples of old metal-rich field stars. In the present work a high dispersion in Li abundances is found for bulgelike stars for all the metallicity range, comparable with values in M67. The role of metallicity and age on a Li depletion pattern is discussed. The possible connection between Li depletion and oxygen abundance due to atmospheric opacity effects is investigated.Comment: 9 pages, 7 figure

Spectroscopic Sensitivity

We describe the overall performance of the STIS CCD after HST Servicing Mission #4 and the associated updates to calibration reference files. Most aspects of CCD performance are found to be fairly consistent with extrapolations of the trends seen prior to the failure of STIS in August 2004. The CCD gain value for the CCDGAIN = 4 setting has been redetermined using net count ratios of standard star spectra taken in the CCDGAIN = 1 and CCDGAIN = 4 settings, resulting in a gain value of 4.016 ± 0.003 e − /DN, which is 0.5% lower than the value used for the calibration of archival STIS CCD data taken before August 2004. Finally, we identify two independent indications of a temperature dependence of the Charge Transfer Efficiency (CTE). However, more calibration data are needed to verify the significance of this effect and, if verified, to calibrate it as a function of CCD housing temperature (as a proxy for CCD chip temperature). This option will be reassessed later during the Cycle 17 calibration program.

Limits on the Optical Brightness of the Epsilon Eridani Dust Ring

The STIS/CCD camera on the {\em Hubble Space Telescope (HST)} was used to take deep optical images near the K2V main-sequence star $\epsilon$ Eridani in an attempt to find an optical counterpart of the dust ring previously imaged by sub-mm observations. Upper limits for the optical brightness of the dust ring are determined and discussed in the context of the scattered starlight expected from plausible dust models. We find that, even if the dust is smoothly distributed in symmetrical rings, the optical surface brightness of the dust, as measured with the {\em HST}/STIS CCD clear aperture at 55 AU from the star, cannot be brighter than about 25 STMAG/"$^2$. This upper limit excludes some solid grain models for the dust ring that can fit the IR and sub-mm data. Magnitudes and positions for $\approx$59 discrete objects between 12.5" to 58" from $\epsilon$ Eri are reported. Most if not all of these objects are likely to be background stars and galaxies.Comment: Revision corrects author lis

Are models of catalytic removal of O_3 by HO_x accurate? Constraints from in situ measurements of the OH to HO_2 ratio

Measurements of the ratio OH/HO_2, NO, O_3, ClO, and BrO were obtained at altitudes from 15–20 km and latitudes from 15–60°N. A method is presented for interpreting these simultaneous in situ observations that constrains the rates of chemical transformations that 1) are responsible for over half the ozone removal rate in the lower stratosphere via reactions of HO_2 and 2) control the abundance of HO_2 through coupling to nitrogen and halogen radicals. The results show our understanding of the chemical reactions controlling the partitioning of OH and HO_2 is complete and accurate and that the potential effects of “missing chemistry” are strictly constrained in the region of the atmosphere encompassed by the observations. The analysis demonstrates that the sensitivity of the ratio OH/HO_2 to changes in NO is described to within 12% by current models. This reduces by more than a factor of 2 the effect of uncertainty in the coupling of hydrogen and nitrogen radicals on the analysis of the potential effects of perturbations to odd nitrogen in the lower stratosphere

The role of HO_x in super- and subsonic aircraft exhaust plumes

The generation of sulfuric acid aerosols in aircraft exhaust has emerged as a critical issue in determining the impact of supersonic aircraft on stratospheric ozone. It has long been held that the first step in the mechanism of aerosol formation is the oxidation of SO_(2) emitted from the engine by OH in the exhaust plume. We report in situ measurements of OH and HO_(2) in the exhaust plumes of a supersonic (Air France Concorde) and a subsonic (NASA ER-2) aircraft in the lower stratosphere. These measurements imply that reactions with OH are responsible for oxidizing only a small fraction of SO_(2) (2%), and thus cannot explain the large number of particles observed in the exhaust wake of the Concorde

Stratification and Isotope Separation in CP Stars

We investigate the elemental and isotopic stratification in the atmospheres of selected chemically peculiar (CP) stars of the upper main sequence. Reconfiguration of the UVES spectrograph in 2004 has made it possible to examine all three lines of the Ca II infrared triplet. Much of the material analyzed was obtained in 2008. We support the claim of Ryabchikova, Kochukhov & Bagnulo (RKB) that the calcium isotopes have distinct stratification profiles for the stars 10 Aql, HR 1217, and HD 122970, with the heavy isotope concentrated toward the higher layers. Better observations are needed to learn the extent to which Ca-40 dominates in the deepest layers of all or most CP stars that show the presence of Ca-48. There is little evidence for Ca-40 in the spectra of some HgMn stars, and the infrared triplet in the magnetic star HD 101065 is well fit by pure Ca-48. In HR 5623 (HD 133792) and HD 217522 it is likely that the heavy isotope dominates, though models are possible where this is not the case. While elemental stratification is surely needed in many cases, we point out the importance of including adjustments in the assumed Teff and log(g) values, in attempts to model stratification. We recommend emphasis on profiles of the strongest lines, where the influence of stratification is most evident. Isotopic mixtures, involving the 4 stable calcium nuclides with masses between 40 and 48 are plausible, but are not emphasized.Comment: 16 Pages, 20 Figures, 10 Tables. Accepted for publication in Monthly Notices of the RA

Turbulent spectrum of the Earth's ozone field

The Total Ozone Mapping Spectrometer (TOMS) database is subjected to an analysis in terms of the Karhunen-Loeve (KL) empirical eigenfunctions. The concentration variance spectrum is transformed into a wavenumber spectrum, $E_c(k)$. In terms of wavenumber $E_c(k)$ is shown to be $O(k^{-2/3})$ in the inverse cascade regime, $O(k^{-2})$ in the enstrophy cascade regime with the spectral {\it knee} at the wavenumber of barotropic instability.The spectrum is related to known geophysical phenomena and shown to be consistent with physical dimensional reasoning for the problem. The appropriate Reynolds number for the phenomena is $Re\approx 10^{10}$.Comment: RevTeX file, 4 pages, 4 postscript figures available upon request from Richard Everson <[email protected]

K-shell photoionization of ground-state Li-like boron ions [B2+^{2+}]: Experiment and Theory

Absolute cross sections for the K-shell photoionization of ground-state Li-like boron [B$^{2+}$(1s$^2$2s $^2$S)] ions were measured by employing the ion-photon merged-beams technique at the Advanced Light Source synchrotron radiation facility. The energy ranges 197.5--200.5 eV, 201.9--202.1 eV of the [1s(2s\,2p)$^3$P]$^2$P${\rm ^o}$ and [1s(2s\,2p)$^1$P] $^2$P${\rm ^o}$ resonances, respectively, were investigated using resolving powers of up to 17\,600. The energy range of the experiments was extended to about 238.2 eV yielding energies of the most prominent [1s(2$\ell$\,n$\ell^{\prime}$)]$^2$P$^o$ resonances with an absolute accuracy of the order of 130 ppm. The natural linewidths of the [1s(2s\,2p)$^3$P] $^2$P${\rm ^o}$ and [1s(2s\,2p)$^1$P] $^2$P${\rm ^o}$ resonances were measured to be $4.8 \pm 0.6$ meV and $29.7 \pm 2.5$ meV, respectively, which compare favourably with theoretical results of 4.40 meV and 30.53 meV determined using an intermediate coupling R-matrix method.Comment: 6 figures and 2 table

Ozone destruction and production rates between spring and autumn in the Arctic stratosphere

In situ measurements of radical and long-lived species were made in the lower Arctic stratosphere (18 to 20 km) between spring and early autumn in 1997. The measurements include O_3, ClO, OH, HO_2, NO, NO_2, N_(2)O, CO, and overhead O_3. A photochemical box model constrained by these and other observations is used to compute the diurnally averaged destruction and production rates of O3 in this region. The rates show a strong dependence on solar exposure and ambient O_3. Total destruction rates, which reach 19%/month in summer, reveal the predominant role of NO_x and HO_x catalytic cycles throughout the period. Production of O_3 is significant only in midsummer air parcels. A comparison of observed O_3 changes with destruction rates and transport effects indicates the predominant role of destruction in spring and an increased role of transport by early autumn

The response of ClO radical concentrations to variations in NO_2 radical concentrations in the lower stratosphere

The response of ClO concentrations to changes in NO_2 concentrations has been inferred from simultaneous observations of [ClO], [NO], [NO_2] and [O_3] in the mid-latitude lower stratosphere. This analysis demonstrates that [ClO] is inversely correlated with [NO_2], consistent with formation and photolysis of [ClONO_2]. A factor of ten range in the concentration of NO_2 was sampled (0.1 to 1×10^9 mol/cm^3), with a comparable range in the ratio of [ClO] to total available inorganic chlorine (1% ≤ [ClO]/[Cl_y] ≤ 5%). This analysis leads to an estimate of [ClONO_2]/[Cl_y] = 0.12 (×/÷2), in the mid-latitude, lower-stratospheric air masses sampled