1,064 research outputs found

    Whole-mantle convection with tectonic plates preserves long-term global patterns of upper mantle geochemistry

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    The evolution of the planetary interior during plate tectonics is controlled by slow convection within the mantle. Global-scale geochemical differences across the upper mantle are known, but how they are preserved during convection has not been adequately explained. We demonstrate that the geographic patterns of chemical variations around the Earth’s mantle endure as a direct result of whole-mantle convection within largely isolated cells defined by subducting plates. New 3D spherical numerical models embedded with the latest geological paleo-tectonic reconstructions and ground-truthed with new Hf-Nd isotope data, suggest that uppermost mantle at one location (e.g. under Indian Ocean) circulates down to the core-mantle boundary (CMB), but returns within ≥100 Myrs via large-scale convection to its approximate starting location. Modelled tracers pool at the CMB but do not disperse ubiquitously around it. Similarly, mantle beneath the Pacific does not spread to surrounding regions of the planet. The models fit global patterns of isotope data and may explain features such as the DUPAL anomaly and long-standing differences between Indian and Pacific Ocean crust. Indeed, the geochemical data suggests this mode of convection could have influenced the evolution of mantle composition since 550 Ma and potentially since the onset of plate tectonics

    Oxygen impurities in NiAl: Relaxation effects

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    We have used a full-potential linear muffin-tin orbital method to calculate the effects of oxygen impurities on the electronic structure of NiAl. Using the supercell method with a 16-atom supercell we have investigated the cases where an oxygen atom is substitutionally placed at either a nickel or an aluminum site. Full relaxation of the atoms within the supercell was allowed. We found that oxygen prefers to occupy a nickel site over an aluminum site with a site selection energy of 138 mRy (21,370 K). An oxygen atom placed at an aluminum site is found to cause a substantial relaxation of its nickel neighbors away from it. In contrast, this steric repulsion is hardly present when the oxygen atom occupies the nickel site and is surrounded by aluminum neighbors. We comment on the possible relation of this effect to the pesting degradation phenomenon (essentially spontaneous disintegration in air) in nickel aluminides.Comment: To appear in Phys. Rev. B (Aug. 15, 2001

    An investigation into the effects of, and interaction between, heel height and shoe upper stiffness on plantar pressure and comfort

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    High heeled shoes remain popular, nevertheless it is not clear what influence manipulating characteristics of this footwear has on their functioning. It is accepted that shoe features other than heel height can affect plantar pressures. However, few investigations have compared such features, and none have compared the influence of modifying upper material stiffness, whilst systematically increasing heel height. A firm understanding of the interactions of footwear properties is essential to ensure that footwear designers can optimise design for the comfort and health of the wearer. This paper investigates a feature that is known to reduce comfort (heel height) and a feature that is easy to change without affecting aesthetics (material stiffness) to better understand the effects of their interaction on plantar pressure and comfort. Sixteen female participants with experience wearing high heels wore a range of shoes with five effective heel heights (35-75 mm) and two upper materials (with different stiffness). In-shoe plantar pressure was recorded and participants completed a comfort questionnaire. Increasing heel height increased plantar pressure under the metatarsal heads, while reducing pressure in the hallux and heel. Higher heel heights also lead to increased discomfort, particularly in the toes where discomfort increased 154.3% from the 35 to 75 mm heels. Upper stiffness did not affect plantar pressure. However, stiffer uppers significantly increased reported discomfort, most notably on top of the foot (108.6%), the back of the heel (87.7%), the overall width (99%), and the overall comfort (100.7%). Significant interaction effects between heel height and upper material existed for comfort questionnaire data. Manipulating heel height alters plantar pressure and comfort, and choice of upper material is paramount to achieving wearer comfort in heels

    First principle study of intrinsic defects in hexagonal tungsten carbide

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    The characteristics of intrinsic defects are important for the understanding of self-diffusion processes, mechanical strength, brittleness, and plasticity of tungsten carbide, which present in the divertor of fusion reactors. Here, we use first-principles calculations to investigate the stability of point defects and their complexes in WC. Our calculation results confirm that the formation energies of carbon defects are much lower than that of tungsten defects. The outward relaxations around vacancy are found. Both interstitial carbon and interstitial tungsten atom prefer to occupy the carbon basal plane projection of octahedral interstitial site. The results of isolated carbon defect diffusion show that the carbon vacancy stay for a wide range of temperature because of extremely high diffusion barriers, while carbon interstitial migration is activated at lower temperatures for its considerable lower activation energy. These results provide evidence for the presumption that the 800K stage is attributed by the annealing out of carbon vacancies by long-range migration.Comment: Submitted to Journal of Nuclear Material

    Ballistic electron transport in stubbed quantum waveguides: experiment and theory

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    We present results of experimental and theoretical investigations of electron transport through stub-shaped waveguides or electron stub tuners (ESTs) in the ballistic regime. Measurements of the conductance G as a function of voltages, applied to different gates V_i (i=bottom, top, and side) of the device, show oscillations in the region of the first quantized plateau which we attribute to reflection resonances. The oscillations are rather regular and almost periodic when the height h of the EST cavity is small compared to its width. When h is increased, the oscillations become less regular and broad depressions in G appear. A theoretical analysis, which accounts for the electrostatic potential formed by the gates in the cavity region, and a numerical computation of the transmission probabilities successfully explains the experimental observations. An important finding for real devices, defined by surface Schottky gates, is that the resonance nima result from size quantization along the transport direction of the EST.Comment: Text 20 pages in Latex/Revtex format, 11 Postscript figures. Phys. Rev. B,in pres

    Search for the Proton Decay Mode proton to neutrino K+ in Soudan 2

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    We have searched for the proton decay mode proton to neutrino K+ using the one-kiloton Soudan 2 high resolution calorimeter. Contained events obtained from a 3.56 kiloton-year fiducial exposure through June 1997 are examined for occurrence of a visible K+ track which decays at rest into mu+ nu or pi+ pi0. We found one candidate event consistent with background, yielding a limit, tau/B > 4.3 10^{31} years at 90% CL with no background subtraction.Comment: 13 pages, Latex, 3 tables and 3 figures, Accepted by Physics Letters

    Spin, charge and orbital ordering in ferrimagnetic insulator YBaMn2_2O5_5

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    The oxygen-deficient (double) perovskite YBaMn2_2O5_5, containing corner-linked MnO5_5 square pyramids, is found to exhibit ferrimagnetic ordering in its ground state. In the present work we report generalized-gradient-corrected, relativistic first-principles full-potential density-functional calculations performed on YBaMn2_2O5_5 in the nonmagnetic, ferromagnetic and ferrimagnetic states. The charge, orbital and spin orderings are explained with site-, angular momentum- and orbital-projected density of states, charge-density plots, electronic structure and total energy studies. YBaMn2_2O5_5 is found to stabilize in a G-type ferrimagnetic state in accordance with experimental results. The experimentally observed insulating behavior appears only when we include ferrimagnetic ordering in our calculation. We observed significant optical anisotropy in this material originating from the combined effect of ferrimagnetic ordering and crystal field splitting. In order to gain knowledge about the presence of different valence states for Mn in YBaMn2_2O5_5 we have calculated KK-edge x-ray absorption near-edge spectra for the Mn and O atoms. The presence of the different valence states for Mn is clearly established from the x-ray absorption near-edge spectra, hyperfine field parameters and the magnetic properties study. Among the experimentally proposed structures, the recently reported description based on PP4/nmmnmm is found to represent the stable structure
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