Ethyl 2-amino-5,6,7,8-tetrahydro-4H-cyclo-hepta[b] thiophene-3-carboxylate

In the structure of the title compound, (C12172S)-S-H-S-NO, the terminal ester group lies in the plane of the thiophene ring system. The cycloheptene ring adopts a half-chair conformation. There are intramolecular N-HO and C-HO interactions, and intermolecular N-HO and C-H interactions

Rapid methods of landslide hazard mapping : Fiji case study

A landslide hazard probability map can help planners (1) prepare for, and/or mitigate against, the effects of landsliding on communities and infrastructure, and (2) avoid or minimise the risks associated with new developments. The aims of the project were to establish, by means of studies in a few test areas, a generic method by which remote sensing and data analysis using a geographic information system (GIS) could provide a provisional landslide hazard zonation map. The provision of basic hazard information is an underpinning theme of the UN’s International Decade for Natural Disaster Reduction (IDNDR). It is an essential requirement for disaster preparedness and mitigation planning. This report forms part of BGS project 92/7 (R5554) ‘Rapid assessment of landslip hazards’ Carried out under the ODA/BGS Technology Development and Research Programme as part of the British Government’s provision of aid to developing countries. It provides a detailed technical account of work undertaken in a test area in Viti Levu in collaboration with Fiji Mineral Resources Department. The study represents a demonstration of a methodology that is applicable to many developing countries. The underlying principle is that relationships between past landsliding events, interpreted from remote sensing, and factors such as the geology, relief, soils etc provide the basis for modelling where future landslides are most likely to occur. This is achieved using a GIS by ‘weighting’ each class of each variable (e.g. each lithology ‘class’ of the variable ‘geology’) according to the proportion of landslides occurring within it compared to the regional average. Combinations of variables, produced by summing the weights in individual classes, provide ‘models’ of landslide probability. The approach is empirical but has the advantage of potentially being able to provide regional scale hazard maps over large areas quickly and cheaply; this is unlikely to be achieved using conventional ground-based geotechnical methods. In Fiji, landslides are usually triggered by intense rain storms commonly associated with tropical cyclones. However, the regional distribution of landslides has not been mapped nor is it known how far geology and landscape influence the location and severity of landsliding events. The report discusses the remote sensing and GIS methodology, and describes the results of the pilot study over an area of 713 km2 in south east Viti Levu. The landslide model uses geology, elevation, slope angle, slope aspect, soil type, and forest cover as inputs. The resulting provisional landslide hazard zonation map, divided into high, medium and low zones of landslide hazard probability, suggests that whilst rainfall is the immediate cause, others controls do exert a significant influence. It is recommended that consideration be given in Fiji to implementing the techniques as part of a national strategic plan for landslide hazard zonation mapping

Nafion-stabilized Pt Nanoparticles and the Effect of Pt Distribution on the Electrochemical Reduction of Oxygen

Nafion stabilized Pt sols was prepared by using methanol to reduce the precursor H2PtCl6. No other ingredient was used in the preparation and Pt nanoparticles of 2 -3 nm size were obtained. Platinum nanoparticles were found to form aggregates. The aggregate size and the stability of Pt sols could be changed by solvent treatment. This suggests that SO3¯ functional groups of Nafion stabilized Pt nanoparticles and that the aggregates formed due to the formation of ionic clusters of Nafion. The electrochemical reduction of oxygen was examined with carbon supported Nafion-Pt catalysts of different aggregate size. At low overpotential, the kinetic rate was not changed by the aggregate size. At high overpotential region where mass-transfer limitation phenomenon was observed, the reaction rate increased with decreasing aggregate size. It indicates that smaller aggregates, i.e., the more even Pt distribution, are less subjected to mass-transfer limitation and could consequently provide better electrode performance

Optical control of nanoparticle catalysis influenced by photoswitch positioning in hybrid peptide capping ligands

YesHere we present an in-depth analysis of structural factors that modulate peptide-capped nanoparticle catalytic activity via optically driven structural reconfiguration of the biointerface present at the particle surface. Six different sets of peptide-capped Au nanoparticles were prepared, in which an azobenzene photoswitch was incorporated into one of two well-studied peptide sequences with known affinity for Au, each at one of three different positions: The N- or C-terminus, or mid-sequence. Changes in the photoswitch isomerization state induce a reversible structural change in the surface-bound peptide, which modulates the catalytic activity of the material. This control of reactivity is attributed to changes in the amount of accessible metallic surface area available to drive the reaction. This research specifically focuses on the effect of the peptide sequence and photoswitch position in the biomolecule, from which potential target systems for on/off reactivity have been identified. Additionally, trends associated with photoswitch position for a peptide sequence (Pd4) have been identified. Integrating the azobenzene at the N-terminus or central region results in nanocatalysts with greater reactivity in the trans and cis conformations, respectively; however, positioning the photoswitch at the C-terminus gives rise to a unique system that is reactive in the trans conformation and partially deactivated in the cis conformation. These results provide a fundamental basis for new directions in nanoparticle catalyst development to control activity in real time, which could have significant implications in the design of catalysts for multistep reactions using a single catalyst. Additionally, such a fine level of interfacial structural control could prove to be important for applications beyond catalysis, including biosensing, photonics, and energy technologies that are highly dependent on particle surface structures.Air Office of Scientific Research, grant number FA9550-12- 1-0226

Numerical simulation of "an American haboob"

A dust storm of fearful proportions hit Phoenix in the early evening hours of 5 July 2011. This storm, an American haboob, was predicted hours in advance because numerical, land-atmosphere modeling, computing power and remote sensing of dust events have improved greatly over the past decade. High-resolution numerical models are required for accurate simulation of the small scales of the haboob process, with high velocity surface winds produced by strong convection and severe downbursts. Dust productive areas in this region consist mainly of agricultural fields, with soil surfaces disturbed by plowing and tracks of land in the high Sonoran Desert laid barren by ongoing draught. Model simulation of the 5 July 2011 dust storm uses the coupled atmospheric-dust model NMME-DREAM (Non-hydrostatic Mesoscale Model on E grid, Janjic et al., 2001; Dust REgional Atmospheric Model, Nickovic et al., 2001; Perez et al., 2006) with 4 km horizontal resolution. A mask of the potentially dust productive regions is obtained from the land cover and the normalized difference vegetation index (NDVI) data from the Moderate Resolution Imaging Spectroradiometer (MODIS). The scope of this paper is validation of the dust model performance, and not use of the model as a tool to investigate mechanisms related to the storm. Results demonstrate the potential technical capacity and availability of the relevant data to build an operational system for dust storm forecasting as a part of a warning system. Model results are compared with radar and other satellite-based images and surface meteorological and PM10 observations. The atmospheric model successfully hindcasted the position of the front in space and time, with about 1 h late arrival in Phoenix. The dust model predicted the rapid uptake of dust and high values of dust concentration in the ensuing storm. South of Phoenix, over the closest source regions (similar to 25 km), the model PM10 surface dust concentration reached similar to 2500 mu g m(-3), but underestimated the values measured by the PM10 stations within the city. Model results are also validated by the MODIS aerosol optical depth (AOD), employing deep blue (DB) algorithms for aerosol loadings. Model validation included Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO), equipped with the lidar instrument, to disclose the vertical structure of dust aerosols as well as aerosol subtypes. Promising results encourage further research and application of high-resolution modeling and satellite-based remote sensing to warn of approaching severe dust events and reduce risks for safety and health

ADHM/Nahm Construction of Localized Solitons in Noncommutative Gauge Theories

We study the relationship between ADHM/Nahm construction and ``solution generating technique'' of BPS solitons in noncommutative gauge theories. ADHM/Nahm construction and ``solution generating technique'' are the most strong ways to construct exact BPS solitons. Localized solitons are the solitons which are generated by the ``solution generating technique.'' The shift operators which play crucial roles in ``solution generating technique'' naturally appear in ADHM/Nahm construction and we can construct various exact localized solitons including new solitons: localized periodic instantons (=localized calorons) and localized doubly-periodic instantons. Nahm construction also gives rise to BPS fluxons straightforwardly from the appropriate input Nahm data which is expected from the D-brane picture of BPS fluxons. We also show that the Fourier-transformed soliton of the localized caloron in the zero-period limit exactly coincides with the BPS fluxon.Comment: 30 pages, LaTeX, 3 figures; v3: minor changes, references added; v4: references added, version to appear in PR

Interruption of torus doubling bifurcation and genesis of strange nonchaotic attractors in a quasiperiodically forced map : Mechanisms and their characterizations

A simple quasiperiodically forced one-dimensional cubic map is shown to exhibit very many types of routes to chaos via strange nonchaotic attractors (SNAs) with reference to a two-parameter $(A-f)$ space. The routes include transitions to chaos via SNAs from both one frequency torus and period doubled torus. In the former case, we identify the fractalization and type I intermittency routes. In the latter case, we point out that atleast four distinct routes through which the truncation of torus doubling bifurcation and the birth of SNAs take place in this model. In particular, the formation of SNAs through Heagy-Hammel, fractalization and type--III intermittent mechanisms are described. In addition, it has been found that in this system there are some regions in the parameter space where a novel dynamics involving a sudden expansion of the attractor which tames the growth of period-doubling bifurcation takes place, giving birth to SNA. The SNAs created through different mechanisms are characterized by the behaviour of the Lyapunov exponents and their variance, by the estimation of phase sensitivity exponent as well as through the distribution of finite-time Lyapunov exponents.Comment: 27 pages, RevTeX 4, 16 EPS figures. Phys. Rev. E (2001) to appea

Evolution of Microstructure and Texture during Warm Rolling Of a Duplex Steel

The effect of warm rolling on the evolution of microstructure and texture in a duplex stainless steel (DSS) was investigated. For this purpose, a DSS steel was warm rolled up to 90 pct reduction in thickness at 498 K, 698 K, and 898 K (225 °C, 425 °C, and 625 °C). The microstructure with an alternate arrangement of deformed ferrite and austenite bands was observed after warm rolling; however, the microstructure after 90 pct warm rolling at 498 K and 898 K (225 °C and 625 °C) was more lamellar and uniform as compared to the rather fragmented and inhomogeneous structure observed after 90 pct warm rolling at 698 K (425 °C). The texture of ferrite in warm-rolled DSS was characterized by the presence of the RD (〈011〉//RD) and ND (〈111〉//ND) fibers. However, the texture of ferrite in DSS warm rolled at 698 K (425 °C) was distinctly different having much higher fraction of the RD-fiber components than that of the ND-fiber components. The texture and microstructural differences in ferrite in DSS warm rolled at different temperatures could be explained by the interaction of carbon atoms with dislocations. In contrast, the austenite in DSS warm rolled at different temperatures consistently showed pure metal- or copper-type deformation texture which was attributed to the increase in stacking fault energy at the warm-rolling temperatures. It was concluded that the evolution of microstructure and texture of the two constituent phases in DSS was greatly affected by the temperature of warm rolling, but not significantly by the presence of the other phas

Optical actuation of inorganic/organic interfaces: comparing peptide-azobenzene ligand reconfiguration on gold and silver nanoparticles

YesPhotoresponsive molecules that incorporate peptides capable of material-specific recognition provide a basis for biomolecule-mediated control of the nucleation, growth, organization, and activation of hybrid inorganic/organic nanostructures. These hybrid molecules interact with the inorganic surface through multiple noncovalent interactions which allow reconfiguration in response to optical stimuli. Here, we quantify the binding of azobenzene-peptide conjugates that exhibit optically triggered cis-trans isomerization on Ag surfaces and compare to their behavior on Au. These results demonstrate differences in binding and switching behavior between the Au and Ag surfaces. These molecules can also produce and stabilize Au and Ag nanoparticles in aqueous media where the biointerface can be reproducibly and reversibly switched by optically triggered azobenzene isomerization. Comparisons of switching rates and reversibility on the nanoparticles reveal differences that depend upon whether the azobenzene is attached at the peptide N- or C-terminus, its isomerization state, and the nanoparticle composition. Our integrated experimental and computational investigation shows that the number of ligand anchor sites strongly influences the nanoparticle size. As predicted by our molecular simulations, weaker contact between the hybrid biomolecules and the Ag surface, with fewer anchor residues compared with Au, gives rise to differences in switching kinetics on Ag versus Au. Our findings provide a pathway toward achieving new remotely actuatable nanomaterials for multiple applications from a single system, which remains difficult to achieve using conventional approaches.Air Office of Scientific Research, grant number FA9550-12-1-0226