Exploring the interplay between passive following on Facebook, fear of missing out, self-esteem, social comparison, age, and life satisfaction in a community-based sample

Facebook is amongst the most frequently used Social Networking Sites (SNSs) worldwide. Previous research reported SNS use such as Facebook use may have both positive and negative psychological impact on users, particularly with regards to users' psychological wellbeing and life satisfaction. To fully acknowledge the extent to which SNS use may affect psychological wellbeing and life satisfaction, different forms of SNS use and experiences need to be taken into account by researchers. There is currently a lack of research investigating how Passive Facebook Use may impact on users' well being. The present study sought to investigate how passive following on Facebook, fear of missing out, self-esteem, social comparison, and age may affect life satisfaction. A sample of 196 Facebook users (Mean age = 31.16, SD = 8.75) completed an online survey consisting of several psychometric tools. Overall, the results obtained suggest that life satisfaction may be differentially affected by a wide range of SNS-related experiences such as social comparison and fear of missing out. The implications of these findings for the use of SNSs are discussed

Differential Responses of Yield and Shoot Traits of Five Tropical Grasses to N and Distance to Trees in Silvopastoral Systems

Light intensity and nitrogen (N) availability are important factors influencing the growth of C4 forage species. Trade-offs may occur in the adaptive responses of species to shading and N inputs, and functional shoot traits can help to explain the consequences of these responses for species performance. Our objective was to gain understanding of the mechanisms between traits of five C4 perennial grasses determining above-ground dry matter yield (DMY) when both resources, light and N, vary. Forage grasses were grown in six shading conditions (full sunlight vs. five positions between Eucalyptus dunnii rows) with two N levels (0 vs. 300 kg N ha-1year-1) and clipped when the canopy reached 95% light interception. Path analysis was used to explore the relationship between DMY, shading levels, N nutrition index and shoot traits. Dry matter yield increased between 126 to 569 g dry matter m-2 with N fertilization. Nitrogen nutrition index was the most important predictor for determining DMY followed by shading level. Increased shading reduced DMY by 9.5 g DM m- ² for each 1% of increase in shading. DMY was also modulated by shoot traits such as specific leaf area and leaf area index, but with different responses according to species, highlighting different strategies to cope with changes in light and N availability

Dynamic headspace solid-phase microextraction combined with one-dimensional gas chromatography–mass spectrometry as a powerful tool to differentiate banana cultivars based on their volatile metabolite profile

In this study the effect of the cultivar on the volatile profile of five different banana varieties was evaluated and determined by dynamic headspace solid-phase microextraction (dHS-SPME) combined with one-dimensional gas chromatography–mass spectrometry (1D-GC–qMS). This approach allowed the definition of a volatile metabolite profile to each banana variety and can be used as pertinent criteria of differentiation. The investigated banana varieties (Dwarf Cavendish, Prata, Maçã, Ouro and Platano) have certified botanical origin and belong to the Musaceae family, the most common genomic group cultivated in Madeira Island (Portugal). The influence of dHS-SPME experimental factors, namely, fibre coating, extraction time and extraction temperature, on the equilibrium headspace analysis was investigated and optimised using univariate optimisation design. A total of 68 volatile organic metabolites (VOMs) were tentatively identified and used to profile the volatile composition in different banana cultivars, thus emphasising the sensitivity and applicability of SPME for establishment of the volatile metabolomic pattern of plant secondary metabolites. Ethyl esters were found to comprise the largest chemical class accounting 80.9%, 86.5%, 51.2%, 90.1% and 6.1% of total peak area for Dwarf Cavendish, Prata, Ouro, Maçã and Platano volatile fraction, respectively. Gas chromatographic peak areas were submitted to multivariate statistical analysis (principal component and stepwise linear discriminant analysis) in order to visualise clusters within samples and to detect the volatile metabolites able to differentiate banana cultivars. The application of the multivariate analysis on the VOMs data set resulted in predictive abilities of 90% as evaluated by the cross-validation procedure

Screening of volatile composition from portuguese multifloral honeys using headspace solid-phase microextraction-gas chromatography–quadrupole mass spectrometry

The volatile composition from four types of multifloral Portuguese (produced in Madeira Island) honeys was investigated by a suitable analytical procedure based on dynamic headspace solid-phase microextraction (HS-SPME) followed by thermal desorption gas chromatography–quadrupole mass spectrometry detection (GC–qMS). The performance of five commercially available SPME fibres: 100 μm polydimethylsiloxane, PDMS; 85 μm polyacrylate, PA; 50/30 μm divinylbenzene/carboxen on polydimethylsiloxane, DVB/CAR/PDMS (StableFlex); 75 μm carboxen/polydimethylsiloxane, CAR/PDMS, and 65 μm carbowax/divinylbenzene, CW/DVB; were evaluated and compared. The highest amounts of extract, in terms of the maximum signal obtained for the total volatile composition, were obtained with a DVB/CAR/PDMS coating fibre at 60 °C during an extraction time of 40 min with a constant stirring at 750 rpm, after saturating the sample with NaCl (30%). Using this methodology more than one hundred volatile compounds, belonging to different biosynthetic pathways were identified, including monoterpenols, C13-norisoprenoids, sesquiterpenes, higher alcohols, ethyl esters and fatty acids. The main components of the HS-SPME samples of honey were in average ethanol, hotrienol, benzeneacetaldehyde, furfural, trans-linalool oxide and 1,3-dihydroxy-2-propanone

Headspace solid-phase microextraction-gas chromatography-quadrupole mass spectrometric methodology for the establishment of the volatile composition of Passiflora fruit species

Dynamic headspace solid-phase microextraction (HS-SPME) followed by thermal desorption gas chromatography-quadrupole mass spectrometry analysis (GC-qMS), was used to investigate the aroma profile of different species of passion fruit samples. The performance of five commercially available SPME fibres: 65 μm polydimethylsiloxane/divinylbenzene, PDMS/DVB; 100 μm polydimethylsiloxane, PDMS; 85 μm polyacrylate, PA; 50/30 μm divinylbenzene/carboxen on polydimethylsiloxane, DVB/CAR/PDMS (StableFlex); and 75 μm carboxen/polydimethylsiloxane, CAR/PDMS; was evaluated and compared. Several extraction times and temperature conditions were also tested to achieve optimum recovery. The SPME fibre coated with 65 μm PDMS/DVB afforded the highest extraction efficiency, when the samples were extracted at 50 °C for 40 min with a constant stirring velocity of 750 rpm, after saturating the sample with NaCl (17%, w/v — 0.2 g). A comparison among different passion fruit species has been established in terms of qualitative and semi-quantitative differences in volatile composition. By using the optimal extraction conditions and GC-qMS it was possible to tentatively identify seventy one different compounds in Passiflora species: 51 volatiles in Passiflora edulis Sims (purple passion fruit), 24 in P. edulis Sims f. flavicarpa (yellow passion fruit) and 21 compounds in Passiflora mollissima (banana passion fruit). It was found that the ethyl esters comprise the largest class of the passion fruit volatiles, including 82.8% in P. edulis variety, 77.4% in P. edulis Sims f. flavicarpa variety and 39.9% in P. mollissima. The semi-quantitative results were then submitted to principal component analysis (PCA) in order to establish relationships between the compounds and the different passion fruit species under investigation

The effect of holding pressure on the shrinkage and birefringence of injection moulded polypropylene plates

This paper shows the results of shrinkage and birefringence of injection moulded plates. The study was done with two polypropylenes with different MFI. Focus is made on the effect of the holding pressure on the experimental as-moulded shrinkage and birefringence in the flow direction. The mouldings are edge gated flat rectangular plate. The moulding process was continuously monitored with pressure transducers. The results show that the rise of holding pressure determines the decrease of the shrinkage. Also, it was observed that the increase of the pressure applied during the holding phase and the associated flow induce re-orientation of the melt, especially in the case of higher molecular weight PP. Consequently, an increase in the birefringence results.(undefined

Procedimento de operação, manutenção e verificação de centrífuga JOUAN refrigerada.

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Dual antibiotherapy of tuberculosis mediated by inhalable locust bean gum microparticles

Despite the existence of effective oral therapy, tuberculosis remains a deadly pathology, namely because of bacterial resistance and incompliance with treatments. Establishing alternative therapeutic approaches is urgently needed and inhalable therapy has a great potential in this regard. As pathogenic bacteria are hosted by alveolar macrophages, the co-localisation of antitubercular drugs and pathogens is thus potentiated by this strategy. This work proposes inhalable therapy of pulmonary tuberculosis mediated by a single locust bean gum (LBG) formulation of microparticles associating both isoniazid and rifabutin, complying with requisites of the World Health Organisation of combined therapy. Microparticles were produced by spray-drying, at LBG/INH/RFB mass ratio of 10/1/0.5. The aerodynamic characterisation of microparticles revealed emitted doses of more than 90% and fine particle fraction of 38%, thus indicating the adequacy of the system to reach the respiratory lung area, thus partially the alveolar region. Cytotoxicity results indicate moderate toxicity (cell viability around 60%), with a concentration-dependent effect. Additionally, rat alveolar macrophages evidenced preferential capture of LBG microparticles, possibly due to chemical composition comprising mannose and galactose units that are specifically recognised by macrophage surface receptors. (C) 2017 Elsevier B.V. All rights reserved.National Portuguese funding through FCT - Fundacao para a Ciencia e a Tecnologia [PTDC/DTP-FTO/0094/2012, UID/BIM/04773/2013, UID/Multi/04326/2013, UID/QUI/00100/2013, PEst-OE/QUI/UI4023/2011

Test equipment

During the ejection phase of the injection moulding cycle the parts are mechanically forced to separate from the moulding surfaces, this aspect being more relevant with deep cores. The design of the ejection system depends on factors such as the draft angles, the surface finish, and the properties of the moulding material at the ejection temperature and the dimensioning of actuation devices (e.g., hydraulic or pneumatic cylinders). Knowledge of the friction properties of the mating metal and plastics surfaces is important to optimize the ejection system. The coefficient of friction at the ejection stage depends on the surface texture of the core and the temperature at ejection. This paper reviews recent research on the static coefficient of friction in moulding conditions. It also reviews results obtained with a prototype apparatus that reproduces the conditions occurring during the ejection phase.Portuguese Foundation for Science and Technology (Research Grant POCTI/ 32978/CTM/2000—Project Mouldfriction)Agency for Innovation (Research Grant IC-PMEP0015— Project Mouldforce