Effects of the excitation density on the laser output of two differently doped Yb:YAG ceramics

We report the behavior of two Yb(3+) doped ceramics (i.e. 10% at. and 20% at.) under quasi-continuous wave laser pumping. Two different behaviors are found depending on the density of Yb(3+) in the excited level. Experimental results show that at low population inversion density, the maximum output power and the efficiency are almost independent on the doping concentration. In particular, an output power as high as 8.9 W with a corresponding slope efficiency of 52% with respect to the injected pump power was reached with the 20% at. sample. Conversely, at high population inversion densities, the 20% doped sample shows a sudden decrease of the laser output for increasing pump power, due to the onset of a nonlinear loss mechanism. Finally, we report a comparison of the experimental results with numerical simulations for the evaluation of the inversion density and of the temperature distribution

Tunability enhancement of Yb:YLF based laser.

We present a comprehensive characterization of a laser, based on a high-quality heavily doped Yb:YLF crystal. The analysis includes the comparison of the laser efficiency in respect of the absorbed pump for both pi and sigma-polarization. In particular, for the tunable laser, we report an enhancement of the tuning range obtained by adapting the output coupler transmission in respect of the lasing wavelength. The experimental results obtained for various output coupling have also been compared with a numerical model in order to give information for a further enlargement of the tuning range

High efficiency laser action of 1% at. Yb 3+ :Sc 2 O 3 ceramic

We report the spectroscopic characteristics and the laser performances of a low-doped 1% at. Yb:Sc(2)O(3) ceramic sample. Under end- pumping at 933 nm and 968 nm in quasi-CW mode, at 1040.5 nm the laser delivers a maximum output power of 4.3 W and 1.77 W, respectively with a corresponding slope efficiency of 74% and 80%, which are, to the best of our knowledge, the highest value reported in literature for ceramics. We explored the tuning range of the sample, which spans from 1005 nm to 1050.5 nm, and finally we characterized the low losses tunable cavity at 1032 nm

Experimental evidence of a nonlinear loss mechanism in highly doped Yb:LuAG crystal

We report a rigorous study of the spectroscopic, laser and thermal properties of a 10at.% and a 15at.% Yb:LuAG crystals. A loss mechanism is observed in the medium with the highest doping, pumped at 936 nm and 968 nm, as a sharp and dramatic decrease of the laser output power is measured at higher excitation densities. The nonlinearity of the loss mechanism is confirmed by the fluorescence data and by the thermal lens. In particular, the dioptric power of the thermal lens acquired at different pumping levels shows a strong deviation of the expected linear trend. Here we report the influence of both the concentration and the ion excitation density of Yb3+ on the output powers, the slope efficiencies and the thresholds. Conversely excellent results are achieved with the 10at.%, which does not show any loss mechanism as at 1046 nm it delivers 11.8 W with a slope efficiency of eta(s) = 82%, which is, to the best of our knowledge, the highest value reported in literature for this material. (C) 2014 Optical Society of Americ

Spectroscopy and CW first laser operation of Yb-doped Gd_3(Al_05Ga_05)_5O_12 crystal

We present the spectroscopic characterization and laser operation of a 2%at. Yb doped Gd3(Al0.5Ga0.5)5O12 (Yb:GAGG) crystal, grown with the Czochralski method. We determined the absorption and the emission spectrum, the upper level lifetime, and the thermal conductivity. The internal disordered structure determines a significant broadening of the emission band (12.1 nm FWHM) with respect to the parent composition Yb:GGG (8 nm FWHM). The laser performances were evaluated on an end pumped cavity, using a CW semiconductor laser as the pump source. We obtained a maximum slope efficiency of 60.8% and an optical to optical efficiency of 46.0%, with a maximum output power of 4 W, limited only by the available pump power. The tuning range extends from 995 nm to 1050 nm. To our knowledge this is the first spectroscopic investigation and the first assessment of the laser performance of an Yb:GAGG crystal with this composition (i.e. Al/Ga balance = 0.5/0.5)

Improvements in the processing of Yb:YAG ceramic materials

Laser ceramics can attain a significant role in the frame of the generation of high peak power, high energy laser pulses at high repetition rate, applications where fiber lasers or single crystals undergo fundamental or technological limitations. A ceramic material in order to be used as a laser amplifier, needs to fulfil strict requirements in terms of properties, in particular microstructure, purity level, porosity. The important role played by the production process on the transparency of ceramic materials has been explained elsewhere. The current study focuses on the optimization of the powder processing. An innovative Spray Drying process of solvent-based suspensions has been adopted for the preparation of ready-to-press powders for the reactive sintering of Yb:YAG materials. The influence of the experimental conditions on the morphology of the granulated powders and eventually on the microstructure evolution during sintering and the transparency, is describe

Direct comparison of Yb3+:CaF2 and heavily doped Yb3+:YLF as laser media at room temperature.

We report an extensive comparison of the laser performances of diode-pumped Yb(3+):YLF (30% at.) and Yb(3+):CaF(2) (5% at.) crystals, lasing at room-temperature and operating in two different operation mode, i.e. Continuous Wave (CW) and quasi-CW. An in-depth investigation of the crystals behavior by changing the pump power, clearly shows the crystal absorption depends on the lasing conditions. Therefore, we report an unambiguous definition of the slope efficiency calculated taken into account the real measured crystal absorption under laser action. Finally, we present a study of problems related to thermally induced losses which are expected influencing the laser performance

Leveraging substrate flexibility and product selectivity of acetogens in two-stage systems for chemical production

Carbon dioxide (CO2 ) stands out as sustainable feedstock for developing a circular carbon economy whose energy supply could be obtained by boosting the production of clean hydrogen from renewable electricity. H2 -dependent CO2 gas fermentation using acetogenic microorganisms offers a viable solution of increasingly demonstrated value. While gas fermentation advances to achieve commercial process scalability, which is currently limited to a few products such as acetate and ethanol, it is worth taking the best of the current state-of-the-art technology by its integration within innovative bioconversion schemes. This review presents multiple scenarios where gas fermentation by acetogens integrate into double-stage biotechnological production processes that use CO2 as sole carbon feedstock and H2 as energy carrier for products' synthesis. In the integration schemes here reviewed, the first stage can be biotic or abiotic while the second stage is biotic. When the first stage is biotic, acetogens act as a biological platform to generate chemical intermediates such as acetate, formate and ethanol that become substrates for a second fermentation stage. This approach holds the potential to enhance process titre/rate/yield metrics and products' spectrum. Alternatively, when the first stage is abiotic, the integrated two-stage scheme foresees, in the first stage, the catalytic transformation of CO2 into C1 products that, in the second stage, can be metabolized by acetogens. This latter scheme leverages the metabolic flexibility of acetogens in efficient utilization of the products of CO2 abiotic hydrogenation, namely formate and methanol, to synthesize multicarbon compounds but also to act as flexible catalysts for hydrogen storage or production

Characterization of the lasing properties of a 5%Yb doped Lu_2SiO_5 crystal along its three principal dielectric axes

The laser performance of a 5% Yb doped Lu2SiO5 (Yb:LSO) has been investigated in quasi continuous-wave pumping regime along the three principal dielectric axes of the crystal, to obtain a complete characterization of its laser properties. The comparison among the obtained results for differently polarized lasers, in term of relative slope efficiency and absolute efficiency, allows the exploitability of different orientations of the material in order to be determined to obtain efficient laser sources. The laser slope efficiency and the energy conversion efficiency were similar for emission polarized along the three indicatrix axes, with noticeable maximum values of slope efficiency around 90% for polarization along the Y and Z axes. Tunable laser action has been obtained in the range 990 nm - 1084 nm, with sizeable differences in the shape of the tuning curve for polarization along the X, Y and Z axes. In particular, the tuning for polarization along the Z axis is relatively flat and uniform in the range 1023 nm - 1083 nm

Spectroscopic and laser characterization of Yb 0.15 :(Lu x Y 1-x ) 3 Al 5 O 12 ceramics with different Lu/Y balance.

We report a broad comparative analysis of the spectroscopic and laser properties of solid solution Lutetium-Yttrium Aluminum Garnet (LuYAG, (LuxY1-x)3Al5O12) ceramics doped with Yb. The investigation was mainly aimed to assess the impact of the Lu/Y ratio on the Yb optical and laser properties. Therefore we analyzed a set of samples with different Y/Lu balance, namely 25/75, 50/50 and 75/25, with 15% Yb doping. We found that the Yb absorption and emission spectra changed from YAG to LuAG when gradually increasing in Lu content. Regarding the laser emission, remarkable results were achieved with all samples. Maximum output power was 8.2 W, 7.3 W and 8.7 W for Y/Lu balance 25/75, 50/50 and 75/25 respectively, at 1030 nm; the slope efficiency and the optical-to-optical efficiencies approached or exceeded 60% and 50% respectively. The tuning range was investigated using an intracavity ZnSe prism. The broadest tuning range (998 nm to 1063 nm) was obtained with Y/Lu balance 75/25, whereas the emission of the other two samples extended from 1000 nm to 1058 nm. To the best of our knowledge, this is the first comparative analysis of Yb:LuYAG ceramics or crystals as laser host across such a broad range of Y/Lu ratios