Influência de anisotropia induzida e magnetostrição na magnetoimpedância e em sua relaxação em fitas amorfas de FeCoSiB

Orientador: Marcelo KnobelDissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Fisica "Gleb Wataghin"Resumo: Magnetoimpedância Gigante ( GM/) é o termo utilizado para descrever variações grandes e sensíveis na impedância, medida a alta frequência, de um material magnético doce, causadas pela aplicação de um campo magnético externo. Desde de sua descoberta recente, a GMI tem atraído muita atenção devido .as enormes perspectivas de aplicações tecnológicas, principalmente em sensores magnéticos. O mecanismo básico responsável pelo fenômeno da GMI está relacionado a mudanças na profundidade de penetração causadas pelas mudanças ocorridas na permeabilidade transversal da amostra devido a aplicação do campo externo. Outro efeito bastante interessante, que foi recentemente descoberto em amostras amorfas, é a lenta relaxação da sua impedância após uma mudança súbita na configuração de domínios. Este efeito, conhecido como aftereffect da GMI (MIAE), possui implicações técnicas importantes pois, após o rearranjo de estrutura de domínios da amostra, sua impedância leva alguns segundos para atingir um valor de equilíbrio, seguindo uma cinética quase-logarítirnica. Propõe-se que este efeito está conectado com o da relaxação da permeabilidade inicial ( desacomodação). Este trabalho apresenta resultados do efeito da GMI e de sua relaxação em fitas amorfas de composição (FexCO1-x)7OSi12B18 com valores de x próximos de 0.057, antes e depois de um tratamento térmico tendo as seguintes condições: 1 h de pré-tratamento a uma temperatura de 360°C seguido de 1 h de tratamento a uma temperatura de 340oC, porém com uma tensão de 400 MPa aplicada longitudinalmente à amostra.. Foi estudada a influência da constante de magnetostrição de saturação ls e da anisotropia induzida pelo referido tratamento, nos efeitos da GMI e do MIAE. Foi verificado que a forma da curva GMI vs. campo externo é extremamente sensível a anisotropia induzida pelo tratamento térmico, e que o MIAE foi drasticamente reduzido após o tratamento. Os resultados do MIAE obtidos para uma frequência de 100 kHz da corrente de sonda foram explicados utilizando os modelos de desacomodação já existentes, enquanto que a causa do efeito para 900 kHz foi atribuída a mecanismos de dissipaçãoAbstract: Giant Magnetoimpedance (GMI) is a term coined to describe large and sensitive field induced changes in the high frequency impedance of soft magnetic materials. Since its recent discovery, GMI has attracted much attenction owing to the enormous perspectives in technological aplications, mainly as magnetic field sensors. The basic mechanism responsible for the GMI phenomenon is the change of the magnetic penetration depth through field induced modifications of the transversal permeability. Another interesting effect that has been recently discovered in amorphous samples is the slow relaxation of the impedance after a sudden change of the domain configuration. This effect, known as Magnetoimpedance Aftereffect (MJAE), has important technical implications because the impedance takes few seconds to achieve a stable value, following a quasi-logarithmic kinetics. This effect seems to be connected with the relaxation of the initial magnetic permeability (disaccommodation). This work presents results of GMJ effect and its relaxation in amorphous ribbons of composition (FexCo1-x)7OSi12B18 whith x values close to 0.057, before and after a thermal annealing consisting of 1 h pre-annealing at 360°C followed by 1 h stress-annealing at 340°C whith applied tensile stress of 400 MPa. The influence of saturation magnetostricton constant ls and anisotropy induced by this particular annealing was studied on GMJ and MJAE effects. It was verified that the shape of the impedance vs. applied field curves results to be extremely sensitive to the induced anisotropies, and that the MIAE effect was drastically suppressed after annealing. The results of MlAE obtained from 100 kHz frequency of driving current are aplained using the existent disaccommodation models, while in the case of 900 kHz dissipatives mechanisms were consideredMestradoFísicaMestre em Físic

Electrical Manipulation of a Single Nanowire by Dielectrophoresis

Nanowires (NWs), due to their unique highly anisotropic characteristics, hold a great promise to be used in wide technological fields, such as building blocks for data storage and memory, advanced scanning probes, and biotechnological applications. In addition, given the high sensitivity to their environment, NWs can be used as sensor for a number of applications. The fabrication and electrical characterization of NW‐based devices can be achieved after proper placing of NWs between electrodes, which represents one of the major challenges in this field. The dielectrophoresis (DEP) method can be used to trap electrically neutral NWs by the application of an alternating electric field between a pair of electrodes. Here, we present a systematic study of DEP parameters as well as electrodes geometry for NW deposition. This method presents a suitable protocol for deposition in a useful and coherent fashion of post‐growth electrodeposited NWs and further electrical characterization. This can be used for investigation of the fundamental transport properties of individual NWs and fabrication of NW‐based devices, such as sensors and field‐effect transistors

Synthesis and magnetic properties of cobalt-iron/cobalt-ferrite soft/hard magnetic core/shell nanowires

A straightforward method for the synthesis of CoFe2.7/CoFe2O4 core/shell nanowires is described. The proposed method starts with a conventional pulsed electrodeposition procedure on alumina nanoporous template. The obtained CoFe2.7 nanowires are released from the template and allowed to oxidize at room conditions over several weeks. The effects of partial oxidation on the structural and magnetic properties were studied by x-ray spectrometry, magnetometry, and scanning and transmission electron microscopy. The results indicate that the final nanowires are composed of 5 nm iron-cobalt alloy nanoparticles. Releasing the nanowires at room conditions promoted surface oxidation of the nanoparticles and created a CoFe2O4 shell spinel-like structure. The shell avoids internal oxidation and promotes the formation of bi-magnetic soft/hard magnetic core/shell nanowires. The magnetic properties of both the initial single-phase CoFe2.7 nanowires and the final core/shell nanowires, reveal that the changes in the properties from the array are due to the oxidation more than effects associated with released processes (disorder and agglomeration).Fil: Londoño Calderon, Cesar Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Moscoso Londoño, Oscar. Universidade Estadual de Campinas; Brasil. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Muraca, Diego. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidade Estadual de Campinas; Brasil. Brazilian Center for Research in Energy and Materials. Brazilian Nanotechnology National Laboratory; BrasilFil: Arzuza, Luis. Universidade Estadual de Campinas; BrasilFil: Carvalho, Peterson. Universidade Estadual de Campinas; BrasilFil: Pirota, Kleber Roberto. Universidade Estadual de Campinas; BrasilFil: Knobel, Marcelo. Universidade Estadual de Campinas; BrasilFil: Pampillo, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long". Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnologías y Ciencias de la Ingeniería "Hilario Fernández Long"; ArgentinaFil: Martinez Garcia, Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional de Formosa. Facultad de Recursos Naturales; Argentin

Domain wall propagation tuning in magnetic nanowires through geometric modulation

The magnetic behavior of nickel modulated nanowires embedded in porous alumina membranes is investigated. Their diameters exhibit a sharp transition between below (35 nm) and above (52 nm) the theoretical limit for transverse and vortex domain walls. Magnetic hysteresis loops and first-order reversal curves (FORCs) were measured on several ordered nanowire arrays with different wide-narrow segment lengths ratio and compared with those from homogenous nanowires. The experimental magnetic response evidences a rather complex susceptibility behavior for nanowires with modulated diameter. Micromagnetic simulations on isolated and first-neighbors arrays of nanowires show that the domain wall structure, which depends on the segment diameter, suffers a transformation while crossing the diameter modulation, but without any pinning. The experimental array magnetic behavior can be ascribed to a heterogeneous stray field induced by the diameter modulation, yielding a stronger interaction field at the wide extremity than at the narrow one. The results evidence the possibility to control the domain wall propagation and morphology by modulating the lateral aspect of the magnetic entity

Magnetoimpedância gigante em fios e fitas amorfos

Orientador: Marcelo KnobelTese (doutorado) - Universidade Estadual de Campinas, Instituto de Fisica Gleb WataghinResumo: Esta tese mostra os resultados de três anos e meio dedicados a investigação do fenômeno da Magnetoimpedância gigante (GMI) em fitas ferromangéticas amorfas e microfios amorfos cobertos por uma camada de vidro. Os resultados obtidos em microfios comprovaram a viabilidade da sua utilização em aplicações que usam o fenômeno da Magnetoimpedância. Com relação às fitas, com a indução de anisotropia transversal mediante tratamentos térmicos com tensão, deixou-se claro a possibilidade de se construir um sensor de tensão que faz uso da GMI. Além do trabalho experimental, que envolveu caracterização magnética de amostras, tratamentos térmicos e medidas de GMI, também foi dada uma contribuição teórica no que diz respeito ao entendimento da influência de anisotropias magnéticas e sua distribuição no efeito da GMIAbstract: This work shows the results of the Giant Magnetoimpedance (GMI) investigations in ferromagnetics ribbons and glass-covered amorphous microwires. The results in microwires demonstrate the viability of its use for GMI applications. Concerning the ribbons, with induced transversal magnetic anisotropy by means of stress-annealing, the possibility of its use as a stress sensor was comproved. In addition witn the experimental work, also some theoretical contribution was done in order to clarify the influence of anisotropies and its distribution on GMI effectDoutoradoFísicaDoutor em Ciência

Influence of the metal ion on the topology and interpenetration of Pyridylvinyl(benzoate) based metal-organic frameworks

FAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOCAPES - COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIORA family of four M(II)-metal-organic frameworks of general formula {[M-x(pvb)(2x)]y(dmf)}(n) (M = Cu, 1; M = Co, 2; M = Ni, 3; M = Mn, 4), based on the bis{4-[2-(4-pyridyl)ethenyl]} benzoic acid (Hpvb) ligand, were obtained. 1 exhibits a 5-fold interpenetrated lvt framework, 2 and 3 a 7-fold interpenetrating dia framework, and 4 a 2-fold interpenetrated dmc framework. Magnetic properties of 1-4 have been investigated. 1 was analyzed by a Curie-Weiss model, while 2 and 3 where analyzed by a zero-field splitting model due to the very long metal-metal distances, which results in very weak antiferromagnetic interactions. The coupling pathway in 4 was done by carboxylate bridges instead of the pvb pathway, affording a short metal-metal separation that was analyzed by a isotropic Heisenberg spin Hamiltonian for a linear trinuclear Mn(II) cluster. The different metal coordination modes and geometries, along with template effects induced by the solvent, play an important role in the formation of distinctive structural topologies.191055925603FAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOCAPES - COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIORFAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOCAPES - COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR2015/22379-700

Observation of ferromagnetism in PdCo alloy nanoparticles encapsulated in carbon nanotubes

INCT - INSTITUTO NACIONAL DE CIÊNCIA E TECNOLOGIA METROLOGIA DE RADIAÇÃO EM MEDICINACNPQ – CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOFAPESP – FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOFAPEMIG - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE MINAS GERAISLNLS - LABORATÓRIO NACIONAL DE LUZ SÍNCROTRONCarbon nanotubes terminated by PdCo catalyst nanoparticles were grown by plasma-enhanced chemical vapor deposition. Transmission electron microscopy reveals that these nanoparticles have a droplike shape and are completely encapsulated inside multiwalled nanotubes. Magnetization measurements showed the existence of a permanent magnetization with a small shape anisotropy effect. The magnetization of both cobalt and palladium was confirmed by x-ray magnetic circular dichroism. These results show that nanotubes ended by magnetic PdCo nanoparticles can be grown and could be used in magnetic storage media and electrical spin injection.9625INCT - INSTITUTO NACIONAL DE CIÊNCIA E TECNOLOGIA METROLOGIA DE RADIAÇÃO EM MEDICINACNPQ – CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOFAPESP – FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOFAPEMIG - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE MINAS GERAISLNLS - LABORATÓRIO NACIONAL DE LUZ SÍNCROTRONINCT - INSTITUTO NACIONAL DE CIÊNCIA E TECNOLOGIA METROLOGIA DE RADIAÇÃO EM MEDICINACNPQ – CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOFAPESP – FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOFAPEMIG - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE MINAS GERAISLNLS - LABORATÓRIO NACIONAL DE LUZ SÍNCROTRO

Synthesis and Characterization of Iron Oxyhydroxide Nanowires

A very simple method of synthesis of goethite,alfa-FeOOH, nanowire is reported. To fabricate the nanowires, an anodiezed alumina nanoporous template (AAO) is used. AAO has pores with an average diameter of 60 nm. The synthesis is based on a self-combustion reaction of the chemical precursor (Fe(NO3)3 satured solution) which occurs inside the nanopores. The geometry of AAO determines the morphology of the nanowires and the confinement conditions in which the heat treatment determines the composition of the nanostruc- ture. The nanowires are characterized using scanning electronmicroscopy, high resolution transmission electronmicroscopy andmagne- tometry [magnetization versus applied field (M versus H)]. TEM analysis indicates that nanowires are composed of several alfa-FeOOH single crystals. The nanowires have a clear magnetic oriented structure.Fil: Londoño Calderon, Cesar Leandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; ArgentinaFil: Bilovol, Vitaliy. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; ArgentinaFil: Cosio Castañeda, Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; ArgentinaFil: Pampillo, Laura Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; ArgentinaFil: Micheli, Sabina R.. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; ArgentinaFil: Pirota, Kleber Roberto. Universidade Estadual de Campinas; BrasilFil: Socolovsky, Leandro Martin. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; ArgentinaFil: Martinez Garcia, Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnologías y Ciencias de la Ingeniería; Argentin