25 research outputs found
Spin-orbit coupling and proximity effects in metallic carbon nanotubes
We study spin-orbit coupling in metallic carbon nanotubes (CNTs) within the
many-body Tomonaga-Luttinger liquid (TLL) framework. For a well defined
sub-class of metallic CNTs, that contains both achiral zig-zag as well as a
sub-set of chiral tubes, an effective low energy field theory description is
derived. We aim to describe system at finite dopings, but close to the charge
neutrality point (commensurability). A new regime is identified where
spin-orbit coupling leads to an inverted hierarchy of mini-gaps of bosonic
modes. We then add a proximity coupling to a superconducting (SC) substrate and
show that the only order parameter that is supported within the novel,
spin-orbit induced phase is a topologically trivial s-SC.Comment: accepted in PhysRev
The two classes of low energy spectra in finite carbon nanotubes
Electrons in carbon nanotubes (CNTs) possess spin and orbital degrees of
freedom. The latter is inherited from the bipartite graphene lattice with two
inequivalent Dirac points. The electronic spectra obtained in several transport
experiments on CNT quantum dots in parallel magnetic field often show an
anticrossing of spectral lines assigned to the opposite Dirac valleys. So far
this valley mixing has been attributed to the disorder, with impurity induced
scattering. We show that this effect can arise also in ultraclean CNTs of the
armchair class and it can be caused solely by the presence of the boundaries.
In contrast, in CNTs of the zigzag class it does not occur. These two
fundamentally different classes of spectra arise because of different
symmetries of the low energy eigenstates of the two types of CNTs. The
magnitude of the level splitting depends in a nonmonotonous way on the distance
of the involved energy levels from the charge neutrality point.Comment: 5 pages, 4 figures, available Supplementary Materia
Magnetic phases in the one-dimensional Kondo chain on a metallic surface
We study the low-temperature properties of a one-dimensional spin-1/2 chain
of magnetic impurities coupled to a (normal) metal environment by means of
anisotropic Kondo exchange. In the case of easy-plane anisotropy, we obtain the
phase diagram of this system at T=0. We show that the in-plane Kondo coupling
destabilizes the Tomonaga-Luttinger phase of the spin-chain, and leads to two
different phases: i) At strong Kondo coupling, the spins in the chain form
Kondo singlets and become screened by the metallic environment, and ii) At weak
and intermediate Kondo coupling, we find a novel dissipative phase
characterized by diffusive gapless spin excitations. The two phases are
separated by a quantum critical point of the Wilson-Fisher universality class
with dynamical exponent .Comment: 15 pages, 3 figures. New version contains clarifications about the
specific approximations. Accepted for publication in PR
Magnetoplasmon resonances in polycrystalline bismuth as seen via terahertz spectroscopy
We report the magnetic field-dependent far-infrared reflectivity of
polycrystalline bismuth. We observe four distinct absorptions that we attribute
to magnetoplasmon resonances, which are collective modes of an electron-hole
liquid in magnetic field and become optical and acoustic resonances of the
electron-hole system in the small-field limit. The acoustic mode is expected
only when the masses of distinct components are very different, which is the
case in bismuth. In a polycrystal, where the translational symmetry is broken,
a big shift of spectral weight to acoustic plasmon is possible. This enables us
to detect an associated plasma edge. Although the polycrystal sample has grains
of randomly distributed orientations, our reflectivity results can be explained
by invoking only two, clearly distinct, series of resonances. In the limit of
zero field, the optical modes of these two series converge onto plasma
frequencies measured in monocrystal along the main optical axes.Comment: Accepted in PR
Performance Modeling and Analysis of a Thermoelectric Building Envelope for Space Heating
To provide energy-efficient space heating and cooling, a thermoelectric building envelope (TBE) embeds thermoelectric devices in building walls. The thermoelectric device in the building envelope can provide active heating and cooling without requiring refrigerant use and energy transport among subsystems. Thus, the TBE system is energy and environmentally friendly. A few studies experimentally investigated the TBE under limited operating conditions, and only simplified models for the commercial thermoelectric module (TEM) were developed to quantify its performance. A holistic approach to optimum system performance is needed for the optimal system design and operation. The study developed a holistic TBE-building system model in Modelica for system simulation and performance analysis. A theoretical model for a single TEM was first established based on energy conversion and thermoelectric principles. Subsequently, a TBE prototype model combining the TEM model was constructed. The prototype model employing a feedback controller was used in a whole building system simulation for a residential house. The system model computed the overall building energy efficiency and dynamic indoor conditions under varying operating conditions. Simulation results indicate the studied TBE system can meet a heating demand to maintain the desired room temperature at 20 °C when the lowest outdoor temperature is at -26.3 degrees C, with a seasonal heating COP near 1.1, demonstrating a better heating performance than electric heaters. It suggests a potential energy-efficient alternative to the traditional natural gas furnaces and electric heaters for space heating
Performance Modeling and Analysis of a Thermoelectric Building Envelope for Space Heating
To provide energy-efficient space heating and cooling, a thermoelectric building envelope (TBE) embeds thermoelectric devices in building walls. The thermoelectric device in the building envelope can provide active heating and cooling without requiring refrigerant use and energy transport among subsystems. Thus, the TBE system is energy and environmentally friendly. A few studies experimentally investigated the TBE under limited operating conditions, and only simplified models for the commercial thermoelectric module (TEM) were developed to quantify its performance. A holistic approach to optimum system performance is needed for the optimal system design and operation. The study developed a holistic TBE-building system model in Modelica for system simulation and performance analysis. A theoretical model for a single TEM was first established based on energy conversion and thermoelectric principles. Subsequently, a TBE prototype model combining the TEM model was constructed. The prototype model employing a feedback controller was used in a whole building system simulation for a residential house. The system model computed the overall building energy efficiency and dynamic indoor conditions under varying operating conditions. Simulation results indicate the studied TBE system can meet a heating demand to maintain the desired room temperature at 20 °C when the lowest outdoor temperature is at -26.3 degrees C, with a seasonal heating COP near 1.1, demonstrating a better heating performance than electric heaters. It suggests a potential energy-efficient alternative to the traditional natural gas furnaces and electric heaters for space heating
Towards temperature-induced topological phase transition in SnTe: A first principles study
The temperature renormalization of the bulk band structure of a topological
crystalline insulator, SnTe, is calculated using first principles methods. We
explicitly include the effect of thermal-expansion-induced modification of
electronic states and their band inversion on electron-phonon interaction. We
show that the direct gap decreases with temperature, as both thermal expansion
and electron-phonon interaction drive SnTe towards the phase transition to a
topologically trivial phase as temperature increases. The band gap
renormalization due to electron-phonon interaction exhibits a non-linear
dependence on temperature as the material approaches the phase transition,
while the lifetimes of the conduction band states near the band edge show a
non-monotonic behavior with temperature. These effects should have important
implications on bulk electronic and thermoelectric transport in SnTe and other
topological insulators.Comment: 10 pages, 8 figures. Accepted for publication in Phys. Rev. B on June
8, 202
State of the art in composition, fabrication, characterization, and modeling methods of cement-based thermoelectric materials for low-temperature applications
The worldwide energy crisis and environmental deterioration are probably humanity’s greatest challenges. Thermoelectricity, which allows for the mutual conversion between thermal and electrical energy, has become a promising technology to alleviate this challenge. Increasingly more research focuses on how to fabricate and apply thermoelectric materials for harvesting energy and regulating the indoor thermal environment. However, only a few studies have focused on cementitious materials with thermoelectric potential. Thermoelectric cement is a composite material in which particular additives can enhance the thermoelectric performance of ordinary cement. By potentially replacing traditional construction materials with thermoelectric cement in building applications, electricity could be generated from waste heat, reducing the use of fossil fuels, and supplementing other renewable energy sources like solar and wind. This article presents a review of fundamentals, fabrication, characterization, composition, and performance, as well as modeling methods and opportunities for thermoelectric cement composites. The literature reviewed covers the period from 1998 to 2020 related to thermoelectric cement. It also presents the challenges and problems to overcome for further development and provide future research directions of thermoelectric cement
Modelling the thermoelectric properties of cement-based materials using finite element method and effective medium theory
Because of the thermoelectric (TE) effect (or Seebeck effect), a difference of potential is generated as a consequence of a temperature gradient across a sample. The TE effect has been mostly studied and engineered in semiconducting materials and it already finds several commercial applications. Only recently the TE effect in cement-based materials has been demonstrated and there is a growing interest in its potential. For instance, a temperature gradient across the external walls of a building can be used to generate electricity. By the inverse of the TE effect (or Peltier effect), one can also seek to control the indoor temperature of a building by biasing TE elements embedded in its external walls. In designing possible applications, the TE properties of cement-based materials must be determined as a function of their chemical composition. For instance, the TE properties of cement paste can be enhanced by the addition of metal oxide (e.g., Fe2O3) powder. In this paper, a single thermoelectric leg is studied using the finite element method. Metal oxide additives in the cement paste are modelled as spherical inhomogeneities. The thermoelectric properties of the single components are based on experimental data, while the overall thermoelectric properties of the composites are obtained from the numerical model. The results of this numerical study are interpreted according to the effective medium theory (EMT) and its generalisation (GEMT)