3,262 research outputs found
Phase diagram of symmetric binary mixtures at equimolar and non-equimolar concentrations: a systematic investigation
We consider symmetric binary mixtures consisting of spherical particles with
equal diameters interacting via a hard-core plus attractive tail potential with
strengths epsilon_{ij}, i,j=1,2, such that epsilon_{11} = epsilon_{22} >
epsilon_{12}. The phase diagram of the system at all densities and
concentrations is investigated as a function of the unlike-to-like interaction
ratio delta = epsilon_{12}/epsilon_{11} by means of the hierarchical reference
theory (HRT). The results are related to those of previous investigations
performed at equimolar concentration, as well as to the topology of the
mean-field critical lines. As delta is increased in the interval 0 < delta < 1,
we find first a regime where the phase diagram at equal species concentration
displays a tricritical point, then one where both a tricritical and a
liquid-vapor critical point are present. We did not find any clear evidence of
the critical endpoint topology predicted by mean-field theory as delta
approaches 1, at least up to delta=0.8, which is the largest value of delta
investigated here. Particular attention was paid to the description of the
critical-plus-tricritical point regime in the whole density-concentration
plane. In this situation, the phase diagram shows, in a certain temperature
interval, a coexistence region that encloses an island of homogeneous,
one-phase fluid.Comment: 27 pages + 20 figure
Local search for stable marriage problems
The stable marriage (SM) problem has a wide variety of practical
applications, ranging from matching resident doctors to hospitals, to matching
students to schools, or more generally to any two-sided market. In the
classical formulation, n men and n women express their preferences (via a
strict total order) over the members of the other sex. Solving a SM problem
means finding a stable marriage where stability is an envy-free notion: no man
and woman who are not married to each other would both prefer each other to
their partners or to being single. We consider both the classical stable
marriage problem and one of its useful variations (denoted SMTI) where the men
and women express their preferences in the form of an incomplete preference
list with ties over a subset of the members of the other sex. Matchings are
permitted only with people who appear in these lists, an we try to find a
stable matching that marries as many people as possible. Whilst the SM problem
is polynomial to solve, the SMTI problem is NP-hard. We propose to tackle both
problems via a local search approach, which exploits properties of the problems
to reduce the size of the neighborhood and to make local moves efficiently. We
evaluate empirically our algorithm for SM problems by measuring its runtime
behaviour and its ability to sample the lattice of all possible stable
marriages. We evaluate our algorithm for SMTI problems in terms of both its
runtime behaviour and its ability to find a maximum cardinality stable
marriage.For SM problems, the number of steps of our algorithm grows only as
O(nlog(n)), and that it samples very well the set of all stable marriages. It
is thus a fair and efficient approach to generate stable marriages.Furthermore,
our approach for SMTI problems is able to solve large problems, quickly
returning stable matchings of large and often optimal size despite the
NP-hardness of this problem.Comment: 12 pages, Proc. COMSOC 2010 (Third International Workshop on
Computational Social Choice
Anisotropy effects on the magnetic excitations of a ferromagnetic monolayer below and above the Curie temperature
The field-driven reorientation transition of an anisotropic ferromagnetic
monolayer is studied within the context of a finite-temperature Green's
function theory. The equilibrium state and the field dependence of the magnon
energy gap are calculated for static magnetic field applied in plane
along an easy or a hard axis. In the latter case, the in-plane reorientation of
the magnetization is shown to be continuous at T=0, in agreement with free spin
wave theory, and discontinuous at finite temperature , in contrast with
the prediction of mean field theory. The discontinuity in the orientation angle
creates a jump in the magnon energy gap, and it is the reason why, for ,
the energy does not go to zero at the reorientation field. Above the Curie
temperature , the magnon energy gap vanishes for H=0 both in the
easy and in the hard case. As is increased, the gap is found to increase
almost linearly with , but with different slopes depending on the field
orientation. In particular, the slope is smaller when is along the hard
axis. Such a magnetic anisotropy of the spin-wave energies is shown to persist
well above ().Comment: Final version accepted for publication in Physical Review B (with
three figures
Non-homogeneous hydrogen deflagrations in small scale enclosure. Experimental results
Abstract University of Pisa performed hydrogen releases and deflagrations in a 1.14 m3 test facility, which shape and dimensions resemble a gas cabinet. Tests were performed for the HySEA project, founded by the Fuel Cells and Hydrogen 2 Joint Undertaking with the aim to conduct pre-normative research on vented deflagrations in enclosures and containers used for hydrogen energy applications. The test facility, named Small Scale Enclosure (SSE), has a vent area of 0,42 m2 which can host different types of vent; plastic sheet and commercial vent were tested. Realistic levels of congestion are obtained placing a number of gas bottles inside the enclosure. Releases are performed from a buffer tank of a known volume filled with hydrogen at a pressure ranging between 15 and 60 bar. Two nozzles of different diameter and three different release directions were tested, being the nozzle placed at a height where in a real application a leak has the highest probability to occur. Three different ignition locations were investigated as well. This paper is aimed to summarize the main features of the experimental campaign as well as to present its results
Validity and reliability of the Structured Clinical Interview for Depersonalization-Derealization Spectrum (SCI-DER).
This study evaluates the validity and reliability of a new instrument developed to assess symptoms of depresonalization: the Structured Clinical Interview for the Depersonalization-Derealization Spectrum (SCI-DER). The instrument is based on a spectrum model that emphasizes soft-signs, sub-threshold syndromes as well as clinical and subsyndromal manifestations. Items of the interview include, in addition to DSM-IV criteria for depersonalization, a number of features derived from clinical experience and from a review of phenomenological descriptions. Study participants included 258 consecutive patients with mood and anxiety disorders, 16.7% bipolar I disorder, 18.6% bipolar II disorder, 32.9% major depression, 22.1% panic disorder, 4.7% obsessive compulsive disorder, and 1.5% generalized anxiety disorder; 2.7% patients were also diagnosed with depersonalization disorder. A comparison group of 42 unselected controls was enrolled at the same site. The SCI-DER showed excellent reliability and good concurrent validity with the Dissociative Experiences Scale. It significantly discriminated subjects with any diagnosis of mood and anxiety disorders from controls and subjects with depersonalization disorder from controls. The hypothesized structure of the instrument was confirmed empirically
Phase transitions in simple and not so simple binary fluids
Compared to pure fluids, binary mixtures display a very diverse phase
behavior, which depends sensitively on the parameters of the microscopic
potential. Here we investigate the phase diagrams of simple model mixtures by
use of a microscopic implementation of the renormalization group technique.
First, we consider a symmetric mixture with attractive interactions, possibly
relevant for describing fluids of molecules with internal degrees of freedom.
Despite the simplicity of the model, slightly tuning the strength of the
interactions between unlike species drastically changes the topology of the
phase boundary, forcing or inhibiting demixing, and brings about several
interesting features such as double critical points, tricritical points, and
coexistence domains enclosing `islands' of homogeneous, mixed fluid.
Homogeneous phase separation in mixtures can be driven also by purely repulsive
interactions. As an example, we consider a model of soft particles which has
been adopted to describe binary polymer solutions. This is shown to display
demixing (fluid-fluid) transition at sufficiently high density. The nature and
the physical properties of the corresponding phase transition are investigated.Comment: 6 pages + 3 figures, presented at the 5th EPS Liquid Matter
Conference, Konstanz, 14-18 September 200
Beyond functional MRI signals: molecular and cellular modifiers of the functional connectome and cognition
Ordered structures formed by ultrasoft, aspherical particles
We have applied the formalism of classical density functional theory to study the shape and the orientation of the density profiles rho(r) formed by aspherical, ultrasoft particles. For simplicity we have considered particles with an elliptic shape, characterised by an aspect ratio lambda. The rho(r)\u2019s are obtained via the minimisation of the grand-potential functional Omega[rho], for which we have used a mean-field format. The optimisation of Omega[rho] is numerically realised in a free (i.e. unbiased) manner minimising the functional with respect to the density profile, which we have discretised in the unit cell of the lattice on 80^3 grid points. Keeping the temperature fixed and varying the chemical potential and lambda, we have investigated the impact of these parameters on the density profile
- …