Atmospheric dry and wet deposition of sulphur and nitrogen species and assessment of critical loads of acidic deposition exceedance in South Africa

We tested the hypothesis that acidic atmospheric pollution deposition, originating from the South African central industrial area, poses an environmental threat across a larger region within the dispersal footprint. A network of 37 passive monitoring sites to measure SO2 and NO2 was operated from August 2005 to September 2007. The area extended over the entire northern and eastern interior of South Africa. Monitoring locations were chosen to avoid direct impacts from local sources such as towns, mines and highways. Dry deposition rates of SO2 and NO2 were calculated from the measured concentrations. Concentrations of sulphur and nitrogen species in wet deposition from a previous study were used in conjunction with measured rainfall for the years 2006 and 2007 to estimate the wet deposition over the region. The calculated total (non-organic) acidic deposition formed the basis for an assessment of exceedance of critical loads based on sensitivity of the regional soils. Regional soil sensitivity was determined by combining two major soil attributes available in the World Inventory of Soil Emission Potentials (International Soil Reference and Information Centre). Results indicate that certain parts of the central pollution source area on the South African Highveld have the potential for critical load exceedance, while limited areas downwind show lower levels of exceedance. Areas upwind and remote areas up and downwind, including forested areas of the Drakensberg escarpment, do not show any exceedance of the critical loads

Surface Ozone Variability and Trends over the South African Highveld from 1990 to 2007

Surface ozone is a secondary air pollutant formed from reactions between nitrogen oxides (NOx = NO + NO2) and volatile organic compounds in the presence of sunlight. In this work we examine effects of the climate pattern known as the El Nio-Southern Oscillation (ENSO) and NOx variability on surface ozone from 1990 to 2007 over the South African Highveld, a heavily populated region in South Africa with numerous industrial facilities. Over summer and autumn (December-May) on the Highveld, El Nio, as signified by positive sea surface temperature (SST) anomalies over the central Pacific Ocean, is typically associated with drier and warmer than normal conditions favoring ozone formation. Conversely, La Nia, or negative SST anomalies over the central Pacific Ocean, is typically associated with cloudier and above normal rainfall conditions, hindering ozone production. We use a generalized regression model to identify any linear dependence that the Highveld ozone, measured at five air quality monitoring stations, may have on ENSO and NOx. Our results indicate that four out of the five stations exhibit a statistically significant sensitivity to ENSO at some point over the December-May period where El Nio amplifies ozone formation and La Nia reduces ozone formation. Three out of the five stations reveal statistically significant sensitivity to NOx variability, primarily in winter and spring. Accounting for ENSO and NOx effects throughout the study period of 18 years, two stations exhibit statistically significant negative ozone trends in spring, one station displays a statistically significant positive trend in August, and two stations show no statistically significant change in surface ozone

Quantification of Emissions Generated from Domestic Burning Activities from Townships in Johannesburg

Domestic burning activities, specifically in informal settlements, contribute greatly to the air quality problems experienced by most developing urban centres. Low-income households that exist within townships in South Africa house a large portion of the South African population. These households burn vast quantities of coal, wood and other substances to provide for their energy needs. Pollutants emitted as a result of domestic burning are estimated to be one of the leading causes of respiratory illnesses in inhabitants of townships. To better understand the relationship that exists between domestic burning and the resultant pollutants, a method of quantifying these pollutants has been developed for a completely un-electrified settlement, near Johannesburg, using the quantities and type of fuel consumed. Seasonality, availability, price and cultural aspects all have a bearing on the fuel source choice and the quantity consumed. The most significant temporal observations identified for domestic burning are seasonal ones

Correcting respirable photometric particulate measurements using a gravimetric sampling method

According to the National Environmental Management: Air Quality Act of 2004 people have the right to clean air and a healthy environment. Particulate matter (PM) emissions pose a significant health threat. Both indoor and ambient air pollution contribute to the burden of disease associated with poor air quality. This is particularly true within the South African setting where low income households make use of different solid fuels for heating and cooking purposes resulting in high levels of PM emissions. This paper focuses on the evaluation mass concentration measurements recorded by continuous photometric PM instruments within KwaDela, a low income settlement in Mpumalanga located on the South African Highveld. Thus, obtaining a photometric calibration factor for both the DustTrak Model 8530 and the SidePak AM510. Sampling took place during August 2014 for a period of seven days. The photometric and gravimetric instruments were collocated within the indoor environment of selected households. These instruments were all fitted with 10mm Dorr-Oliver Cyclone inlets to obtain the respirable (PM4) cut-point. The study found that both instruments tend to overestimate the indoor particulate mass concentrations when compared to the reference gravimetric method. The estimated photometric calibration factors for the DustTrak Model 8530 and SidePak AM510 are 0.14 (95%Cl: 0.09, 0.15) and 0.24 (95%Cl: 0.16, 0.30) respectively. The overestimation of the photometric measurements is rather significant. It is therefore important that the correction factors are applied to data collected in indoor environments prone to the combustion of solid fuels. The correction factors obtained from this and other studies vary as a result of the environment (ambient, indoor etc.) as well as the aerosol size fraction and the origin thereof. Thus, it is important to considered site specific calibration factors when implementing these photometric light-scattering instruments

Idiopathic focal eosinophilic enteritis associated with ileocaecal and ileal obstruction in a 10-year-old warmblood gelding

A 10-year-old, 600-kg, warmblood gelding was referred due to persistent colic, non-responsive to medical treatment. Diagnostic evaluation revealed abdominal distention, tachycardia and distended small intestines. Preoperative blood testing revealed an increased packed cell volume and normal total white cell count, whereas an abdominocentesis revealed raised peritoneal fluid lactate. Exploratory laparotomy was performed and revealed a circumferential band of thickened tissue and hyperaemia in the distal jejunum, as well as marked wall thickening of the distal ileum and ileocaecal valve, leading to complete luminal obstruction. Due to financial constraints and complications associated with jejuno-caecostomy, the owner requested the horse to be humanely euthanased. Postmortem examination findings revealed a circumferential constriction of the distal ileum and ileocaecal valve. Histopathology of the affected segments was characterised by a large population of eosinophils within the mucosa, submucosa and muscularis layers in conjunction with severe submucosal oedema. A diagnosis of idiopathic focal eosinophilic enteritis was made.https://wileyonlinelibrary.com/journal/vrc2hj2023Companion Animal Clinical StudiesParaclinical Science

Smoke and clouds above the Southeast Atlantic: upcoming field campaigns probe absorbing aerosol’s impact on climate

ArticleFrom July through October, smoke from biomass burning fires on the southern African sub-continent are transported westward through the free troposphere over one of the largest stratocumulus cloud decks on our planet. Biomass burning aerosol (smoke) absorbs shortwave radiation efficiently. This fundamental property implicates smoke within myriad small-scale processes with potential large-scale impacts on climate that are not yet well-understood. A coordinated, international team of scientists from the United States, United Kingdom, France, South Africa and Namibia will provide an unprecedented interrogation of this smoke-and-cloud regime from 2016 to 2018, using multiple aircraft and surface-based instrumentation suites to span much of the breadth of the southeast Atlantic

Indoor and outdoor particulate matter concentrations on the Mpumalanga highveld – A case study

The household combustion of solid fuels, for the purpose of heating and cooking, is an activity practiced by many people in South Africa. Air pollution caused by the combustion of solid fuels in households has a significant influence on public health. People mostaffected are those considered to be the poorest, living in low-income settlements, where burning solid fuel is the primary source of energy. Insufficient data has been collected in South Africa to quantify the concentrations of particulate emissions that peopleare exposed to, especially the respirable fraction, associated with the combustion of solid fuels. The aim of this paper is to gain an understanding of the particulate matter (PM) concentrations a person living in a typical household in a low income settlement in theSouth African Highveld is exposed to. It also seeks to demonstrate that the use of solid fuels in the household can lead to indoor air pollution concentrations reaching levels very similar to ambient PM concentrations, which could be well in excess of the NationalAmbient Air Quality Standards, representing a major national public health threat. A mobile monitoring station was used in KwaDela, Mpumalanga to measure both ambient particulate concentrations and meteorological conditions, while a range of dust/particulate monitors were used for indoor and personal particulate concentration measurements. Indoor and personal measurements are limited to the respirable fraction (PM4) as this fraction contributes significantly to the negative health impacts. The sampling for this case study took place from 7-19 August 2014. Highest particulate matter concentrations were evident during the early mornings and the early evenings, when solid fuel burning activities were at their highest. Indoor and personal daily average PM4 concentrations did not exceed the 24h National Ambient PM2.5 Standard of 65 μg/m3 nor did they exceed the 24h National Ambient PM10 Standard of 75 μg/ m3. The outdoor PM2.5 concentrations were found to be below the standards for the duration of the sampling period. The outdoor PM10 concentrations exceeded the standards for one day during the sampling period. Results indicate that, although people in KwaDelamay be exposed to ambient PM concentrations that can be non-compliant to ambient standards, the exposure to indoor air, where solid fuel is burnt, may be detrimental to their health

Source apportionment of ambient PM10−2.5 and PM2.5 for the Vaal Triangle, South Africa

The Vaal Triangle Airshed Priority Area (VTAPA), like other priority areas in South Africa, has an air pollution problem. Understanding the sources contributing to air pollution in this priority area will assist in the selection and implementation of appropriate control strategies. For this study, aerosol samples in the coarse (PM10-2.5) and fine (PM2.5) fraction were collected at four sites in the VTAPA during summer/autumn, winter, and spring. The contributing sources were identified and characterised based on the elemental and ionic compositions obtained through X-ray fluorescence and ion chromatography analysis. The highest seasonal median concentrations of PM10-2.5 (116 μg/m3) and PM2.5 (88 μg/m3) were observed in Sharpeville during the winter. The lowest median concentrations of PM10-2.5 (25 μg/m3) and PM2.5 (18 μg/m3) were detected in Zamdela during the summer/autumn period. At all sites, there was a high abundance of crustal elements in PM10-2.5 and a dominance of coal and biomass combustion-related elements in PM2.5. The Positive Matrix Factorisation receptor model identified dust-related and secondary aerosols as the major contributing sources of PM10-2.5. PM2.5 contributions were predominantly from coal burning for Sebokeng and Sharpeville and from industry, wood and biomass burning, and secondary aerosols for Kliprivier and Zamdela. The results of this study identify the main sources contributing to particulate air pollution in the VTAPA and provide local authorities with valuable information for decision-making.Significance: Dust, industry, domestic coal burning, vehicles, and wood and biomass combustion are the key sources of particulate air pollution in the VTAPA that need to be prioritised by decision-makers. Although Sebokeng and Sharpeville are located within the vicinity of industries, domestic coal burning has a greater contribution to particulate loading at these sites. Results from this study will assist in the design of local municipality air quality management plans for the VTAPA

A perspective on South African coal fired power station emissions

This paper investigates trends of historical and projected future South African coal-fired power station criteria (total primary Particulate Matter (PM), Sulphur Dioxide (SO2) and Nitrogen Oxides (NOx)) and Carbon Dioxide (CO2) emissions. It was found that an energy restricted environment has an increasing effect on emissions, as emissions per energy unit increased from the onset of the South African energy crisis. PM emissions particularly, increased during the energy crisis period, due to increased pressure on PM abatement and lowered maintenance opportunity. Projections of future coal-fired power station criteria and CO2 emissions are made for four different future scenarios for the period 2015 to 2030. Three of the four scenarios are based on the lower projected energy demand baseline case as published in the updated Integrated Development Plan (IRP). The difference between these three scenarios is different retrofit rates of power stations with emissions abatement technologies. The fourth scenario is a worst case scenario and assumes high energy demand (and therefore no decommissioning of power stations), high emission rates (similar to worst past emission rates during the period 1999-2012) and no further abatement of emissions above and beyond current mitigation efforts. This scenario gives an indication of what South African coal-fired power station emissions could look like if the energy crisis persists. There is a marked difference between projected best and worst case PM emissions during the entire projected period, but especially during 2030 when worst case PM emissions compared to a 2015 baseline value are expected to rise by 40% and best case PM emissions are projected to decline by 40%. Worst case NOx emissions are expected to increase by 40% in 2030 from a 2015 baseline value whereas best case emissions are expected to decline 10% from the same level in 2030. Worst case SO2 emissions are predicted to increase by around 38% in 2030 and best case emissions are expected to decrease by around 20% in 2030 from a 2015 baseline value. Relative emissions used in the projection of future CO2 emissions in this paper differ from that used in the energy demand and energy mix modelling done for the updated IRP baseline case. The reason for this is that the modelling for the updated IRP assumed relative CO2 emission factors for supercritical boilers, whereas only Kusile and Medupi fall in this category and relative emissions from all other stations are, in fact, between 5% and 16% higher. For this reason, it seems unlikely that the South African climate commitment target for 2030 will be made