A Non-equilibrium STM model for Kondo Resonance on surface

Based on a no-equilibrium STM model, we study Kondo resonance on a surface by self-consistent calculations. The shapes of tunneling spectra are dependent on the energy range of tunneling electrons. Our results show that both energy-cutoff and energy-window of tunneling electrons have significant influence on the shapes of tunneling spectra. If no energy-cutoff is used, the Kondo resonances in tunneling spectrum are peaks with the same shapes in the density of state of absorbed magnetic atoms. This is just the prediction of Tersoff theory. If we use an energy cutoff to remove high-energy lectrons, a dip structure will modulate the Kondo resonance peak in the tunneling spectrum. The real shape of Kondo peak is the mixing of the peak and dip, the so-called Fano line shape. The method of self-consistent non-equilibrium matrix Green function is discussed in details.Comment: 11 pages and 8 eps figur

Accounting for changing temperature patterns increases historical estimates of climate sensitivity

Eight atmospheric general circulation models (AGCMs) are forced with observed historical (1871–2010) monthly sea surface temperature and sea ice variations using the Atmospheric Model Intercomparison Project II data set. The AGCMs therefore have a similar temperature pattern and trend to that of observed historical climate change. The AGCMs simulate a spread in climate feedback similar to that seen in coupled simulations of the response to CO2 quadrupling. However, the feedbacks are robustly more stabilizing and the effective climate sensitivity (EffCS) smaller. This is due to a pattern effect, whereby the pattern of observed historical sea surface temperature change gives rise to more negative cloud and longwave clear‐sky feedbacks. Assuming the patterns of long‐term temperature change simulated by models, and the radiative response to them, are credible; this implies that existing constraints on EffCS from historical energy budget variations give values that are too low and overly constrained, particularly at the upper end. For example, the pattern effect increases the long‐term Otto et al. (2013, https://doi.org/10.1038/ngeo1836) EffCS median and 5–95% confidence interval from 1.9 K (0.9–5.0 K) to 3.2 K (1.5–8.1 K

Vascular health in children and adolescents: effects of obesity and diabetes

The foundations for cardiovascular disease in adults are laid in childhood and accelerated by the presence of comorbid conditions, such as obesity, diabetes, hypertension, and dyslipidemia. Early detection of vascular dysfunction is an important clinical objective to identify those at risk for subsequent cardiovascular morbidity and events, and to initiate behavioral and medical interventions to reduce risk. Typically, cardiovascular screening is recommended for young adults, especially in people with a family history of cardiovascular conditions. Children and adolescents were once considered to be at low risk, but with the growing health concerns related to sedentary lifestyle, poor diet and obesity, cardiovascular screening may be needed earlier so that interventions to improve cardiovascular health can be initiated. This review describes comorbid conditions that increase cardiovascular risk in youth, namely obesity and diabetes, and describes noninvasive methods to objectively detect vascular disease and quantify vascular function and structure through measurements of endothelial function, arterial compliance, and intima-media thickness. Additionally, current strategies directed toward prevention of vascular disease in these populations, including exercise, dietary interventions and pharmacological therapy are described

The effect of electrolyte filling method on the performance of dye-sensitized solar cells

The effect of electrolyte filling method on the performance of the dye-sensitized solar cells is investigated with the segmented cell method, a recent technique which is very simple but effective as it can be used to examine all the photovoltaic characteristics. The electrolyte filling techniques compared were single injection, which is typically used in small laboratory cells, and pumping the electrolyte through the cell several times, which is often used for larger cells and modules. Significant photovoltage and photocurrent variations occur with the repeated pumping of the electrolyte in the cell preparation. Transient and charge extraction measurements confirmed that the differences in open circuit voltage were due to the shifts of the TiO2 conduction band and time correlated single photon counting confirmed that the reduction of short circuit current was largely due to reduced electron injection correlated with the increasing conduction band edge in the studied cases. This was interpreted as an effect of molecular filtering by the TiO2 causing an accumulation of electrolyte additives (4-tert-butylpyridine and benzimidazole) near the electrolyte filling hole, the concentration of which increased with repeated pumping of the electrolyte. Interestingly, spatial variations were seen not only in the relative TiO2 conduction band energy but also in the density of trap states. In this contribution it is demonstrated how the changes in the conduction band can be separated from the changes in the density of trap states which is an essential for the correct interpretation of the data.Peer reviewe

Implications of different nitrogen input sources for potential production and carbon flux estimates in the coastal Gulf of Mexico (GOM) and Korean Peninsula coastal waters

The coastal Gulf of Mexico (GOM) and coastal sea off the Korean Peninsula (CSK) both suffer from human-induced eutrophication. We used a nitrogen (N) mass balance model in two different regions with different nitrogen input sources to estimate organic carbon fluxes and predict future carbon fluxes under different model scenarios. The coastal GOM receives nitrogen predominantly from the Mississippi and Atchafalaya rivers and atmospheric nitrogen deposition is only a minor component in this region. In the CSK, groundwater and atmospheric nitrogen deposition are more important controlling factors. Our model includes the fluxes of nitrogen to the ocean from the atmosphere, groundwater and rivers, based on observational and literature data, and identifies three zones (brown, green and blue waters) in the coastal GOM and CSK with different productivity and carbon fluxes. Based on our model results, the potential primary production rate in the inner (brown water) zone are over 2 gC m−2 d−1 (GOM) and 1.5 gC m−2 d−1 (CSK). In the middle (green water) zone, potential production is from 0.1 to 2 (GOM) and 0.3 to 1.5 gC m−2 d−1 (CSK). In the offshore (blue water) zone, productivity is less than 0.1 (GOM) and 0.3 (CSK) gC m−2 d−1. Through our model scenario results, overall oxygen demand in the GOM will increase approximately 21 % if we fail to reduce riverine N input, likely increasing considerably the area affected by hypoxia. Comparing the results from the USA with those from the Korean Peninsula shows the importance of considering both riverine and atmospheric inputs of nitrogen. This has direct implications for investigating how changes in energy technologies can lead to changes in the production of various atmospheric contaminants that affect air quality, climate and the health of local populations

Investigations of excitation energy transfer and intramolecular interactions in a nitrogen corded distrylbenzene dendrimer system.

The photophysics of an amino-styrylbenzene dendrimer (A-DSB) system is probed by time-resolved and steady state luminescence spectroscopy. For two different generations of this dendrimer, steady state absorption, emission, and photoluminescence excitation spectra are reported and show that the efficiency of energy transfer from the dendrons to the core is very close to 100%. Ultrafast time-resolved fluorescence measurements at a range of excitation and detection wavelengths suggest rapid (and hence efficient) energy transfer from the dendron to the core. Ultrafast fluorescence anisotropy decay for different dendrimer generations is described in order to probe the energy migration processes. A femtosecond time-scale fluorescence depolarization was observed with the zero and second generation dendrimers. Energy transfer process from the dendrons to the core can be described by a Förster mechanism (hopping dynamics) while the interbranch interaction in A-DSB core was found to be very strong indicating the crossover to exciton dynamics

Emergent Potts Order in a Coupled Hexatic-Nematic XY model

Addressing the nature of an unexpected smectic-A' phase in liquid crystal 54COOBC films, we perform large scale Monte Carlo simulations of a coupled hexatic-nematic XY model. The resulting finite-temperature phase diagram reveals a small region with composite Potts $\mathbb{Z}_3$ order above the vortex binding transition; this phase is characterized by relative hexatic-nematic ordering though both variables are disordered. The system develops algebraic hexatic and nematic order only at a lower temperature. This multi-step melting scenario agrees well with the experimental observations of a sharp specific heat anomaly that emerges above the onset of hexatic positional order. We therefore propose that the smectic-A' phase is characterized by composite Potts order and bound-states of fractional vortices.Comment: 22 pages, 10 figures, 1 tabl

Barrett’s esophagus registries

The following on Barrett's esophagus registries contains commentaries on the data sets to be included, organizational issues, and the demographic, lifestyle, and diagnostic differences between the United States and Europe. The importance of collaborative studies is also discussed

Summertime Nutrient Supply to Near-Surface Waters of the Northeastern Gulf of Mexico: 1998, 1999, and 2000

In the summers of 1998, 1999, and 2000, deep water eddies induced strong anticyclonic currents along the upper slope and outer shelf from the Mississippi River delta to the west Florida shelf. Those currents transported Mississippi River discharge eastward along the outer shelf and slope, reversing the normal offshore increase in salinity, with the exception of a few regions very near the coast that were influenced by the discharges from other rivers or bays. The entrainment of low-salinity river water resulted in anomalously high chlorophyll a concentrations in the upper 15 m over the outer shelf and upper slope, in contrast to the concentrations that typically occur over deep water in the subtropics in summer. Nitrate concentrations in this surface water were quite low except near the mouths of rivers, which act as point sources for nutrients; presumably, this was because of the rapid utilization of nitrate by phytoplankton. A significant supply of nutrients to the euphotic zone at regions quite removed from these point sources resulted from eddies intruding onto or formed over the slope. These caused mid-depth water rich in nutrients to be uplifted to within the euphotic zone, the uplift depending on the location and intensity of the eddies. Based on measurements at approximately 100 stations on each cruise, estimates were made of the quantity of nitrate and silicate in the upper 15 m of the water column and in the depth interval from 15m to 60 m, the nominal depth of the euphotic zone. Study results suggest that the nitrate and silicate in the near-surface interval of 0-15 m largely resulted from riverine discharge and subsequent advection, while the nutrients between 15 and 60 m resulted from uplift of waters by circulation features. The euphotic zone occupied at least the upper 60 m of the water column, but standing stocks of nitrate and silicate in the 15- to 60-m layer were between two and six times those in the upper 15 m on all three cruises and appeared to depend on the strength and relative proximity to the shelf break of local anticyclonic features. The effects of these circulation features were potentially significant in supplying nutrients to the euphotic zone during these summers