5,855 research outputs found
Vibrational Modes in LiBC: Theory Compared with Experiment
The search for other superconductors in the MgB2 class currently is focussed
on Li{1-x}BC, which when hole-doped (concentration x) should be a metal with
the potential to be a better superconductor than MgB2. Here we present the
calculated phonon spectrum of the parent semiconductor LiBC. The calculated
Raman-active modes are in excellent agreement with a recent observation, and
comparison of calculated IR-active modes with a recent report provides a
prediction of the LO--TO splitting for these four modes, which is small for the
B-C bond stretching mode at ~1200 cm^{-1}, but large for clearly resolved modes
at 540 cm^{-1} and 620 cm^{-1}.Comment: 4 pages, two embedded figures. Physica B (in press
Half metallic digital ferromagnetic heterostructure composed of a -doped layer of Mn in Si
We propose and investigate the properties of a digital ferromagnetic
heterostructure (DFH) consisting of a -doped layer of Mn in Si, using
\textit{ab initio} electronic-structure methods. We find that (i) ferromagnetic
order of the Mn layer is energetically favorable relative to antiferromagnetic,
and (ii) the heterostructure is a two-dimensional half metallic system. The
metallic behavior is contributed by three majority-spin bands originating from
hybridized Mn- and nearest-neighbor Si- states, and the corresponding
carriers are responsible for the ferromagnetic order in the Mn layer. The
minority-spin channel has a calculated semiconducting gap of 0.25 eV. Analysis
of the total and partial densities of states, band structure, Fermi surfaces
and associated charge density reveals the marked two-dimensional nature of the
half metallicity. The band lineup is found to be favorable for retaining the
half metal character to near the Curie temperature (). Being Si based
and possibly having a high as suggested by an experiment on dilutely
doped Mn in Si, the heterostructure may be of special interest for integration
into mature Si technologies for spintronic applications.Comment: 4 pages, 4 figures, Revised version, to appear in Phys. Rev. Let
Origin of Superconductivity in Boron-doped Diamond
Superconductivity of boron-doped diamond, reported recently at T_c=4 K, is
investigated exploiting its electronic and vibrational analogies to MgB2. The
deformation potential of the hole states arising from the C-C bond stretch mode
is 60% larger than the corresponding quantity in MgB2 that drives its high Tc,
leading to very large electron-phonon matrix elements. The calculated coupling
strength \lambda ~ 0.5 leads to T_c in the 5-10 K range and makes phonon
coupling the likely mechanism. Higher doping should increase T_c somewhat, but
effects of three dimensionality primarily on the density of states keep doped
diamond from having a T_c closer to that of MgB2.Comment: Four pages with two embedded figures, corrected fig1. (To appear in
Physical Review Letters(2004)
Pest-predator spatial relationships in winter rape: implications for integrated crop management
Douglas Warner, Les J Allen-Williams, Andrew W Ferguson, and Ingrid H Williams, 'Pest–predator spatial relationships in winter rape: implications for integrated crop management', Pest Management Science, Vol. 56 (11): 977-982, November 2000, doi: 10.1002/1526-4998(200011)56:113.0.CO;2-U. Copyright © 2000 Society of Chemical IndustryThe brassica pod midge (Dasineura brassicae) is an important and widespread pest of winter and spring oilseed rape throughout Europe. Pods infested by D brassicae larvae split prematurely, releasing seeds, and the larvae drop to the soil into which they burrow to pupate. At this stage in its lifecycle D brassicae is potentially vulnerable to predation by carabid beetles foraging on the soil surface. This is the first study in the UK to focus on carabid beetles as predators of D brassicae in the oilseed rape crop. The spatio-temporal distributions of larvae of D brassicae dropping to the soil from the crop canopy and of adult carabid beetles active on the soil surface were analysed in two consecutive years. Insect samples were collected from spatially referenced sampling points across each crop. Counts of insects were mapped and analysed, and the degree of spatial association between predator and prey determined using Spatial Analysis by Distance Indices (SADIE). Carabid species abundant and active during peak drop of first generation D brassicae larvae included Agonum dorsale, Amara similata, Harpalus rufipes and Nebria brevicollis. The larvae of D brassicae had a marked edge distribution within the crop. SADIE analysis revealed significant spatial association between larvae of D brassicae and adult H rufipes (P <0.05) in 1998, but not with adults of A dorsale, A similata or N brevicollis. In 1999, there was strong spatial association only between larvae of D brassicae and adult A dorsale (P <0.01). Aggregation of N brevicollis adults occurred in some areas of greatest D brassicae larval counts in 1999, but overall spatial association was not signi®cant. The distributions are discussed in terms of their relevance to integrated crop management (ICM) strategies and spatial targeting of insecticides.Peer reviewe
Submillimeter-Wave Measurements and Analysis of the Ground and ν2 = 1 States of Water
In order to facilitate further studies of water in the interstellar medium, the envelopes of late-type stars, jets, and shocked regions, the frequencies of 17 newly measured H_2 ^(16)O transitions between 0.841 and 1.575 THz are reported. A complete update of the available water line frequencies and a detailed calculation of unmeasured rotational transitions and transition intensities as a function of temperature are presented for the ground and ν_2 = 1 state levels below 3000 cm^(-1) of excitation energy. The new terahertz transitions were measured with a recently developed laser difference frequency spectrometer. Six of these transitions arise from the ν_2 = 1 state, and the other 11 are in the ground state; all have lower state energies from 700 to 1750 cm^(-1) and should be accessible to Stratospheric Observatory For Infrared Astronomy (SOFIA) through the atmosphere. The transitions near 0.850 THz are accessible from the ground with existing receivers. Observations of the newly measured ν_2 = 1 state transitions, which include the 1_(1, 1)-0_(0, 0) fundamental at 1.2057 THz and five other very low J transitions, should provide valuable insights into role played by the ν2 = 1 state in the cooling dynamics of jets, shocks, masers, and strongly infrared-pumped regions. The line list is presented to assist in the planning of observational campaigns with the Far-Infrared Space Telescope (FIRST) and other proposed space missions with which a full suite of water observations can be carried out
A High Power Frequency-Stabilized Tunable Two-Frequency Diode Laser System for the Generation of Coherent THz-Waves by Photomixing
A tunable two-frequency high-power diode laser system at 850 nm for terahertz (Thz)-wave generation by photomixing in low-temperature-grown GaAs photo-conductors has been developed. The difference frequency is obtained through a three laser system, where two lasers are locked to different orders of a Fabry-Perot cavity and a third is offset-locked to the first, The difference-frequency signal is generated by the offset laser and the other cavity-locked laser. The spectral purity of the beat note is better than 1 MHz. The maximum output power of -500 mW was obtained by using the master oscillator power amplifier (MOPA) technique, simultaneous injection of two seed frequencies with a single semiconductor optical amplifier. Here we report the generation of THz waves and spectroscopy of acetonitrile as proof of concept
Linear bands, zero-momentum Weyl semimetal, and topological transition in skutterudite-structure pnictides
It was reported earlier [Phys. Rev. Lett. 106, 056401 (2011)] that the
skutterudite structure compound CoSb displays a unique band structure with
a topological transition versus a symmetry-preserving sublattice (Sb)
displacement very near the structural ground state. The transition is through a
massless Dirac-Weyl semimetal, point Fermi surface phase which is unique in
that (1) it appears in a three dimensional crystal, (2) the band critical point
occurs at =0, and (3) linear bands are degenerate with conventional
(massive) bands at the critical point (before inclusion of spin-orbit
coupling). Further interest arises because the critical point separates a
conventional (trivial) phase from a topological phase. In the native cubic
structure this is a zero-gap topological semimetal; we show how spin-orbit
coupling and uniaxial strain converts the system to a topological insulator
(TI). We also analyze the origin of the linear band in this class of materials,
which is the characteristic that makes them potentially useful in
thermoelectric applications or possibly as transparent conductors. We
characterize the formal charge as Co , consistent with the gap, with
its site symmetry, and with its lack of moment. The Sb states are
characterized as (separately, ) -bonded ring states
occupied and the corresponding antibonding states empty. The remaining
(locally) orbitals form molecular orbitals with definite parity centered
on the empty site in the skutterudite structure. Eight such orbitals must
be occupied; the one giving the linear band is an odd orbital singlet
at the zone center. We observe that the provocative linearity of the band
within the gap is a consequence of the aforementioned near-degeneracy, which is
also responsible for the small band gap.Comment: 10 pages, 7 figure
Prediction Model for the Life of Nickel-cadmium Batteries in Geosynchronous Orbit Satellites
A mathematical model is described which predicts the service life of nickel-cadmium batteries designed for geosynchronous orbit satellites. Regression analysis technique is used to analyze orbital data on second generation trickle charged batteries. The model gives average cell voltage as a function of design parameters, operating parameters and time. The voltage model has the properties of providing a good fit to the data, good predictive capability, and agreement with known battery performance characteristics. Average cell voltage can be predicted to within 0.02 volts for up to 8 years. This modeling shows that these batteries will operate reliably for 10 years. Third-generation batteries are expected to operate even longer
Laboratory measurements and theoretical calculations of O_2 A band electric quadrupole transitions
Frequency-stabilized cavity ring-down spectroscopy was utilized to measure electric quadrupole transitions within the ^(16)O_2 A band, b^1Σ^+_g ← X^3Σ^-_g(0,0). We report quantitative measurements (relative uncertainties in intensity measurements from 4.4% to 11%) of nine ultraweak transitions in the ^NO, ^PO, ^RS, and ^TS branches with line intensities ranging from 3×10^(−30) to 2×10^(−29) cm molec.^(−1). A thorough discussion of relevant noise sources and uncertainties in this experiment and other cw-cavity ring-down spectrometers is given. For short-term averaging (t<100 s), we estimate a noise-equivalent absorption of 2.5×10^(−10) cm^(−1) Hz^(−1/2). The detection limit was reduced further by co-adding up to 100 spectra to yield a minimum detectable absorption coefficient equal to 1.8×10^(−11) cm^(−1), corresponding to a line intensity of ~2.5×10^(−31) cm molec.^(−1). We discuss calculations of electric quadrupole line positions based on a simultaneous fit of the ground and upper electronic state energies which have uncertainties <3 MHz, and we present calculations of electric quadrupole matrix elements and line intensities. The electric quadrupole line intensity calculations and measurements agreed on average to 5%, which is comparable to our average experimental uncertainty. The calculated electric quadrupole band intensity was 1.8(1)×10^(−27) cm molec.−1 which is equal to only ~8×10^(−6) of the magnetic dipole band intensity
The NASA integrated test facility and its impact on flight research
The Integrated Test Facility (ITF), being built at NASA Ames-Dryden Flight Research Facility, will provide new test capabilities for emerging research aircraft. An overview of the ITF and the challenges being addressed by this unique facility are outlined. The current ITF capabilities, being developed with the X-29 Forward Swept Wing Program, are discussed along with future ITF activities
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