4,787 research outputs found
In-situ cross linking of polyvinyl alcohol
A method of producing a crosslinked polyvinyl alcohol structure, such as a battery separator membrane or electrode envelope is described. An aqueous solution of a film-forming polyvinyl alcohol is admixed with an aldehyde crosslinking agent a basic pH to inhibit crosslinking. The crosslinking agent, perferably a dialdehyde such as glutaraldehyde, is used in an amount of from about 1/2 to about 20% of the theoretical amount required to crosslink all of the hydroxyl groups of the polymer. The aqueous admixture is formed into a desired physical shape, such as by casting a sheet of the solution. The sheet is then dried to form a self-supporting film. Crosslinking is then effected by immersing the film in aqueous acid solution. The resultant product has excellent properties for use as a battery separator
In situ self cross-linking of polyvinyl alcohol battery separators
A battery separator was produced from a polyvinyl alcohol sheet structure which was subjected to an in situ, self crosslinking process by selective oxidation of the 1,2 diol units present in the polyvinyl alcohol sheet structure. The 1,2 diol units were cleaved to form aldehyde end groups which subsequently crosslink through acetalization of the 1,3 diol units of the polyvinyl alcohol. Selective oxidation was achieved using a solution of a suitable oxidizing agent such as periodic acid or lead tetraacetate
Cross-linked polyvinyl alcohol and method of making same
A film-forming polyvinyl alcohol polymer is mixed with a polyaldehyde-polysaccharide cross-linking agent having at least two monosaccharide units and a plurality of aldehyde groups per molecule, perferably an average of at least one aldehyde group per monosaccharide units. The cross-linking agent, such as a polydialdehyde starch, is used in an amount of about 2.5 to 20% of the theoretical amount required to cross-link all of the available hydroxyl groups of the polyvinyl alcohol polymer. Reaction between the polymer and cross-linking agent is effected in aqueous acidic solution to produce the cross-linked polymer. The polymer product has low electrical resistivity and other properties rendering it suitable for making separators for alkaline batteries
Alkaline battery containing a separator of a cross-linked copolymer of vinyl alcohol and unsaturated carboxylic acid
A battery separator for an alkaline battery is described. The separator comprises a cross linked copolymer of vinyl alcohol units and unsaturated carboxylic acid units. The cross linked copolymer is insoluble in water, has excellent zincate diffusion and oxygen gas barrier properties and a low electrical resistivity. Cross linking with a polyaldehyde cross linking agent is preferred
Multistep greedy algorithm identifies community structure in real-world and computer-generated networks
We have recently introduced a multistep extension of the greedy algorithm for
modularity optimization. The extension is based on the idea that merging l
pairs of communities (l>1) at each iteration prevents premature condensation
into few large communities. Here, an empirical formula is presented for the
choice of the step width l that generates partitions with (close to) optimal
modularity for 17 real-world and 1100 computer-generated networks. Furthermore,
an in-depth analysis of the communities of two real-world networks (the
metabolic network of the bacterium E. coli and the graph of coappearing words
in the titles of papers coauthored by Martin Karplus) provides evidence that
the partition obtained by the multistep greedy algorithm is superior to the one
generated by the original greedy algorithm not only with respect to modularity
but also according to objective criteria. In other words, the multistep
extension of the greedy algorithm reduces the danger of getting trapped in
local optima of modularity and generates more reasonable partitions.Comment: 17 pages, 2 figure
Nature of Ar bonding to small Co_n^+ clusters and its effect on the structure determination by far-infrared absorption spectroscopy
Far-infrared vibrational spectroscopy by multiple photon dissociation has
proven to be a very useful technique for the structural fingerprinting of small
metal clusters. Contrary to previous studies on cationic V, Nb and Ta clusters,
measured vibrational spectra of small cationic cobalt clusters show a strong
dependence on the number of adsorbed Ar probe atoms, which increases with
decreasing cluster size. Focusing on the series Co_4^+ to Co_8^+ we therefore
use density-functional theory to analyze the nature of the Ar-Co_n^+ bond and
its role for the vibrational spectra. In a first step, energetically low-lying
isomer structures are identified through first-principles basin-hopping
sampling runs and their vibrational spectra computed for a varying number of
adsorbed Ar atoms. A comparison of these fingerprints with the experimental
data enables in some cases a unique assignment of the cluster structure.
Independent of the specific low-lying isomer, we obtain a pronounced increase
of the Ar binding energy for the smallest cluster sizes, which correlates
nicely with the observed increased influence of the Ar probe atoms on the IR
spectra. Further analysis of the electronic structure motivates a simple
electrostatic picture that not only explains this binding energy trend, but
also why the influence of the rare-gas atom is much stronger than in the
previously studied systems.Comment: 12 pages including 10 figures; related publications can be found at
http://www.fhi-berlin.mpg.de/th/th.htm
Resonant coupling of a Bose-Einstein condensate to a micromechanical oscillator
We report experiments in which the vibrations of a micromechanical oscillator
are coupled to the motion of Bose-condensed atoms in a trap. The interaction
relies on surface forces experienced by the atoms at about one micrometer
distance from the mechanical structure. We observe resonant coupling to several
well-resolved mechanical modes of the condensate. Coupling via surface forces
does not require magnets, electrodes, or mirrors on the oscillator and could
thus be employed to couple atoms to molecular-scale oscillators such as carbon
nanotubes.Comment: 9 pages, 4 figure
Resonant Auger decay of the core-excited CO molecule in intense X-ray laser fields
The dynamics of the resonant Auger (RA) process of the core-excited
CO(1s) molecule in an intense X-ray laser field is
studied theoretically. The theoretical approach includes the analogue of the
conical intersections of the complex potential energy surfaces of the ground
and `dressed' resonant states due to intense X-ray pulses, taking into account
the decay of the resonance and the direct photoionization of the ground state,
both populating the same final ionic states coherently, as well as the direct
photoionization of the resonance state itself. The light-induced non-adiabatic
effect of the analogue of the conical intersections of the resulting complex
potential energy surfaces gives rise to strong coupling between the electronic,
vibrational and rotational degrees of freedom of the diatomic CO molecule. The
interplay of the direct photoionization of the ground state and of the decay of
the resonance increases dramatically with the field intensity. The coherent
population of a final ionic state via both the direct photoionization and the
resonant Auger decay channels induces strong interference effects with distinct
patterns in the RA electron spectra. The individual impact of these physical
processes on the total electron yield and on the CO electron
spectrum are demonstrated.Comment: 13 figs, 1 tabe
An evaluation of Bradfordizing effects
The purpose of this paper is to apply and evaluate the bibliometric method Bradfordizing for information retrieval (IR) experiments. Bradfordizing is used for generating core document sets for subject-specific questions and to reorder result sets from distributed searches. The method will be applied and tested in a controlled scenario of scientific literature databases from social and political sciences, economics, psychology and medical science (SOLIS, SoLit, USB Köln Opac, CSA Sociological Abstracts, World Affairs Online, Psyndex and Medline) and 164 standardized topics. An evaluation of the method and its effects is carried out in two laboratory-based information retrieval experiments (CLEF and KoMoHe) using a controlled document corpus and human relevance assessments. The results show that Bradfordizing is a very robust method for re-ranking the main document types (journal articles and monographs) in today’s digital libraries (DL). The IR tests show that relevance distributions after re-ranking improve at a significant level if articles in the core are compared with articles in the succeeding zones. The items in the core are significantly more often assessed as relevant, than items in zone 2 (z2) or zone 3 (z3). The improvements between the zones are statistically significant based on the Wilcoxon signed-rank test and the paired T-Test
Internal Friction and Vulnerability of Mixed Alkali Glasses
Based on a hopping model we show how the mixed alkali effect in glasses can
be understood if only a small fraction c_V ofthe available sites for the mobile
ions is vacant. In particular, we reproduce the peculiar behavior of the
internal friction and the steep fall (''vulnerability'') of the mobility of the
majority ion upon small replacements by the minority ion. The single and mixed
alkali internal friction peaks are caused by ion-vacancy and ion-ion exchange
processes. If c_V is small, they can become comparable in height even at small
mixing ratios. The large vulnerability is explained by a trapping of vacancies
induced by the minority ions. Reasonable choices of model parameters yield
typical behaviors found in experiments.Comment: 4 pages, 4 figure
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