Physisorption of positronium on quartz surfaces

The possibility of having positronium (Ps) physisorbed at a material surface is of great fundamental interest, since it can lead to new insight regarding quantum sticking and is a necessary first step to try to obtain a Ps$_2$ molecule on a material host. Some experiments in the past have produced evidence for physisorbed Ps on a quartz surface, but firm theoretical support for such a conclusion was lacking. We present a first-principles density-functional calculation of the key parameters determining the interaction potential between Ps and an $\alpha$-quartz surface. We show that there is indeed a bound state with an energy of 0.14 eV, a value which agrees very well with the experimental estimate of $\sim0.15$ eV. Further, a brief energy analysis invoking the Langmuir-Hinshelwood mechanism for the reaction of physisorbed atoms shows that the formation and desorption of a Ps$_2$ molecule in that picture is consistent with the above results.Comment: 5 pages, 3 figures, submitte

Electron beam chemistry produces high purity metals

Application of radiation chemistry for deposition of metals by irradiation of aqueous solutions with high energy electrons is presented. Design of reaction vessel for irradiation of solution is illustrated. Features of radiochemical technique and procedures followed are described

New type of ellipsometry in infrared spectroscopy: The double-reference method

We have developed a conceptually new type of ellipsometry which allows the determination of the complex refractive index by simultaneously measuring the unpolarized normal-incidence reflectivity relative to the vacuum and to another reference media. From these two quantities the complex optical response can be directly obtained without Kramers-Kronig transformation. Due to its transparency and large refractive index over a broad range of the spectrum, from the far-infrared to the soft ultraviolet region, diamond can be ideally used as a second reference. The experimental arrangement is rather simple compared to other ellipsometric techniques.Comment: submitted to Appl. Phys. Let

Laser microscopy of tunneling magnetoresistance in manganite grain-boundary junctions

Using low-temperature scanning laser microscopy we directly image electric transport in a magnetoresistive element, a manganite thin film intersected by a grain boundary (GB). Imaging at variable temperature allows reconstruction and comparison of the local resistance vs temperature for both, the manganite film and the GB. Imaging at low temperature also shows that the GB switches between different resistive states due to the formation and growth of magnetic domains along the GB. We observe different types of domain wall growth; in most cases a domain wall nucleates at one edge of the bridge and then proceeds towards the other edge.Comment: 5 pages, 4 figures; submitted to Phys. Rev. Let

Use of radiation in preparative chemistry

A summary and updating of previous work on the use of radiation chemistry for the preparation of pure materials are presented. Work was chiefly concerned with the reduction of metal salts in solution to the free metal using 2 MeV electrons. Metals deposited from aqueous solution are copper, silver, zinc, cadmium, thallium, tin, lead, antimony, iron, nickel, cobalt, and palladium. Dry organic solvents were evaluated for the deposition of metals based on a study involving deposition of antimony from soltions of antimony (III) chloride. The use of organic liquids for the preparation of anhydrous metal halides is also presented. Reaction mechanisms for both organic liquids and aqueous system are discussed

Physical Properties and Baryonic Content of Low-Redshift Intergalactic Ly-alpha and O VI Absorption Systems: The PG1116+215 Sight Line

We present HST and FUSE observations of the intergalactic absorption toward PG1116+215 in the 900-3000 A spectral region. We detect 25 Ly-alpha absorbers at rest-frame equivalent widths W_r > 30 mA, yielding (dN/dz)_Ly-alpha = 154+/-18 over an unblocked redshift path of 0.162. Two additional weak Ly-alpha absorbers with W_r ~ 15-20 mA are also present. Eight of the Ly-alpha absorbers have large line widths (b > 40 km/sec). The detection of narrow OVI in the broad Ly-alpha absorber at z=0.06244 supports the idea that the Ly-alpha profile is thermally broadened in gas with T > 10^5 K. We find dN/dz ~ 50 for broad Ly-alpha absorbers with W_r > 30 mA and b > 40 km/sec. If the broad Ly-alpha lines are dominated by thermal broadening in hot gas, the amount of baryonic material in these absorbers is enormous, perhaps as much as half the baryonic mass in the low-redshift universe. We detect OVI absorption in several of the Ly-alpha clouds along the sight line. Two detections at z=0.13847 and z=0.16548 are confirmed by the presence of other ions at these redshifts, while the detections at z=0.04125, 0.05895, 0.05928, and 0.06244 are based upon the Ly-alpha and OVI detections alone. The information available for 13 low-redshift OVI absorbers with W_r > 50 mA along 5 sight lines yields (dN/dz)_OVI ~ 14 and Omega_b(OVI) > 0.0027/h_75, assuming a metallicity of 0.1 solar and an OVI ionization fraction < 0.2. The properties and prevalence of low-redshift OVI absorbers suggest that they too may be a substantial baryon repository, perhaps containing as much mass as stars and gas inside galaxies. The redshifts of the OVI absorbers are highly correlated with the redshifts of galaxies along the sight line, though few of the absorbers lie closer than 600/h_75 kpc to any single galaxy. [abbreviated]Comment: 99 pages, 30 figures, aastex format, ApJS in pres

Reliability assessment and criticality analysis for Wave Energy Converters

This paper applies existing reliability methods, namely Reliability Block diagrams, to a notional wave energy converter configuration. It shows possible source of information and difficulties associated with an omnipresent lack of failure rate data.The reliability of wave energy converters (WECs) is a key issue that has to be addressed in order to make them a viable energy option. At this stage of early industrial development the reliability assessment of WECs is a challenging task. In this paper existing reliability methods, namely Reliability Block diagrams, have been applied to a notional configuration. It was found that omnipresent lack of failure rate data makes rather crude adjustments of often generic data necessary which generally lead to rather unfavourable and highly uncertain results. Reliability data is either not available due to sparse field experience or is kept confidential, within different project developments to secure competitive advantages and intellectual property. In order to foster the progress of the marine energy industry, the reliability of devices must be demonstrated and improved. This requires a joint effort between industry stakeholders to collect, share and disseminate existing failure knowledge and future operational experience.Engineering and Physical Sciences Research Council (EPSRC) under the SUPERGEN Marine Doctoral Programm

Testing spontaneous localization theories with matter-wave interferometry

We propose to test the theory of continuous spontaneous localization (CSL) in an all-optical time-domain Talbot-Lau interferometer for clusters with masses exceeding 1000000 amu. By assessing the relevant environmental decoherence mechanisms, as well as the growing size of the particles relative to the grating fringes, we argue that it will be feasible to test the quantum superposition principle in a mass range excluded by recent estimates of the CSL effect.Comment: 4 pages, 3 figures; corresponds to published versio

Is it a showstopper? Reliability assessment and criticality analysis for Wave Energy Converters

The reliability of wave energy converters (WECs) is a key issue that has to be addressed in order to make them a viable energy option. At this stage of early industrial development the reliability assessment of WECs is a challenging task. In this paper existing reliability methods, namely Reliability Block diagrams, have been applied to a notional configuration. It was found that omnipresent lack of failure rate data makes rather crude adjustments of often generic data necessary which generally lead to rather unfavourable and highly uncertain results. Reliability data is either not available due to sparse field experience or is kept confidential, within different project developments to secure competitive advantages and intellectual property. In order to foster the progress of the marine energy industry, the reliability of devices must be demonstrated and improved. This requires a joint effort between industry stakeholders to collect, share and disseminate existing failure knowledge and future operational experience