27 research outputs found
Spin-flip and spin-conserving optical transitions of the nitrogen-vacancy centre in diamond
We map out the first excited state sublevel structure of single nitrogen-vacancy (NV) colour centres in diamond. The excited state is an orbital doublet where one branch supports an efficient cycling transition, while the other can simultaneously support fully allowed optical Raman spin-flip transitions. This is crucial for the success of many recently proposed quantum information applications of the NV defects. We further find that an external electric field can be used to completely control the optical properties of a single centre. Finally, a group theoretical model is developed that explains the observations and provides good physical understanding of the excited state structure
Driving current through single organic molecules
We investigate electronic transport through two types of conjugated
molecules. Mechanically controlled break-junctions are used to couple thiol
endgroups of single molecules to two gold electrodes. Current-voltage
characteristics (IVs) of the metal-molecule-metal system are observed. These
IVs reproduce the spatial symmetry of the molecules with respect to the
direction of current flow. We hereby unambigously detect an intrinsic property
of the molecule, and are able to distinguish the influence of both the molecule
and the contact to the metal electrodes on the transport properties of the
compound system.Comment: 4 pages, 5 figure
Single photon quantum non-demolition in the presence of inhomogeneous broadening
Electromagnetically induced transparency (EIT) has been often proposed for
generating nonlinear optical effects at the single photon level; in particular,
as a means to effect a quantum non-demolition measurement of a single photon
field. Previous treatments have usually considered homogeneously broadened
samples, but realisations in any medium will have to contend with inhomogeneous
broadening. Here we reappraise an earlier scheme [Munro \textit{et al.} Phys.
Rev. A \textbf{71}, 033819 (2005)] with respect to inhomogeneities and show an
alternative mode of operation that is preferred in an inhomogeneous
environment. We further show the implications of these results on a potential
implementation in diamond containing nitrogen-vacancy colour centres. Our
modelling shows that single mode waveguide structures of length in single-crystal diamond containing a dilute ensemble of NV
of only 200 centres are sufficient for quantum non-demolition measurements
using EIT-based weak nonlinear interactions.Comment: 21 pages, 9 figures (some in colour) at low resolution for arXiv
purpose
Franck-Condon Effect in Central Spin System
We study the quantum transitions of a central spin surrounded by a
collective-spin environment. It is found that the influence of the
environmental spins on the absorption spectrum of the central spin can be
explained with the analog of the Franck-Condon (FC) effect in conventional
electron-phonon interaction system. Here, the collective spins of the
environment behave as the vibrational mode, which makes the electron to be
transitioned mainly with the so-called "vertical transitions" in the
conventional FC effect. The "vertical transition" for the central spin in the
spin environment manifests as, the certain collective spin states of the
environment is favored, which corresponds to the minimal change in the average
of the total spin angular momentum.Comment: 8 pages, 8 figure
Laser-induced resonance shifts of single molecules self-coupled by a metallic surface
The spectral properties of single molecules placed near a metallic surface are investigated at low temperatures. Because of the high quality factor of the optical resonance, a laser-induced shift of the molecular lines is evidenced for the first time. The shift dependence on the laser excitation intensity and on the dephasing rate of the transition dipole is studied. A simple theoretical model of a laser-driven molecule self-coupled by a mirror is developed to qualitatively interpret the observations.Peer reviewedPhysic
Quantum phase transitions of light
Recently, condensed matter and atomic experiments have reached a length-scale
and temperature regime where new quantum collective phenomena emerge. Finding
such physics in systems of photons, however, is problematic, as photons
typically do not interact with each other and can be created or destroyed at
will. Here, we introduce a physical system of photons that exhibits strongly
correlated dynamics on a meso-scale. By adding photons to a two-dimensional
array of coupled optical cavities each containing a single two-level atom in
the photon-blockade regime, we form dressed states, or polaritons, that are
both long-lived and strongly interacting. Our zero temperature results predict
that this photonic system will undergo a characteristic Mott insulator
(excitations localised on each site) to superfluid (excitations delocalised
across the lattice) quantum phase transition. Each cavity's impressive photon
out-coupling potential may lead to actual devices based on these quantum
many-body effects, as well as observable, tunable quantum simulators. We
explicitly show that such phenomena may be observable in micro-machined diamond
containing nitrogen-vacancy colour centres and superconducting microwave
strip-line resonators.Comment: 11 pages, 5 figures (2 in colour
Efficient generation of near infra-red single photons from the zero-phonon line of a single molecule
Using the zero-phonon line (ZPL) emission of a single molecule, we realized a triggered source of near-infra-red (λ=785 nm) single photons at a high repetition rate. A Weierstrass solid immersion lens is used to image single molecules with an optical resolution of 300 nm (~0.4λ) and a high collection efficiency. Because dephasing of the transition dipole due to phonons vanishes at liquid helium temperatures, our source is attractive for the efficient generation of single indistinguishable photons