Brief Amicus Curiae of Shell Petroleum N.V.

https://digitalcommons.nyls.edu/sumitomo_briefs/1017/thumbnail.jp

Sorrows of a Saloon-Keeper

Narrative moral satire on the evils of alcohol and drinking.https://place.asburyseminary.edu/ecommonsatsdigitalresources/1185/thumbnail.jp

R.J.W. Douglas Medal Award: Dr. Raymond Thorsteinsson

Dr. Raymond Thorsteinsson, Fellow of The Arctic Institute of North America, was awarded the R.J.W. Douglas Medal (1982) for his many contributions to Canadian geology and in particular the geology of the High Arctic. ... He began a lifelong career with the GSC in 1952. Most of the subsequent years were spent on arctic studies. Initially, his field work was done on foot and by dogteam, but soon he pioneered the use of small aircraft, equipped with oversize tires, which could be landed virtually anywhere on the Arctic Islands. This advance resulted in a rapid increase in the geological knowledge and understanding of the Canadian Arctic. It was the work of Dr. Thorsteinsson and his fellow geologists at the GSC which led to extensive land acquisitions by many oil and mining companies in the region during the late '50s and early '60s. Their work still forms the broad base for present exploration. Ray Thorsteinsson made significant contributions in the fields of structural geology and biochronology, as well as in regional stratigraphy. He supplemented his predominantly stratigraphic work by paleontological studies, making fundamental advances in the knowledge of graptolites and of the extinct ostracoderm fishes. He has also established the most complete succession of faunal zones in Pennsylvanian and Permian rocks in the Arctic based on Upper Paleozoic foraminifera, the Fusilinacea. He is Head of the Arctic Islands section of the Geological Survey, and has published more than fifty maps and articles. His maps cover an area larger than the British Isles. ..

Image based simulation of one-dimensional compression tests on carbonate sand

High factors of safety and conservative methods are commonly used on foundation design on shelly carbonate soils. A better understanding of the behavior of this material is, thus, critical for more sustainable approaches for the design of a number of offshore structures and submarine pipelines. In particular, understanding the physical phenomena taking place at the microscale has the potential to spur the development of robust computational methods. In this study, a one-dimensional compression test was performed inside an X-ray scanner to obtain 3D images of the evolving internal structure of a shelly carbonate sand. A preliminary inspection of the images through five loading increments has shown that the grains rearrange under loading and in some cases cracks develop at the contacts. In order to replicate of the experiments in the numerical domain, the 3D image of the soil prior to loading was imported into a micro Finite Element (µFE) framework. This image-based modelling tool enables measurements of the contact force and stress map inside the grains while making use of the real microstructure of the soil. The potential of the µFE model to contribute insights into yield initiation within the grain is demonstrated here. This is of particular interest to better understand the breakage of shelly grains underpinning their highly compressive behavior

Security risk assessment and protection in the chemical and process industry

This article describes a security risk assessment and protection methodology that was developed for use in the chemical- and process industry in Belgium. The approach of the method follows a risk-based approach that follows desing principles for chemical safety. That approach is beneficial for workers in the chemical industry because they recognize the steps in this model from familiar safety models .The model combines the rings-of-protection approach with generic security practices including: management and procedures, security technology (e.g. CCTV, fences, and access control), and human interactions (pro-active as well as re-active). The method is illustrated in a case-study where a practical protection plan was developed for an existing chemical company. This chapter demonstrates that the method is useful for similar chemical- and process industrial activities far beyond the Belgian borders, as well as for cross-industrial security protection. This chapter offers an insight into how the chemical sector protects itself on the one hand, and an insight into how security risk management can be practiced on the other hand

Use of coal fly ash as a catalyst in the production of biodiesel

South Africa is largely dependent on the combustion of coal for electricity production; Eskom’s coalfired power stations consume approximately 109 million tons of coal per annum, producing around 25 million tons of ash, to supply the bulk (93%) of South Africa’s electricity. The management of this fly ash has been a concern with various approaches for its beneficial use being investigated. This work presents the results of transesterification reaction using sunflower oil as feedstock with methanol and class F fly ash catalyst derived from a coal fly ash dump in South Africa to produce methyl esters (biodiesel). The fly ash based catalyst was prepared using the wet impregnation procedure with different loadings of potassium. This was characterized by powder X-ray diffraction (XRD), FTIR spectroscopy. The XRD patterns obtained indicated that the structure of the support gradually deformed with an increase in the loading and the extent of decomposition of KNO3 varied with the amount of loading. The influence of various reactions parameters such as loading amount of active components, methanol: oil ratio, reaction time, temperature and catalyst deactivation was investigated. The fly ash based catalyst loaded with 5% wt KNO3 at a reaction temperature of 160ºC exhibited maximum oil conversion (86.13%). The biodiesel synthesized was tested and important fuel properties of the methyl esters (Biodiesel) compared well with ASTM biodiesel standar

Chemical Kinetic Insights into the Octane Number and Octane Sensitivity of Gasoline Surrogate Mixtures

Gasoline octane number is a significant empirical parameter for the optimization and development of internal combustion engines capable of resisting knock. Although extensive databases and blending rules to estimate the octane numbers of mixtures have been developed and the effects of molecular structure on autoignition properties are somewhat understood, a comprehensive theoretical chemistry-based foundation for blending effects of fuels on engine operations is still to be developed. In this study, we present models that correlate the research octane number (RON) and motor octane number (MON) with simulated homogeneous gas-phase ignition delay times of stoichiometric fuel/air mixtures. These correlations attempt to bridge the gap between the fundamental autoignition behavior of the fuel (e.g., its chemistry and how reactivity changes with temperature and pressure) and engine properties such as its knocking behavior in a cooperative fuels research (CFR) engine. The study encompasses a total of 79 hydrocarbon gasoline surrogate mixtures including 11 primary reference fuels (PRF), 43 toluene primary reference fuels (TPRF), and 19 multicomponent (MC) surrogate mixtures. In addition to TPRF mixture components of iso-octane/n-heptane/toluene, MC mixtures, including n-heptane, iso-octane, toluene, 1-hexene, and 1,2,4-trimethylbenzene, were blended and tested to mimic real gasoline sensitivity. ASTM testing protocols D-2699 and D-2700 were used to measure the RON and MON of the MC mixtures in a CFR engine, while the PRF and TPRF mixtures' octane ratings were obtained from the literature. The mixtures cover a RON range of 0-100, with the majority being in the 70-100 range. A parametric simulation study across a temperature range of 650-950 K and pressure range of 15-50 bar was carried out in a constant-volume homogeneous batch reactor to calculate chemical kinetic ignition delay times. Regression tools were utilized to find the conditions at which RON and MON best correlate with simulated ignition delay times. Furthermore, temperature and pressure dependences were investigated for fuels with varying octane sensitivity. This analysis led to the formulation of correlations useful to the definition of surrogates for modeling purposes and allowed one to identify conditions for a more in-depth understanding of the chemical phenomena controlling the antiknock behavior of the fuels