154 research outputs found
: Implications of the rhombohedral k-space texture on the evaluation of the in-plane/out-of-plane conductivity anisotropy
Different computational scheme for calculating surface integrals in
anisotropic Brillouin zones are compared. The example of the transport
distribution function (plasma frequency) of the thermoelectric Material \BiTe
near the band edges will be discussed. The layered structure of the material
together with the rhombohedral symmetry causes a strong anisotropy of the
transport distribution function for the directions in the basal (in-plane) and
perpendicular to the basal plane (out-of-plane). It is shown that a thorough
reciprocal space integration is necessary to reproduce the
in-plane/out-of-plane anisotropy. A quantitative comparison can be made at the
band edges, where the transport anisotropy is given in terms of the anisotropic
mass tensor.Comment: 7 pages, 6 figs., subm. to J. Phys. Cond. Ma
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Influence of volcanic eruptions on midlatitude upper tropospheric aerosol and consequences for cirrus clouds
The influence of downwelling stratospheric sulfurous aerosol on the UT (upper troposphere) aerosol concentrations and on cirrus clouds is investigated using CARIBIC (Civil Aircraft for Regular Investigation of the Atmosphere Based on an Instrument Container observations) (between 1999–2002 and 2005–2013) and the cirrus reflectance product from Moderate Resolution Imaging Spectroradiometer (MODIS). The initial period, 1999–2002, was volcanically quiescent after which the sulfurous aerosol in the LMS (lowermost stratosphere) (SLMS) became enhanced by several volcanic eruptions starting 2005. From 2005 to 2008 and in 2013, volcanic aerosol from several tropical eruptions increased SLMS. Due to consequent subsidence, the sulfur loading of the upper troposphere (SUT) was increased by a factor of 2.5 compared to background levels. Comparison of SLMS and SUT during the seasons March–July and August–November shows a close coupling of the UT and LMS. Finally, the relationship between SLMS and the cirrus cloud reflectance (CR) retrieved from MODIS spectrometer (on board the satellites Terra and Aqua) is studied. SLMS and CR show a strong anticorrelation, with a factor of 3.5 increase in SLMS and decrease of CR by 8 ± 2% over the period 2001–2011. We propose that the increase of SLMS due to volcanism has caused the coinciding cirrus CR decrease, which would be associated with a negative radiative forcing in the Northern Hemisphere midlatitudes
Influence of volcanic eruptions on midlatitude upper tropospheric aerosol and consequences for cirrus clouds – Volc Affects S Aerosol in UT and Cirrus
The influence of downwelling stratospheric sulfurous aerosol on the UT (upper troposphere) aerosol concentrations and on cirrus clouds is investigated using CARIBIC (Civil Aircraft for Regular Investigation of the Atmosphere Based on an Instrument Container observations) (between 1999–2002 and 2005–2013) and the cirrus reflectance product from Moderate Resolution Imaging Spectroradiometer (MODIS). The initial period, 1999–2002, was volcanically quiescent after which the sulfurous aerosol in the LMS (lowermost stratosphere) (S) became enhanced by several volcanic eruptions starting 2005. From 2005 to 2008 and in 2013, volcanic aerosol from several tropical eruptions increased S. Due to consequent subsidence, the sulfur loading of the upper troposphere (S) was increased by a factor of 2.5 compared to background levels. Comparison of SLMS and S during the seasons March–July and August–November shows a close coupling of the UT and LMS. Finally, the relationship between S and the cirrus cloud reflectance (CR) retrieved from MODIS spectrometer (on board the satellites Terra and Aqua) is studied. S and CR show a strong anticorrelation, with a factor of 3.5 increase in SLMS and decrease of CR by 8 ± 2% over the period 2001–2011. We propose that the increase of S due to volcanism has caused the coinciding cirrus CR decrease, which would be associated with a negative radiative forcing in the Northern Hemisphere midlatitudes
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Trapping, chemistry, and export of trace gases in the South Asian summer monsoon observed during CARIBIC flights in 2008
The CARIBIC (Civil Aircraft for the Regular Investigation of the Atmosphere Based on an Instrument Container) passenger aircraft observatory performed in situ measurements at 10–12 km altitude in the South Asian summer monsoon anticyclone between June and September 2008. These measurements enable us to investigate this atmospheric region (which so far has mostly been observed from satellites) using the broad suite of trace gases and aerosol particles measured by CARIBIC. Elevated levels of a variety of atmospheric pollutants (e.g. carbon monoxide, total reactive nitrogen oxides, aerosol particles, and several volatile organic compounds) were recorded. The measurements provide detailed information about the chemical composition of air in different parts of the monsoon anticyclone, particularly of ozone precursors. While covering a range of 3500 km inside the monsoon anticyclone, CARIBIC observations show remarkable consistency, i.e. with distinct latitudinal patterns of trace gases during the entire monsoon period.
Using the CARIBIC trace gas and aerosol particle measurements in combination with the Lagrangian particle dispersion model FLEXPART, we investigated the characteristics of monsoon outflow and the chemical evolution of air masses during transport. The trajectory calculations indicate that these air masses originated mainly from South Asia and mainland Southeast Asia. Estimated photochemical ages of the air were found to agree well with transport times from a source region east of 90–95° E. The photochemical ages of the air in the southern part of the monsoon anticyclone were systematically younger (less than 7 days) and the air masses were mostly in an ozone-forming chemical mode. In its northern part the air masses were older (up to 13 days) and had unclear ozone formation or destruction potential. Based on analysis of forward trajectories, several receptor regions were identified. In addition to predominantly westward transport, we found evidence for efficient transport (within 10 days) to the Pacific and North America, particularly during June and September, and also of cross-tropopause exchange, which was strongest during June and July. Westward transport to Africa and further to the Mediterranean was the main pathway during July
Hexatic Order and Surface Ripples in Spherical Geometries
In flat geometries, two dimensional hexatic order has only a minor effect on
capillary waves on a liquid substrate and on undulation modes in lipid
bilayers. However, extended bond orientational order alters the long wavelength
spectrum of these ripples in spherical geometries. We calculate this frequency
shift and suggest that it might be detectable in lipid bilayer vesicles, at the
surface of liquid metals and in multielectron bubbles in liquid helium at low
temperatures. Hexatic order also leads to a shift in the threshold for the
fission instability induced in the later two systems by an excess of electric
charge.Comment: 5 pages, 1 figure; revised version; to appear in Phys. Rev. Let
Elastic moduli, dislocation core energy and melting of hard disks in two dimensions
Elastic moduli and dislocation core energy of the triangular solid of hard
disks of diameter are obtained in the limit of vanishing dislocation-
antidislocation pair density, from Monte Carlo simulations which incorporates a
constraint, namely that all moves altering the local connectivity away from
that of the ideal triangular lattice are rejected. In this limit, we show that
the solid is stable against all other fluctuations at least upto densities as
low as . Our system does not show any phase transition so
diverging correlation lengths leading to finite size effects and slow
relaxations do not exist. The dislocation pair formation probability is
estimated from the fraction of moves rejected due to the constraint which
yields, in turn, the core energy E_c and the (bare) dislocation fugacity y.
Using these quantities, we check the relative validity of first order and
Kosterlitz-Thouless-Halperin-Nelson-Young (KTHNY) melting scenarios and obtain
numerical estimates of the typical expected transition densities and pressures.
We conclude that a KTHNY transition from the solid to a hexatic phase preempts
the solid to liquid first order transition in this system albeit by a very
small margin, easily masked by crossover effects in unconstrained
``brute-force'' simulations with small number of particles.Comment: 17 pages, 8 figure
Direct Visualization of Dislocation Dynamics in Grain Boundary Scars
Mesoscale objects with unusual structural features may serve as the analogues
of atoms in the design of larger-scale materials with novel optical, electronic
or mechanical behaviour. In this paper we investigate the structural features
and the equilibrium dynamics of micron-scale spherical crystals formed by
polystyrene particles adsorbed on the surface of a spherical water droplet. The
ground state of sufficiently large crystals possesses finite-length grain
boundaries (scars). We determine the elastic response of the crystal by
measuring single-particle diffusion and quantify the fluctuations of individual
dislocations about their equilibrium positions within a scar determining the
dislocation spring constants. We observe rapid dislocation glide with
fluctuations over the barriers separating one local Peierls minimum from the
next and rather weak binding of dislocations to their associated scars. The
long-distance (renormalised) dislocation diffusion glide constant is extracted
directly from the experimental data and is found to be moderately faster than
single particle diffusion. We are also able to determine the parameters of the
Peierls potential induced by the underlying crystalline lattice.Comment: 11 pages, 4 figures, pdf forma
Limitations of the MELD score in predicting mortality or need for removal from waiting list in patients awaiting liver transplantation
<p>Abstract</p> <p>Background</p> <p>Decompensated cirrhosis is associated with a poor prognosis and liver transplantation provides the only curative treatment option with excellent long-term results. The relative shortage of organ donors renders the allocation algorithms of organs essential. The optimal strategy based on scoring systems and/or waiting time is still under debate.</p> <p>Methods</p> <p>Data sets of 268 consecutive patients listed for single-organ liver transplantation for nonfulminant liver disease between 2003 and 2005 were included into the study. The Model for End-Stage Liver Disease (MELD) and Child-Turcotte-Pugh (CTP) scores of all patients at the time of listing were used for calculation. The predictive ability not only for mortality on the waiting list but also for the need for withdrawal from the waiting list was calculated for both scores. The Mann-Whitney-U Test was used for the univariate analysis and the AUC-Model for discrimination of the scores.</p> <p>Results</p> <p>In the univariate analysis comparing patients who are still on the waiting list and patients who died or were removed from the waiting list due to poor conditions, the serum albumin, bilirubin INR, and CTP and MELD scores as well as the presence of ascites and encephalopathy were significantly different between the groups (p < 0.05), whereas serum creatinine and urea showed no difference.</p> <p>Comparing the predictive abilities of CTP and MELD scores, the best discrimination between patients still alive on the waiting list and patients who died on or were removed from the waiting list was achieved at a CTP score of ≥9 and a MELD score of ≥14.4. The sensitivity and specificity to identify mortality or severe deterioration for CTP was 69.0% and 70.5%, respectively; for MELD, it was 62.1% and 72.7%, respectively. This result was supported by the AUC analysis showing a strong trend for superiority of CTP over MELD scores (AUROC 0.73 and 0.68, resp.; p = 0.091).</p> <p>Conclusion</p> <p>The long term prediction of mortality or removal from waiting list in patients awaiting liver transplantation might be better assessed by the CTP score than the MELD score. This might have implications for the development of new improved scoring systems.</p
Developmental Robustness by Obligate Interaction of Class B Floral Homeotic Genes and Proteins
DEF-like and GLO-like class B floral homeotic genes encode closely related MADS-domain transcription factors that act as developmental switches involved in specifying the identity of petals and stamens during flower development. Class B gene function requires transcriptional upregulation by an autoregulatory loop that depends on obligate heterodimerization of DEF-like and GLO-like proteins. Because switch-like behavior of gene expression can be displayed by single genes already, the functional relevance of this complex circuitry has remained enigmatic. On the basis of a stochastic in silico model of class B gene and protein interactions, we suggest that obligate heterodimerization of class B floral homeotic proteins is not simply the result of neutral drift but enhanced the robustness of cell-fate organ identity decisions in the presence of stochastic noise. This finding strongly corroborates the view that the appearance of this regulatory mechanism during angiosperm phylogeny led to a canalization of flower development and evolution
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