Visualization of the homogeneous charge compression ignition/controlled autoignition combustion process using two-dimensional planar laser-induced fluorescence imaging of formaldehyde

The paper reports an investigation into the HCCI/CAI combustion process using the two-dimensional PLIF technique. The PLIF of formaldehyde formed during the low-temperature reactions of HCCI/CAI combustion was exciting by a tunable dye laser at 355nm wavelength and detected by a gated ICCD camera. Times and locations of the two-stage autoignition of HCCI/CAI combustion were observed in a single cylinder optical engine for several fuel blends mixed with n-heptane and iso-octane. The results show, when pure n-heptane was used, the initial formation of formaldehyde and its subsequent burning were closely related to the start of the low temperature heat release stage and the start of the main heat release stage of HCCI combustion respectively. Meanwhile, it was found that the formation of formaldehyde was more affected by the charge temperature than by the fuel concentration. But its subsequent burning or the start of main heat release combustion toke place at those areas where both the fuel concentration and the charge temperature were sufficient high. As a result, it was found that the presence of stratified residual gases affected both the spatial location and the temporal site of autoignition in a HCCI/CAI combustion engine. All studied fuels were found having similar formaldehyde formation timings with n-heptane. This means that the presence of iso-octane did not affect the start of low temperature reactions apparently. However, the heat release during low temperature reaction was significantly reduced with the presence of iso-octane in the studied fuels. In addition, the presence of iso-octane retarded the start of the main combustion stage

An Invariance Principle of G-Brownian Motion for the Law of the Iterated Logarithm under G-expectation

The classical law of the iterated logarithm (LIL for short)as fundamental limit theorems in probability theory play an important role in the development of probability theory and its applications. Strassen (1964) extended LIL to large classes of functional random variables, it is well known as the invariance principle for LIL which provide an extremely powerful tool in probability and statistical inference. But recently many phenomena show that the linearity of probability is a limit for applications, for example in finance, statistics. As while a nonlinear expectation--- G-expectation has attracted extensive attentions of mathematicians and economists, more and more people began to study the nature of the G-expectation space. A natural question is: Can the classical invariance principle for LIL be generalized under G-expectation space? This paper gives a positive answer. We present the invariance principle of G-Brownian motion for the law of the iterated logarithm under G-expectation

Continuity of the Solution Maps for Generalized Parametric Set-Valued Ky Fan Inequality Problems

Under new assumptions, we provide suffcient conditions for the (upper and lower) semicontinuity and continuity of the solution mappings to a class of generalized parametric set-valued Ky Fan inequality problems in linear metric space. These results extend and improve some known results in the literature (e.g., Gong, 2008; Gong and Yoa, 2008; Chen and Gong, 2010; Li and Fang, 2010). Some examples are given to illustrate our results

targeted therapies in conversion therapy in mcrc a systematic review and meta analysis

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Carbon supported CdSe nanocrystals

Insights to the mechanism of CdSe nanoparticle attachment to carbon nanotubes following the hot injection method are discussed. It was observed that the presence of water improves the nanotube coverage while Cl containing media are responsible for the shape transformation of the nanoparticles and further attachment to the carbon lattice. The experiments also show that the mechanism taking place involves the right balance of several factors, namely, low passivated nanoparticle surface, particles with well-defined crystallographic facets, and interaction with an organics-free sp2 carbon lattice. Furthermore, this procedure can be extended to cover graphene by quantum dots.Comment: 5 pages, 5 figure

Etching suspended superconducting hybrid junctions from a multilayer

A novel method to fabricate large-area superconducting hybrid tunnel junctions with a suspended central normal metal part is presented. The samples are fabricated by combining photo-lithography and chemical etch of a superconductor - insulator - normal metal multilayer. The process involves few fabrication steps, is reliable and produces extremely high-quality tunnel junctions. Under an appropriate voltage bias, a significant electronic cooling is demonstrated

Decay and expansion of the early aftershock activity following the 2011, M_w9.0 Tohoku earthquake

The 2011, M_w9.0 Tohoku earthquake was followed by an abundant amount of seismicity providing a unique opportunity to analyze the triggering mechanism of great earthquakes. Although the Tohoku earthquake occurred close to a dense seismic network, many aftershocks that occurred in the first few hours after the mainshock are not recorded in the earthquake catalogs. Here we use a template waveform approach to recover as many as possible missing events in the first 12 hours following the Tohoku mainshock. Our analysis is able to detect about 1.4 times more events than those listed in the High Sensitivity Seismograph (Hi-net) earthquake catalog. Combining our new dataset with earthquakes that occurred at latter times, we are able to observe a continuous decay of the aftershock rate and along strike expansion of aftershock area. We relate the latter observation to the occurrence of post-seismic slip over the deep interface

Interplay of phase boundary anisotropy and electro-autocatalytic surface reactions on the lithium intercalation dynamics in LiX_XFePO4_4 platelet-like nanoparticles

Experiments on single crystal Li$_X$FePO$_4$ (LFP) nanoparticles indicate rich nonequilibrium phase behavior, such as suppression of phase separation at high lithiation rates, striped patterns of coherent phase boundaries, nucleation by binarysolid surface wetting and intercalation waves. These observations have been successfully predicted (prior to the experiments) by 1D depth-averaged phase-field models, which neglect any subsurface phase separation. In this paper, using an electro-chemo-mechanical phase-field model, we investigate the coherent non-equilibrium subsurface phase morphologies that develop in the $ab$- plane of platelet-like single-crystal platelet-like Li$_X$FePO$_4$ nanoparticles. Finite element simulations are performed for 2D plane-stress conditions in the $ab$- plane, and validated by 3D simulations, showing similar results. We show that the anisotropy of the interfacial tension tensor, coupled with electroautocatalytic surface intercalation reactions, plays a crucial role in determining the subsurface phase morphology. With isotropic interfacial tension, subsurface phase separation is observed, independent of the reaction kinetics, but for strong anisotropy, phase separation is controlled by surface reactions, as assumed in 1D models. Moreover, the driven intercalation reaction suppresses phase separation during lithiation, while enhancing it during delithiation, by electro-autocatalysis, in quantitative agreement with {\it in operando} imaging experiments in single-crystalline nanoparticles, given measured reaction rate constants