Global sensitivity analysis of detailed chemical kinetic schemes for DME oxidation in premixed flames

Detailed chemical kinetic investigations on dimethylether oxidation in one-dimensional premixed flat flames were performed. Local and global sensitivities of the reaction rate constants within selected chemical kinetic schemes were studied using maximum flame temperature, and peak methane and formaldehyde concentrations as predictive target quantities. The global sensitivity analysis was based on the application of high dimensional model representations using quasi-random sampling. First- and second-order sensitivity indices of important reaction steps were determined for fuel rich (Φ = 1.49) and fuel lean (Φ = 0.67) conditions. Differences in the importance ranking for key reactions were found to exist between the selected schemes, highlighting the influence of differences in the key rate constants. Whilst the peak flame temperature was predicted with fairly low uncertainty by both schemes, significant uncertainties were identified in the prediction of the target minor species. Key reaction rates requiring better quantification in order to improve the prediction of methane and formaldehyde concentrations are identified

Dynamics of new party formation in the Czech Republic 1996–2010: looking for the origins of a ‘political earthquake’

The stable and closed nature of the Czech party system and the failure of most new political parties have been among the most salient features of Czech democracy over the past two decades. The results of the 2010 parliamentary elections seemed to mark a break with this pattern: support for two main parties slumped to historically low levels and two new parties, TOP09 and Public Affairs (VV), entered parliament. This article seeks to put the ‘political earthquake’ of 2010 into perspective by mapping the development of new parties in the Czech Republic from the mid-1990s and relating them to comparative literature and typologies of new party emergence. It concludes that of the two successful new parties in 2010, Public Affairs was, by far, the more novel and important phenomenon

Inspection of Construction Structures

The reasearch report is aimed to methods and techniques for detection failures in concrete structures.The used methods were Impact-Echo method, High-frequency radar and Ultrasound