Strength Analysis of a Freight Bogie Frame under the Defined Load Cases

This work presents results of strength analyses of a modified freight wagon bogie frame. It consists of two main parts. The first part is addressed to introduction of the structure of a freight wagon bogie frame. It is a modified frame structure, which reflects current requirements of modern railway transport means. The conditions for rail vehicles approval and the main load cases, which every bogie frame must meet for commissioning, are described. The next part deals with computer modelling and analyses of this bogie frame. Strength analyses were performed using the FE method and they were focused on the assessment of stresses in the frame structure. Loads definition and the method of calculation were based on valid norms and standards

The Impact of Bark Content in Wood Pellets on Emission Production During Combustion in Small Heat Source

The combustion of biomass is relatively complicated. To minimize the emission production it is necessary to ensure the optimal setting of combustion process. The article deals with the impact of bark content in wood biomass on performance and emission parameters of a small heat source. The increasing content of bark in wood biomass changes its chemical composition and parameters, namely its net calorific value, ash content, ash fusion temperature and others. During experiments samples of wood pellets made from spruce having 1, 2, 5 and 10 percent bark content together with a reference sample without any bark content were burned. The samples were burned in a hot water boiler with a rated output of 18 kW. It was found out that with the increasing bark content, the thermal output of the heat source decreases and the emission production increases, particularly the production of both carbon monoxide (CO) and particulate matter (PM). At the same time it was confirmed that with the increasing bark content the amount of ash also increases. Results showed that the burning of wood pellets with higher bark content has a more negative impact on the environment

Pyridyl-benzimidazole derivatives decorated with phenylazo substituents and their low-spin iron( ii ) complexes: a study of the synthesis, structure and photoisomerization

International audienceA series of phenylazo-substituted derivatives of pyridyl-benzimidazoles L1–L5 has been synthesized via a modified Mills reaction and their structural, spectral and photoswitching properties were investigated. NMR spectroscopy and single-crystal X-ray diffraction analysis of the desired compounds confirmed their E conformation. The light-induced E ↔ Z (also called trans ↔ cis) isomerization was monitored using UV-VIS and 1H NMR spectroscopy that revealed a reversible photochromic behavior governed by first-order kinetics. State-of-the-art meta-dynamics simulations (iMTD-GC) and ab initio calculations (CASSCF-NEVPT2 and STEOM-DLPNO-CCSD) made the analysis of the electronic structures of ligands possible, which helped to explain the bland E-to-Z conversion of L1 and pronounced switching of L2–L5 ligands. Furthermore, the computational studies identified the active wavelengths of E-to-Z conversion and allowed assessing the mechanisms of photoisomerization. Additionally, ligands L1 and L2 were used for the preparation of four ferrous coordination compounds C1–C4 in which the structural and magnetic investigations confirmed the permanent low-spin state and diamagnetic behavior in the solid state. On the other hand, dissolved compounds C1 and C2 are high-spin at room temperature and their blue light irradiation causes the decomplexation instead of the desired E-to-Z isomerization

Fungal Systematics and Evolution : FUSE 4

Eight new species presented are Calostoma areolatum collected in Wuyishan National Park (China), Crinipellis bidens from Hubei Province (China), Lactifluus sainii from Himalayan India, Inocybe elata from Yunnan (China), Inocybe himalayensis from Pakistan. Specimens previously identified as Massalongia carnosa represent a new species, namely M. patagonica restricted to southern South America. Saprolegnia maragheica is a new oomycete species of fresh water in Maraghe (Iran). Uncispora wuzhishanensis is a new aquatic hyphomycete species. A type specimen of Raddetes turkestanicus was studied and based on this the new combination Conocybe turkestanica, is proposed. Argyranthemum frutescens is a new host for Alternaria alternata and Syzygium cumini for Phyllosticta capitalensis in India. Crepidotus ehrendorferi is confirmed for Hungary and Pluteus leucoborealis for Central Europe, and for the phytogeographical region of Carpaticum. Pseudopithomyces palmicola is shown to occur on grapevine and it is validated by adding a unique identifier. Terfezia fanfani is reported first from Algeria.Peer reviewe