Скоростная модуляция поперечно-модового состава лазерных пучков с помощью дифракционных оптических элементов на основе LiNbO3

A diffractive optical element based on a nonlinear-optical ferroelectric single crystal has been proposed, synthesized, and experimentally characterized. The element allows fast modulation of transverse modes of a Gaussian laser beam. © 2021, Institution of Russian Academy of Sciences. All rights reserved.The equipment of the Ural Center for Shared Use “Modern nanotechnolo- gy” UrFU was used. This work was supported by the Russian Foundation for Basic Research (grant no. 18-29-20077 mk)

Performance of Waterborne Polyurethanes in Inhibition of Gas Hydrate Formation and Corrosion: Influence of Hydrophobic Fragments

The design of new dual-function inhibitors simultaneously preventing hydrate formation and corrosion is a relevant issue for the oil and gas industry. The structure-property relationship for a promising class of hybrid inhibitors based on waterborne polyurethanes (WPU) was studied in this work. Variation of diethanolamines differing in the size and branching of N-substituents (methyl, n-butyl, and tert-butyl), as well as the amount of these groups, allowed the structure of polymer molecules to be preset during their synthesis. To assess the hydrate and corrosion inhibition efficiency of developed reagents pressurized rocking cells, electrochemistry and weight-loss techniques were used. A distinct effect of these variables altering the hydrophobicity of obtained compounds on their target properties was revealed. Polymers with increased content of diethanolamine fragments with n- or tert-butyl as N-substituent (WPU-6 and WPU-7, respectively) worked as dual-function inhibitors, showing nearly the same efficiency as commercial ones at low concentration (0.25 wt%), with the branched one (tert-butyl; WPU-7) turning out to be more effective as a corrosion inhibitor. Commercial kinetic hydrate inhibitor Luvicap 55 W and corrosion inhibitor Armohib CI-28 were taken as reference samples. Preliminary study reveals that WPU-6 and WPU-7 polyurethanes as well as Luvicap 55 W are all poorly biodegradable compounds; BODt/CODcr (ratio of Biochemical oxygen demand and Chemical oxygen demand) value is 0.234 and 0.294 for WPU-6 and WPU-7, respectively, compared to 0.251 for commercial kinetic hydrate inhibitor Luvicap 55 W. Since the obtained polyurethanes have a bifunctional effect and operate at low enough concentrations, their employment is expected to reduce both operating costs and environmental impact.publishedVersio

Application of locality principle to radio occultation studies of the Earth's atmosphere and ionosphere

A new formulation of the previously introduced principle of locality is presented. The principle can be applied for modernization of the radio occultation (RO) remote sensing of the atmospheres and ionospheres of the Earth and other planets. The principle states that significant contributions to variations of the intensity and phase of the radio waves passing through a layered medium are connected with influence of the vicinities of tangential points where the refractivity gradient is perpendicular to the radio ray trajectory. The RO method assumes spherical symmetry of the investigated medium. In this case, if location of a tangent point relative to the spherical symmetry centre is known, the time derivatives of the RO signal phase and Doppler frequency variations can be recalculated into the refractive attenuation

Application of the locality principle to radio occultation studies of the Earth's atmosphere and ionosphere

A new formulation of the previously introduced principle of locality is presented. The principle can be applied for modernization of the radio occultation (RO) remote sensing of the atmospheres and ionospheres of the Earth and other planets. The principle states that significant contributions to variations of the intensity and phase of the radio waves passing through a layered medium are connected with influence of the vicinities of tangential points where the refractivity gradient is perpendicular to the radio ray trajectory. The RO method assumes spherical symmetry of the investigated medium. In this case, if location of a tangent point relative to the spherical symmetry centre is known, the time derivatives of the RO signal phase and Doppler frequency variations can be recalculated into the refractive attenuation. Several important findings are consequences of the locality principle: (i) if position of the centre of symmetry is known, the total absorption along the ray path can be determined at a single frequency; (ii) in the case of low absorption the height, displacement from the radio ray perigee, and tilt of the inclined ionospheric (atmospheric) layers can be evaluated; (iii) the contributions of the layered and irregular structures in the RO signal can be separated and parameters of layers and turbulence can be measured at a single frequency using joint analysis of the intensity and phase variations. Specially for the Earth's troposphere, the altitude distributions of the weak total absorption (about of 1–4 db) of the radio waves at GPS frequencies corresponding to possible influence of the oxygen, water vapour, and hydrometeors can be measured with accuracy of about 0.1 db at a single frequency. In accordance with the locality principle, a new index of ionospheric activity is introduced. This index is measured from the phase variations of radio waves passing through the ionosphere. Its high correlation with the S4 scintillation index is established. This correlation indicates the significant influence of locally spherical symmetric ionospheric layers on variations of the phase and intensity of the RO signal passing through transionospheric communication links. Obtained results expand applicable domain of the RO method as a powerful remote sensing technique for geophysical and meteorological research

Identification and localization of layers in the ionosphere using the eikonal and amplitude of radio occultation signals

By using the CHAllenge Minisatellite Payload (CHAMP) radio occultation (RO) data, a description of different types of the ionospheric impacts on the RO signals at the altitudes 30–90 km of the RO ray perigee is given and compared with the results of measurements obtained earlier in the satellite-to-Earth communication link at frequency 1.5415 GHz. An analytical model is introduced for describing propagation of radio waves in a stratified medium consisting of sectors with spherically symmetric refractivity distribution. This model gives analytical expressions for the phase, bending angle, and refractive attenuation of radio waves and is applied to the analysis of radio wave propagation phenomena along an extended path including the atmosphere and two parts of the ionosphere. The model explains significant amplitude and phase variations at altitudes 30–90 km of the RO ray perigee and attributes them to inclined ionospheric layers. Based on this analytical model, an innovative technique is introduced to locate layers in the atmosphere and ionosphere. A necessary and sufficient criterion is obtained for a layer to be located at the RO ray perigee. This criterion gives both qualitative and quantitative estimation of the displacement of an ionospheric and/or atmospheric layer from the RO ray perigee. This is important, in particular, for determining the location of wind shears and directions of the internal wave propagation in the lower ionosphere, and, possibly, in the atmosphere