3,531 research outputs found
DFT Calculations as a Tool to Analyse Quadrupole Splittings of Spin Crossover Fe(II) complexes
Density functional methods have been applied to calculate the quadrupole
splitting of a series of iron(II) spin crossover complexes. Experimental and
calculated values are in reasonable agreement. In one case spin-orbit coupling
is necessary to explain the very small quadrupole splitting value of 0.77 mm/s
at 293 K for a high-spin isomer
High-spin low-spin transition
Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron
radiation was applied to investigate both spin states of the spin-crossover
complex [Fe(tpa)(NCS)(2)] (tpa = tris(2-pyridylmethyl)amine). A remarkable
increase of the iron-ligand bond stretching upon spin crossover has
unambiguously been identified by comparing the measured NIS spectra with
theoretical simulations based on density-functional calculations
Type I superconductivity in the Dirac semimetal PdTe2
The superconductor PdTe was recently classified as a Type II Dirac
semimetal, and advocated to be an improved platform for topological
superconductivity. Here we report magnetic and transport measurements conducted
to determine the nature of the superconducting phase. Surprisingly, we find
that PdTe is a Type I superconductor with K and a critical
field mT. Our crystals also exhibit the intermediate
state as demonstrated by the differential paramagnetic effect. For we
observe superconductivity of the surface sheath. This calls for a close
examination of superconductivity in PdTe in view of the presence of
topological surface states.Comment: 5 page
Pressure-induced changes of the vibrational modes of spin-crossover complexes studied by nuclear resonance scattering of synchrotron radiation
Nuclear inelastic scattering (NIS) spectra were recorded for the
spin-crossover complexes STP and ETP (STP =
[Fe(1,1,1-trisf[N-(2-pyridylmethyl)-N-methylamino]methylg- ethane)](ClO4)2 and
ETP =
[Fe(1,1,1-trisf[N-(2-pyridylmethyl)-N-methylamino]methylg-butane)](ClO4)2) at
30 K and at room temperature and also at ambient pressure and applied pressure
(up to 2.6 GPa). Spin transition from the high-spin (HS) to the low-spin (LS)
state was observed by lowering temperature and also by applying pressure at
room temperature and has been assigned to the hardening of iron-bond stretching
modes due to the smaller volume in the LS isomer
An automated and versatile ultra-low temperature SQUID magnetometer
We present the design and construction of a SQUID-based magnetometer for
operation down to temperatures T = 10 mK, while retaining the compatibility
with the sample holders typically used in commercial SQUID magnetometers. The
system is based on a dc-SQUID coupled to a second-order gradiometer. The sample
is placed inside the plastic mixing chamber of a dilution refrigerator and is
thermalized directly by the 3He flow. The movement though the pickup coils is
obtained by lifting the whole dilution refrigerator insert. A home-developed
software provides full automation and an easy user interface.Comment: RevTex, 10 pages, 10 eps figures. High-resolution figures available
upon reques
Dynamics of Metal Centers Monitored by Nuclear Inelastic Scattering
Nuclear inelastic scattering of synchrotron radiation has been used now since
10 years as a tool for vibrational spectroscopy. This method has turned out
especially useful in case of large molecules that contain a M\"ossbauer active
metal center. Recent applications to iron-sulfur proteins, to iron(II) spin
crossover complexes and to tin-DNA complexes are discussed. Special emphasis is
given to the combination of nuclear inelastic scattering and density functional
calculations
Superconductivity and magnetic order in the non-centrosymmetric Half Heusler compound ErPdBi
We report superconductivity at K and magnetic order at K in the semi-metallic noncentrosymmetric Half Heusler compound ErPdBi.
The upper critical field, , has an unusual quasi-linear temperature
variation and reaches a value of 1.6 T for . Magnetic order is
found below and is suppressed at T for . Since , the interaction of superconductivity and magnetism
is expected to give rise to a complex ground state. Moreover, electronic
structure calculations show ErPdBi has a topologically nontrivial band
inversion and thus may serve as a new platform to study the interplay of
topological states, superconductivity and magnetic order.Comment: 6 pages, 5 figures; accepted for publication in Europhysics Letter
Density functional theory calculations and vibrational spectroscopy on iron spin-crossover compounds
Iron complexes with a suitable ligand field undergo spin-crossover (SCO),
which can be induced reversibly by temperature, pressure or even light.
Therefore, these compounds are highly interesting candidates for optical
information storage, for display devices and pressure sensors. The SCO
phenomenon can be conveniently studied by spectroscopic techniques like Raman
and infrared spectroscopy as well as nuclear inelastic scattering, a technique
which makes use of the M\"ossbauer effect. This review covers new developments
which have evolved during the last years like, e.g. picosecond infrared
spectroscopy and thin film studies but also gives an overviewon newtechniques
for the theoretical calculation of spin transition phenomena and vibrational
spectroscopic data of SCO complexes
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