Gaussian ellipsoid model for confined polymer systems

Polymer systems in slab geometries are studied on the basis of the recently presented Gaussian Ellipsoid Model [J. Chem. Phys. 114, 7655 (2001)].The potential of the confining walls has an exponential shape. For homogeneous systems in thermodynamic equilibrium we discuss density, orientation and deformation profiles of the polymers close to the walls. For strongly segregated mixtures of polymer components A and B equilibrium profiles are studied near a planar interface separating A and B rich regions. Spinodal decomposition processes of the mixtures in the presence of neutral walls show upon strong confinement an increase of the lateral size of A and B rich domains and a slowing down of the demixing kinetics. These findings are in agreement with predictions from time dependent Ginzburg--Landau theory. In the case, where one wall periodically favors one of the two mixture components over the other, different equilibrium structures emerge and lead to different kinetic pathways of spinodal decomposition processes in such systems.Comment: 18 pages, 16 figures, submitted to J. Chem. Phy

Ocean services user needs assessment. Volume 1: Survey results, conclusions and recommendations

An interpretation of environmental information needs of marine users, derived from a direct contact survey of eight important sectors of the marine user community is presented. Findings of the survey and results and recommendations are reported. The findings consist of specific and quantized measurement and derived product needs for each sector and comparisons of these needs with current and planned NOAA data and services. The following supportive and reference material are examined: direct contact interviews with industry members, analyses of current NOAA data gathering and derived product capabilities, evaluations of new and emerging domestic and foreign satellite data gathering capabilities, and a special commercial fishing survey conducted by the Jet Propulsion Laboratory (JPL)

Shear Flows of Rapidly Flowing Granular Materials

Shear flows of granular materials are studied in an open channel. The wall shear is calculated from an open channel momentum equation which includes the density variations in the flow. An experimental technique was developed that allowed the measurement of the average density of the flow at different longitudinal locations in the channel. Two sizes of glass beads are examined and results show the variations in the wall shear as a function of various dimensionless parameters

Synthesis of perfluorinated polyethers

A series of highly fluorinated acetylenes was prepared and their cyclization reactions were studied. A series of perfluoropolytriazines with -CF2I pendent groups were prepared. These materials can be cured thermally or photochemically to an elastomeric gum. Perfluoropolytriazines with -CN pendent groups were prepared. These materials can be crosslinked by reaction with terephthalonitrile oxide

Flight tests of a direct lift control system during approach and landing

Flight tests of modified aileron direct lift control system during approach and landing of F8-C aircraf

Dissipation due to tunneling two-level systems in gold nanomechanical resonators

We present measurements of the dissipation and frequency shift in nanomechanical gold resonators at temperatures down to 10 mK. The resonators were fabricated as doubly-clamped beams above a GaAs substrate and actuated magnetomotively. Measurements on beams with frequencies 7.95 MHz and 3.87 MHz revealed that from 30 mK to 500 mK the dissipation increases with temperature as $T^{0.5}$, with saturation occurring at higher temperatures. The relative frequency shift of the resonators increases logarithmically with temperature up to at least 400 mK. Similarities with the behavior of bulk amorphous solids suggest that the dissipation in our resonators is dominated by two-level systems

Nonlinear modal coupling in a high-stress doubly-clamped nanomechanical resonator

We present results from a study of the nonlinear intermodal coupling between different flexural vibrational modes of a single high-stress, doubly-clamped silicon nitride nanomechanical beam. The measurements were carried out at 100 mK and the beam was actuated using the magnetomotive technique. We observed the nonlinear behavior of the modes individually and also measured the coupling between them by driving the beam at multiple frequencies. We demonstrate that the different modes of the resonator are coupled to each other by the displacement induced tension in the beam, which also leads to the well known Duffing nonlinearity in doubly-clamped beams.Comment: 15 pages, 7 figure

Clues to the Origin of the Mass-Metallicity Relation: Dependence on Star Formation Rate and Galaxy Size

We use a sample of 43,690 galaxies selected from the Sloan Digital Sky Survey Data Release 4 to study the systematic effects of specific star formation rate (SSFR) and galaxy size (as measured by the half light radius, r_h) on the mass-metallicity relation. We find that galaxies with high SSFR or large r_h for their stellar mass have systematically lower gas phase-metallicities (by up to 0.2 dex) than galaxies with low SSFR or small r_h. We discuss possible origins for these dependencies, including galactic winds/outflows, abundance gradients, environment and star formation rate efficiencies.Comment: Accepted by ApJ Letter

New Techniques for Relating Dynamically Close Galaxy Pairs to Merger and Accretion Rates : Application to the SSRS2 Redshift Survey

We introduce two new pair statistics, which relate close galaxy pairs to the merger and accretion rates. We demonstrate the importance of correcting these (and other) pair statistics for selection effects related to sample depth and completeness. In particular, we highlight the severe bias that can result from the use of a flux-limited survey. The first statistic, denoted N_c, gives the number of companions per galaxy, within a specified range in absolute magnitude. N_c is directly related to the galaxy merger rate. The second statistic, called L_c, gives the total luminosity in companions, per galaxy. This quantity can be used to investigate the mass accretion rate. Both N_c and L_c are related to the galaxy correlation function and luminosity function in a straightforward manner. We outline techniques which account for various selection effects, and demonstrate the success of this approach using Monte Carlo simulations. If one assumes that clustering is independent of luminosity (which is appropriate for reasonable ranges in luminosity), then these statistics may be applied to flux-limited surveys. These techniques are applied to a sample of 5426 galaxies in the SSRS2 redshift survey. Using close dynamical pairs, we find N_c(-21<M_B<-18) = 0.0226+/-0.0052 and L_c(-21<M_B<-18) = 0.0216+/-0.0055 10^{10} h^2 L_sun at z=0.015. These are the first secure estimates of low-z close pair statistics. If N_c remains fixed with redshift, simple assumptions imply that ~ 6.6% of present day galaxies with -21<M_B<-18 have undergone mergers since z=1. When applied to redshift surveys of more distant galaxies, these techniques will yield the first robust estimates of evolution in the galaxy merger and accretion rates. [Abridged]Comment: 26 pages (including 10 postscript figures) plus 3 gif figures. Accepted for publication in ApJ. Paper (including full resolution images) also available at http://www.astro.utoronto.ca/~patton/ssrs2, along with associated pair classification experiment (clickable version of Figure 5