7,667 research outputs found

    XANES in (TMTSeF)2Re04: Polarization Dependence of the Se K-Edge

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    We have measured XANES (X-ray Absorption Near Edge Spectra) near the Re Li (i=l,II,III) edges in (TMTTF)2Re04 and (TMTSeF) 2Re04 and the Se K edge in the latter compound. An important dependence of the XANES at the Se K edge on the polarisation of the incident beam with respect to the crystal axes was observed, whose interpretation can give information on the symmetry of the unoccupied conduction band states. The positions of the Re L edges were compared with those in several inorganic compounds containing Re in various oxidation states, and were found to be, within experimental error, the same as those in KRe04, suggesting the molecular environment in the organic materials affects little the chemical state of the perrhenate anion

    Fire and rescue service reconfiguration: a case study in Nottinghamshire

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    The Fire Cover Review in Nottinghamshire arises out of the Integrated Risk Management Planning process introduced in the UK by the Fire and Rescue 2004 Act,. It is intended to provide the evidence and analysis for the reconfiguration of services and the future deployment of resources in in the short, medium and long terms. Any future reconfigurations of services must be based on contemporary and comprehensive risk assessments of the areas affected.(ODPM 2004). The need to undertake the review pre-dated the current financial crises, the general election and the need for significant reductions in public expenditure in the UK, although these circumstances made the review more challenging and politically sensitive. This paper evaluates the practical implementation of the Integrated Risk Management Planning process and the Fire Cover Review in Nottinghamshire to identify good practice and to generate recommendations for improving the process and its implementation

    Transport and Magnetic Properties of FexVse2 (x = 0 - 0.33)

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    We present our results of the effect of Fe intercalation on the structural, transport and magnetic properties of 1T-VSe2. Intercalation of iron, suppresses the 110K charge density wave (CDW) transition of the 1T-VSe2. For the higher concentration of iron, formation of a new kind of first order transition at 160K takes place, which go on stronger for the 33% Fe intercalation. Thermopower of the FexVSe2 compounds (x = 0 - 0.33), however do not show any anomaly around the transition. The intercalation of Fe does not trigger any magnetism in the weak paramagnetic 1T-VSe2, and Fe is the low spin state of Fe3+.Comment: 7 pages, 8 figures, 2 table

    Spin-torque generation by dc or ac voltages in magnetic layered structures

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    A general expression of the current induced spin torque in a magnetic layered structure in the presence of external dc or ac voltages is derived in the framework of the scattering matrix approach. A detailed analysis is performed for a magnetic-nonmagnetic-magnetic trilayer connected to external leads in the presence of dc voltage bias in the ballistic regime. Alternatively, the possibility of producing spin torque by means of the adiabatic ac modulation of external gate voltages (quantum pumping) is proposed and discussed

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    Nanoparticles in explosives detection – the state-of-the-art and future directions

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    ESR Study of Optically Induced Phase Transitions

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    We have identified an optically enhanced magnetic phase transition in the newly synthesized organic molecular charge transfer salt, (BEDT-TTF)3Ta2F11 (BEDT-TTF bisethylenedithiolotetrathiafulvalene) by ESR absorption measurements in the X band microwave region. At room temperature, only a doublet state ESR absorption is observed, but below 30 K severa~ tripl~t E.SR absorpti_ons appear. The orientation dependence of the ESR absorption under lllummat10n at energies near the band gaps in the material ( 640 nm, T = 12 to 5 K H0 \u3c 0.34 T) indicates that there are rapid spin exchange processes with times r \u3c w-s; near 7 ~o 5 K.along cert~in ~rystallographic directions with a temperature dependen~e suggesting spm-lattlce relaxation times which proceed via Van Vleck direct processes. This, to our knowledge, is the first case where the magnetic properties of a charge transfer salt are altered by the interaction with photons of energy equal to the band gaps in a low dimensional solid providing a new, interesting way to investigate these materials

    Iron abundance and magnetic permeability of the moon

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    A larger set of simultaneous data from the Apollo 12 lunar surface magnetometer and the Explorer 35 Ames magnetometer are used to construct a whole-moon hysteresis curve, from which a new value of global lunar permeability is determined to be mu = 1.012 + or - 0.006. The corresponding global induced dipole moment is 2.1 x 10 to the 18th power gauss-cu cm for typical inducing fields of .0001 gauss in the lunar environment. From the permeability measurement, lunar free iron abundance is determined to be 2.5 + or - 2.0 wt. %. Total iron abundance (sum of iron in the ferromagnetic and paramagnetic states) is calculated for two assumed compositional models of the lunar interior: a free iron/orthopyroxene lunar composition and a free iron/olivine composition. The overall lunar total iron abundance is determined to be 9.0 + or - 4.7 wt. %. Other lunar models with a small iron core and with a shallow iron-rich layer are discussed in light of the measured global permeability
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